Abstract
Highly oriented diamond films were grown on single-crystal silicon substrates. Textured films were first nucleated by a two-step process that involved the conversion of the silicon surface to an epitaxial SiC layer, followed by bias-enhanced nucleation. The nucleation stage, which produced a partially oriented diamond film, was immediately followed by a (100) textured growth process, thus resulting in a film surface where approximately 100% of the grains are epitaxially oriented relative to the silicon substrate. The diamond films were characterized by both SEM and Raman spectroscopy. Structural defects in the film are discussed in the context of their potential effect on the electrical characteristics of the resulting film.
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S. Yugo, T. Kanai, T. Kimura, and T. Muto, Appl. Phys. Lett. 58, 1036–1038 (1991).
B. R. Stoner, B. E. Williams, S. D. Wolter, K. Nishimura, and J. T. Glass, J. Mater. Res. 7, 257–260 (1992).
B. R. Stoner, G-H. M. Ma, S. D. Wolter, and J. T. Glass, Phys. Rev. B 45, 11067–11084 (1992).
B.R. Stoner and J.T. Glass, Appl. Phys. Lett. 60, 698–700 (1992).
B. R. Stoner, G-H. M. Ma, S. D. Wolter, W. Zhu, Y. C. Wang, R. F. Davis, and J. T. Glass, submitted to Diamond and Related Materials, presented at Diamond Films ‘92, paper No. 4.3. (1992).
W. Zhu, X. H. Wang, B. R. Stoner, G. H. Ma, H. S. Kong, M. W. H. Braun, and J. T. Glass, Phys. Rev. B (in press).
S. D. Wolter, B. R. Stoner, J. T. Glass, P. J. Ellis, D. S. Buhaenko, C. E. Jenkins, and P. Southworth, Appl. Phys. Lett. (in press).
R.E. Clausing, L. Heatherly, E.D. Specht, and K.L. Moore in New Diamond Science and Technology, edited by R. Messier, J. T. Glass, J. E. Butler, and R. Roy (Mater. Res. Soc. Symp. Int. Proc. NDST-2, Pittsburgh, PA, 1991) p. 575.
C. Wild, W. Miiller-Sebert, T. Eckermann, and P. Koidl, Electrochem. Soc. Proc. 91–8, 224 (1991).
C. Wild, P. Koidl, N. Herres, W. Miiller-Sebert, and T. Eckermann, Presented at the 2nd Int. Conf. on Diamond Materials, ECS Spring Meeting, Washington, DC, May 1991.
A. van der Drift, Philips Res. Rep. 22, 267 (1967).
C. Wild, N. Herres, and P. Koidl, J. Appl. Phys. 68, 973 (1990).
The Experimental Strategies Foundation, P.O. Box 27254, Seattle, WA 98125.
P. Koidl, C. Wild, N. Herres, W. Muller, H. Walcher, R. Walcher, R. Locher, R. Kohl, R. Samlenski, G. Fleming, and R. Brenn, to appear in Diamond and Related Materials, presented at Diamond Films ‘92, Heidelberg, Germany, Aug. 31–Sept. 3, 1992, paper No. 5.2 (1992).
P.M.J. Maree, J.C. Barbour, J.F.v.d. Veen, K.L. Kavanagh, C. W. T. Bulle-Lieuwma, and M. P. A. Viegers, J. Appl. Phys. 62, 4413–4420 (1987).
R. J. Matyi, J. W. Lee, and H. F. Schaake, J. Electron. Mater. 17, 87–93 (1988).
J. A. von Windheim, V. Venkatesan, D. M. Malta, and K. Das, submitted to Diamond and Related Materials, presented at Diamond Films ‘92, Heidelberg, Germany, Aug. 31–Sept. 3, paper No. 13.88 (1992).
E. P. Visser, G. J. Bauhuis, G. Janssen, W. Vollenberg, W. J. P. van Enckevort, and L. J. Giling, J. Phys.: Condens. Matter 4, 7365 (1992).
M. W. Geis, H.I. Smith, A. Argoitia, J. Angus, G-H.M. Ma, J.T. Glass, J. Buttler, C. J. Robinson, and R. Pryor, Appl. Phys. Lett. 58, 2485–2487 (1991).
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Stoner, B.R., Sahaida, S.R., Bade, J.P. et al. Highly oriented, textured diamond films on silicon via bias-enhanced nucleation and textured growth. Journal of Materials Research 8, 1334–1340 (1993). https://doi.org/10.1557/JMR.1993.1334
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DOI: https://doi.org/10.1557/JMR.1993.1334