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Synthesis and characterization of a novel layered titanium phosphate

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Abstract

A novel metastable layered titanium phosphate has been synthesized by the treatment of layered titanates (Na2Ti3O7 and Na4Ti9O20) with 1–2 M phosphoric acid solution at 120–150 °C. Based on the data of 31P MAS NMR and IR spectroscopy, x-ray powder diffraction, and thermal and elemental analysis, the formula Ti2O3(H2PO4)2 • 2H2O was assigned to the novel compound. The layered nature of the compound was confirmed from n-alkylamine intercalation and the ion exchange behavior toward alkali, alkaline earth, and some transition metal ions.

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Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843, USA

    Anatoly I. Bortun, Lyudmila Bortun & Abraham Clearfield

  2. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Oviedo, 33071, Spain

    María A. Villa-García, José R. García & Julio Rodríguez

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  1. Anatoly I. Bortun
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  2. Lyudmila Bortun
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  3. Abraham Clearfield
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  4. María A. Villa-García
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  5. José R. García
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  6. Julio Rodríguez
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Bortun, A.I., Bortun, L., Clearfield, A. et al. Synthesis and characterization of a novel layered titanium phosphate. Journal of Materials Research 11, 2490–2498 (1996). https://doi.org/10.1557/JMR.1996.0314

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  • DOI: https://doi.org/10.1557/JMR.1996.0314

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