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Strain gradient plasticity effect in indentation hardness of polymers

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Abstract

Plasticity in material is typically described as a function of strain, but recent observations from torsion and indentation experiments in metals suggested that plasticity is also dependent on strain gradient. The effects of strain gradient on plastic deformation in thermosetting epoxy and polycarbonate thermoplastic were experimentally investigated by nanoindentation and atomic force microscopy in this study. Both thermosetting and thermoplastic polymers exhibited hardening as a result of imposed strain gradients. Strain gradient plasticity theory developed on the basis of a molecular kinking mechanism has predicted strain gradient hardening in polymers. Comparisons made between indentation data and theoretical predictions correlated well. This suggests that strain gradient plasticity in glassy polymers is determined by molecular kinking mechanisms.

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Authors and Affiliations

  1. Department of Mechanical Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong

    Arthur C. M. Chong & David C. C. Lam

Authors
  1. Arthur C. M. Chong
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  2. David C. C. Lam
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Chong, A.C.M., Lam, D.C.C. Strain gradient plasticity effect in indentation hardness of polymers. Journal of Materials Research 14, 4103–4110 (1999). https://doi.org/10.1557/JMR.1999.0554

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  • DOI: https://doi.org/10.1557/JMR.1999.0554

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