Abstract
To date graphene and graphene-derived materials have created an immense research interests due to its extraordinary physical, chemical, and physiochemical properties, which delineated graphene as an outstanding material for future electronics, optics, and energy-harvesting devices. Typically, graphene has high mobility and optical transparency along with excellent mechanical properties and chemical inertness. Single-layer graphene exhibits ultrahigh optical transmissivity (∼98%), which allows passing through wide range of light wave lengths, thus designated as an ever-reported material for an optically conducting window. Furthermore, graphene’s optical, electrical, and electrocatalytic properties can be tuned by applying different chemical functionalization protocols, which make it one of the most suitable candidates for advanced applications in optoelectronic and energy-harvesting devices. This review is intended to summarize the most important experimental results from the recent publications concerning the fascinating properties of graphene electrodes and their applications in various types of solar cells. Furthermore, the state of the art of different graphene synthesis processes and functionalization for the applications in solar cells are also discussed in this review.
Similar content being viewed by others
References
A.A. Balandin: Thermal properties of graphene and nanostructured carbon materials. Nat. Mater. 10, 569–581 (2011).
A.K. Geim and K.S. Novoselov: The rise of graphene. Nat. Mater. 6, 183–191 (2007).
S. Das and W. Choi: Graphene synthesis. In Graphene: Synthesis and Applications, Vol. 3, 1st ed.; W. Choi and J-W. Lee eds.; Taylor & Francis Group: Boca Raton, FL, 2011; pp. 27–63.
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, and A.A. Firsov: Electric field effect in atomically thin carbon films. Science 306, 666–669 (2004).
L.M. Viculis, J.J. Mack, and R.B. Kaner: A chemical route to carbon nanoscrolls. Science 299, 1361 (2003).
Y. Hernandez, V. Nicolosi, M. Lotya, F.M. Blighe, Z.Y. Sun, S. De, I.T. McGovern, B. Holland, M. Byrne, Y.K. Gun’ko, J.J. Boland, P. Niraj, G. Duesberg, S. Krishnamurthy, R. Goodhue, J. Hutchison, V. Scardaci, A.C. Ferrari, and J.N. Coleman: High-yield production of graphene by liquid-phase exfoliation of graphite. Nat. Nanotechnol. 3, 563–568 (2008).
W.S. Hummers and R.E. Offeman: Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958).
S.S. Li, K.H. Tu, C.C. Lin, C.W. Chen, and M. Chhowalla: Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cells. ACS Nano 4, 3169–3174 (2010).
P. Hasin, M.A. Alpuche-Aviles, and Y.Y. Wu: Electrocatalytic activity of graphene multi layers toward I−/I3−: Effect of preparation conditions and polyelectrolyte modification. J. Phys. Chem. C 114, 15857–15861 (2010).
J.D. Roy-Mayhew, D.J. Bozym, C. Punckt, and I.A. Aksay: Functionalized graphene as a catalytic counter electrode in dye-sensitized solar cells. ACS Nano 4, 6203–6211 (2010).
G.L. Li, G. Liu, M. Li, D. Wan, K.G. Neoh, and E.T. Kang: Organo- and water-dispersible graphene oxide-polymer nanosheets for organic electronic memory and gold nanocomposites. J. Phys. Chem. C 114, 12742–12748 (2010).
S.Q. Chen and Y. Wang: Microwave-assisted synthesis of a Co3O4-graphene sheet-on-sheet nanocomposite as a superior anode material for Li-ion batteries. J. Mater. Chem. 20, 9735–9739 (2010).
J. Wintterlin and M.L. Bocquet: Graphene on metal surfaces. Surf. Sci. 603, 1841–1852 (2009).
J.K. Wassei, M. Mecklenburg, J.A. Torres, J.D. Fowler, B.C. Regan, R.B. Kaner, and B.H. Weiller: Chemical vapor deposition of graphene on copper from methane, ethane and propane: Evidence for bilayer selectivity. Small 8, 1415–1422 (2012).
C. Berger, Z.M. Song, T.B. Li, X.B. Li, A.Y. Ogbazghi, R. Feng, Z.T. Dai, A.N. Marchenkov, E.H. Conrad, P.N. First, and W.A. de Heer: Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics. J. Phys. Chem. B 108, 19912–19916 (2004).
M. Hupalo, E.H. Conrad, and M.C. Tringides: Growth mechanism for epitaxial graphene on vicinal 6H-SiC(0001) surfaces: A scanning tunneling microscopy study. Phys. Rev. B 80, 4 (2009).
K.V. Emtsev, A. Bostwick, K. Horn, J. Jobst, G.L. Kellogg, L. Ley, J.L. McChesney, T. Ohta, S.A. Reshanov, J. Rohrl, E. Rotenberg, A.K. Schmid, D. Waldmann, H.B. Weber, and T. Seyller: Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide. Nat. Mater. 8, 203–207 (2009).
W.A. de Heer, C. Berger, X.S. Wu, P.N. First, E.H. Conrad, X.B. Li, T.B. Li, M. Sprinkle, J. Hass, M.L. Sadowski, M. Potemski, and G. Martinez: Epitaxial graphene. Solid State Commun. 143, 92–100 (2007).
