Abstract
Rutile TiO2 nanowhiskers have been synthesized by annealing a precursor powder in which NaCl and Ti(OH)4 particles were homogeneously mixed. The precursor powder was prepared by mixing three kinds of inverse microemulsions (μE) containing TiCl4 aqueous solution, ammonia, and NaCl aqueous solution, respectively, followed by washing with acetone. Annealing temperature and packing density of Ti(OH)4 in the precursor powder influenced the formation of rutile nanowhiskers. The optimum temperature was 750 °C. TiO2 nanowhiskers obtained by annealing a precursor powder in which the molar ratio of sodium to titanium was 400 at 750 °C for 2 h had diameters of 10–50 nm and lengths of several micrometers. They were straight rods with square cross sections, and the side surfaces were composed of four equivalent {110} planes.
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References
Nanostructured Materials in Electrochemistry, edited by P.C. Searson and G.J. Mayer (Electrochem. Soc. Proc. 95–8, Pennington, 1995).
Photocatalysis: Fundamentals and Applications, edited by N. Serpone and E. Pellizetti (John Wiley & Sons, New York, 1989).
P. Jones and J.A. Hockey, Trans. Faraday Soc. 67, 2679 (1971).
S. Toshev in Crystal Growth: A Introduction, edited by P. Hartman (North-Holland, Amsterdam, 1973), p. 328.
H. Dal, E.W. Wong, Y.Z. Lu, S. Fan, and C.M. Lieber, Nature 375, 769 (1995).
W. Han, S. Fan, Q. Li, and Y. Hu, Science 277, 1287 (1997).
A.M. Morales and C.M. Lieber, Science 279, 208 (1998).
J. Westwater, D.P. Gosain, S. Tomiya, and S. Usui, J. Vac. Sci. Technol. B15, 554 (1997).
K. Hiruma, M. Yazawa, T. Katsuyama, K. Ogawa, K. Haraguchi, and M. Koguchi, J. Appl. Phys. 77, 447 (1995).
T.J. Trantler, K.M. Hickman, S.C. Goel, A.M. Viano, P.C. Gibbons, and W.E. Buhro, Science 270, 1791 (1995).
C.R. Martin, Science 266, 1961 (1994).
C. Cuerrent-Plecourt, Nature 372, 761 (1994).
E. Braun, Nature 391, 775 (1998).
S. Matsuda, Appl. Catal. 8, 149 (1983).
G. Dagan and M. Tomkiewics, J. Phys. Chem. 97, 12651 (1003).
A.M. Azad, L.B. Younkman, and S. A. Akbar, J. Am. Ceram. Soc. 77, 481 (1994).
Y.C. Yeh, T.T. Tseng, and D.A. Chang, J. Am. Ceram. Soc. 73, 1992 (1990).
A.M. Katayama, H. Hasegawa, T. Noda, T. Akiba, and H. Yanagida, Sensors and Actuators B2, 143 (1992).
R. Marchand, L. Brohan, and M. Tournoux, Mater. Res. Bull. 15, 1129 (1980).
H. Yanagita, T. Shimizu, K. Hashimoto, T. Morita, and D. Tsbone, Jpn. Patent 78 41,518 (1978).
L. Elfenthal, E. Klein, and F. Rosendahl, German Patent 41 05,345.1 (1992).
T. Oota and I. Yamai, J. Cryst. Growth 66, 262 (1984).
J. Wang, L.S. Ee, S.C. Ng, C.H. Chew, and L.M. Gan, Mater. Lett. 30, 119 (1997).
P. Barnickel, A. Wokaun, W. Sager, and H.F. Eiche, J. Colloid Interface Sci. 148, 80 (1992).
H. Herrig and R. Hempelmann, Mater. Lett. 27, 287 (1996).
S. Hingorani, D.O. Shah, and M.S. Multani, J. Mater. Res. 10, 461 (1995).
W. Hartl, Ch. Beck, M. Roth, F. Meyer, and R. Hempelmann, Ber. Bunsenges Phys. Chem. 101, 1714 (1997).
P. Kumar, V. Pilloi, and D.O. Shah, Appl. Phys. Lett. 62, 765 (1993).
S. Schlag, H.E. Eicke, D. Mathys, and R. Guggenheim, Langmuir 10, 3775 (1994).
M. Gan, H.S.O. Chan, L.H. Zhang, C.H. Chew, and B.H. Loo, Mater. Chem. Phys. 37, 263 (1994).
A. Pathank, D.K. Mukhopadhyay, and P. Pramnik, Mater. Res. Bull. 27, 155 (1992).
H.K. Park, D.K. Kim, and C.H. Kim, J. Am. Ceram. Soc. 80, 743 (1997).
J. Harada, M. Takata, H. Miyatake, and H. Koyama, J. Appl. Cryst. 22, 592 (1989).
J.W. Edington, Electron Diffraction in The Electron Microscope (Macmillan Press, London, 1975), p. 54.
A. Szabo and T. Engel, Surf. Sci. 329, 241 (1995).
H. Onishi and Y. Iwasawa, Surf. Sci. 313, L783 (1994).
C. Xu, X. Lai, G.W. Zajac, and D.W. Goodman, Phys. Rev. B56, 13464 (1992).
L.D. Marks and D.J. Smith, Nature 303, 316 (1983).
L.D. Marks, Phys. Rev. Lett. 51, 1000 (1983).
K-N.P. Kumar, Script. Metal. Mater. 32, 873 (1995).
X.Z. Ding and Y.Z. He, J. Mater. Sci. Lett. 15, 320 (1996).
R. Rodriguez, S. Vrgas, R. Arroyo-Murillo, R. Montiel-Campos, and E. Haro-Poniatowski, J. Mater. Res. 12, 439 (1997).
E.M. Levin and H.F. McMuride, Phase Diagrams for Ceramist, edited by K.R. Margie (Am. Ceram. Soc., Columbus, OH, 1969) suppl. p. 473.
K-N.P. Kumar, K. Keizer, A.J. Burggraaf, T. Okubo, H. Nagamoto, and S. Morooka, Nature 358, 48 (1992).
U. Gesenhues, Solid State Ionics 101–103, 1171 (1997).
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Li, G.L., Wang, G.H. & Hong, J.M. Synthesis and characterization of rutile TiO2 nanowhiskers. Journal of Materials Research 14, 3346–3354 (1999). https://doi.org/10.1557/JMR.1999.0453
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DOI: https://doi.org/10.1557/JMR.1999.0453