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Classification and consequences of complex lead perovskite ferroelectrics with regard to B-site cation order

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Abstract

From a number of studies on ferroelectric and related materials based on complex lead perovskites [Pb(Bx′B1−x″)O3], it is apparent that the B-site cation order influences the crystallography, phase transitions, and other physical properties. A classification of complex lead perovskites is presented based on the relative scale of long-range cation order. In particular, we discuss the implications of cation order in relation to relaxor and normal ferroelectric behavior.

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Authors and Affiliations

  1. Materials Research Laboratory, The Pennsylvania State University, University Park, 16802, Pennsylvania, USA

    C. A. Randall, A. S. Bhalla, T. R. Shrout & L. E. Cross

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  1. C. A. Randall
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  2. A. S. Bhalla
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  3. T. R. Shrout
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  4. L. E. Cross
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Randall, C.A., Bhalla, A.S., Shrout, T.R. et al. Classification and consequences of complex lead perovskite ferroelectrics with regard to B-site cation order. Journal of Materials Research 5, 829–834 (1990). https://doi.org/10.1557/JMR.1990.0829

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  • DOI: https://doi.org/10.1557/JMR.1990.0829

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