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Growth of superconducting and non-superconducting whiskers in the Bi-Sr-Ca-Cu-O (BSCCO) system

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Abstract

Growth of such non-superconducting whiskers [Sr2.24Ca0.4Al2Ox, (Ca0.8–0.85Sr0.15–0.1)2CuO3,CuO, or Bi2.44Sr2Ca1.3–2Cu6.9–9.95Al0.35–0.46Ox (Cu-rich whiskers)] formed during the growth of Bi-2212 superconducting whiskers from powder or glassy substrates, is discussed. These whiskers are likely to grow from the bottom end, and there is a tight relationship with the growth of the Bi-2212 whiskers. A general reaction-path model for the whisker growth in the BSCCO system, independent of the type of the catalytic impurity and substrate, is proposed. When whiskers are grown under magnetic fields, up to 10 T, changes in the whisker size, aspect ratio, and morphology are observed.

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References

  1. I. Matsubara T. Ogura H. Tanigawa H. Yamashita M. Kinoshita and T. Kawai: Growth of Bi-Sr-Ca-Cu-O based superconducting whiskers. J. Cryst. Growth 110 973 (1991).

    Article  CAS  Google Scholar 

  2. H. Uemoto M. Mizutani S. Kishida and T. Yamashita: Growth mechanism of Bi-based superconducting whiskers. Physica C 392 512 (2003).

    Article  Google Scholar 

  3. M. Yamada N. Hosi and S. Kambe: Addition of Ag Pb K or Li to Bi2Sr2CaCu2Oy whisker. Physica C 378–381 152 (2002).

    Article  Google Scholar 

  4. S. Kishida and H. Uemoto: Characterization of Bi-based whiskers by the method of Al2O3-seeded glassy quenched platelets. Int. J. Mod. Phys. B 16 4497 (2002).

    Article  CAS  Google Scholar 

  5. I. Matsubara H. Kageyama H. Tanigawa T. Ogura H. Yamashita and T. Kawai: Preparation of fibrous Bi(Pb)-Sr-Ca-Cu-O crystals and their superconducting properties in a bending state. Jpn. J. Appl. Phys. 28 L1121 (1989).

    Article  CAS  Google Scholar 

  6. P. Badica K. Togano and H. Kumakura: A modified airtight two-crucible method for growth of Bi-2212 whiskers from glassy pellets. Supercond. Sci. Technol. 17 891 (2004).

    Article  CAS  Google Scholar 

  7. P. Badica K. Togano S. Awaji K. Watanabe A. Iyo and H. Kumakura: Application of elevated magnetic fields during growth of BiSrCaCuO superconducting whiskers and studies of growth defects for better understanding of the growth mechanism. J. Cryst. Growth 269 518 (2004).

    Article  CAS  Google Scholar 

  8. I. Matsubara R. Funahashi T. Ogura H. Yamashita K. Tsuru and T. Kawai: Growth mechanism of Bi2Sr2CaCu2Ox superconducting whiskers. J. Cryst. Growth 141 131 (1994).

    Article  CAS  Google Scholar 

  9. C.J. Murphy: Nanocubes and nanoboxes. Science 298 2139 (2002).

    Article  CAS  Google Scholar 

  10. D. Wang M. Mo D. Yu L. Xu F. Li and Y. Qian: Large-scale growth and shape evolution of Cu2O cubes. Cryst. Growth Des. 3 717 (2003).

    Article  CAS  Google Scholar 

  11. J. Grivel-C. and R. Flükiger: A study of the stability of the (Bi,Pb)2Sr2Ca2Cu3Ox phase in Ag-sheathed tapes. Physica C 235–240 505 (1994).

    Article  Google Scholar 

  12. P.E. Kazin V.V. Poltavetz Y.D. Tretyakov M. Jansen B. Freitag and W. Mader: Study on the superconducting composite material formation in the system Bi2Sr2CaCu2O8+x/Al-containing phases. Physica C 280 253 (1997).

    Article  CAS  Google Scholar 

  13. E.E. Hellstrom: Phase relations and alignment in Bi-based high-Tc wires. JOM 44 48 (1992).

    Article  CAS  Google Scholar 

  14. J. Polonka M. Xu Q. Li A.I. Goldman and D.K. Finnemore: In-situ x-ray investigation of the melting of Bi-Sr-Ca-Cu-O phases. Appl. Phys. Lett. 59 3640 (1991).

    Article  CAS  Google Scholar 

  15. P.E. Kazin V.V. Poltavetz O.N. Poltavetz A.A. Kovalevsky Y.D. Tretyakov and M. Jansen: Formation of Bi-2212 phase and phase assemblage in Ga-doped BSCCO system. Physica C 324 30 (1999).

    Article  CAS  Google Scholar 

  16. L. Dimesso I. Matsubara T. Ogura R. Funahashi H. Yamashita and A. Tampieri: Effect of the Ga-doping on the growth and superconducting properties of the Bi2Sr2CaCu2Oy whiskers. Physica C 235–240 473 (1994).

    Article  Google Scholar 

  17. M. Nagao M. Sato and H. Maeda: Growth and superconducting properties of Bi2Sr2CaCu2O8+d single crystal whiskers using tellurium-doped precursors. Appl. Phys. Lett. 79 2612 (2001).

    Article  CAS  Google Scholar 

  18. M. Nagao M. Sato Y. Tachiki K. Miyagawa M. Tanaka H. Maeda K.S. Yun Y. Takano and T. Hatano: Growth of R-123 phase single crystal whiskers. Jpn. J. Appl. Phys. 43 L324 (2004).

    Article  CAS  Google Scholar 

  19. T. Kasuga and Y. Abe: Phase separation and crystallization of BiSrCaCu2Al0.5Ox glass. J. Am. Ceram. Soc. 76 1885 (1993).

    Article  CAS  Google Scholar 

  20. X.G. Zheng M. Suzuki and C.N. Xu: A new approach to single crystal growth of CuO. Mater. Res. Bull. 33 605 (1998).

    Article  CAS  Google Scholar 

  21. T. Sata K. Sakai and S. Tashiro: Vapor pressures of bismuth lead and copper components in Bi2Sr1.7CaCu2Oy and Bi1.7Pb0.3Sr1.7Ca2Cu3Oy superconductor ceramics. J. Am. Ceram. Soc. 75 805 (1992).

    Article  CAS  Google Scholar 

  22. S. Räth L. Woodall C. Deroche B. Seipel F. Schwaigerer and W.W. Schmahl: Quantitative phase analysis of PBSCCO 2223 precursor powders—an XRD/Rietveld refinement study. Supercond. Sci. Technol. 15 543 (2002).

    Article  Google Scholar 

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Badica, P., Togano, K. Growth of superconducting and non-superconducting whiskers in the Bi-Sr-Ca-Cu-O (BSCCO) system. Journal of Materials Research 20, 3358–3367 (2005). https://doi.org/10.1557/jmr.2005.0413

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  • DOI: https://doi.org/10.1557/jmr.2005.0413

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