E. Kymakis, E. Stratakis, M.M. Stylianakis, E. Koudoumas, and C. Fotakis: Spin coated graphene films as the transparent electrode in organic photovoltaic devices. Thin Solid Films 520, 1238–1241 (2011).
H.A. Becerril, J. Mao, Z. Liu, R.M. Stoltenberg, Z. Bao, and Y. Chen: Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2, 463–470 (2008).
X. Wang, L.J. Zhi, and K. Mullen: Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett. 8, 323–327 (2008).
A. Chavez-Valdez, M.S.P. Shaffer, and A.R. Boccaccini: Applications of graphene electrophoretic deposition. A review. J. Phys. Chem. B 117, 1502–1515 (2013).
G. Eda, Y-Y. Lin, S. Miller, C-W. Chen, W-F. Su, and M. Chhowalla: Transparent and conducting electrodes for organic electronics from reduced graphene oxide. Appl. Phys. Lett. 92, 233305–233313 (2008).
D. Li, M.B. Muller, S. Gilje, R.B. Kaner, and G.G. Wallace: Processable aqueous dispersions of graphene nanosheets. Nat. Nanotechnol. 3, 101–105 (2008).
L.J. Cote, F. Kim, and J. Huang: Langmuir−blodgett assembly of graphite oxide single layers. J. Am. Chem. Soc. 131, 1043–1049 (2008).
R. Ishikawa, M. Bando, H. Wada, Y. Kurokawa, A. Sandhu, and M. Konagai: Layer-by-layer assembled transparent conductive graphene films for silicon thin-film solar cells. Jpn. J. Appl. Phys. 51, 4 (2012).
Y. Zhu, W. Cai, R.D. Piner, A. Velamakanni, and R.S. Ruoff: Transparent self-assembled films of reduced graphene oxide platelets. Appl. Phys. Lett. 95, 103104–103113 (2009).
C. Chen, Q-H. Yang, Y. Yang, W. Lv, Y. Wen, P-X. Hou, M. Wang, and H-M. Cheng: Self-assembled free-standing graphite oxide membrane. Adv. Mater. 21, 3007–3011 (2009).
J. Kim, L.J. Cote, F. Kim, W. Yuan, K.R. Shull, and J. Huang: Graphene oxide sheets at interfaces. J. Am. Chem. Soc. 132, 8180–8186 (2010).
X.S. Li, W.W. Cai, J.H. An, S. Kim, J. Nah, D.X. Yang, R. Piner, A. Velamakanni, I. Jung, E. Tutuc, S.K. Banerjee, L. Colombo, and R.S. Ruoff: Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324, 1312–1314 (2009).
S. Das, P. Sudhagar, V. Verma, D. Song, E. Ito, S.Y. Lee, Y.S. Kang, and W. Choi: Amplifying charge-transfer characteristics of graphene for triiodide reduction in dye-sensitized solar cells. Adv. Funct. Mater. 21, 3729–3736 (2011).
X. Li, R. Zhang, W. Yu, K. Wang, J. Wei, D. Wu, A. Cao, Z. Li, Y. Cheng, Q. Zheng, R.S. Ruoff, and H. Zhu: Stretchable and highly sensitive graphene-on-polymer strain sensors. Sci. Rep. 2, 870 (2012). doi: 10.1038/srep00870.
V.P. Verma, S. Das, I. Lahiri, and W. Choi: Large-area graphene on polymer film for flexible and transparent anode in field emission device. Appl. Phys. Lett. 96, 203108 (2010). doi: 10.1063/1.3431630.
D.H. Wang, J.K. Kim, J.H. Seo, I. Park, B.H. Hong, J.H. Park, and A.J. Heeger: Transferable graphene oxide by stamping nanotechnology: Electron-transport layer for efficient bulk-heterojunction solar cells. Angew. Chem. Int. Ed. 52, 2874–2880 (2013).
S. Bae, H. Kim, Y. Lee, X.F. Xu, J.S. Park, Y. Zheng, J. Balakrishnan, T. Lei, H.R. Kim, Y.I. Song, Y.J. Kim, K.S. Kim, B. Ozyilmaz, J.H. Ahn, B.H. Hong, and S. Iijima: Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nat. Nanotechnol. 5, 574–578 (2010).
J-H. Chen, C. Jang, S. Xiao, M. Ishigami, and M.S. Fuhrer: Intrinsic and extrinsic performance limits of graphene devices on SiO2. Nat. Nanotechnol. 3, 206–209 (2008).
A. Akturk and N. Goldsman: Electron transport and full-band electron-phonon interactions in graphene. J. Appl. Phys. 103, 053702–053708 (2008).
X.S. Li, Y.W. Zhu, W.W. Cai, M. Borysiak, B.Y. Han, D. Chen, R.D. Piner, L. Colombo, and R.S. Ruoff: Transfer of large-area graphene films for high-performance transparent conductive electrodes. Nano Lett. 9, 4359–4363 (2009).
I. Lahiri, V.P. Verma, and W. Choi: An all-graphene based transparent and flexible field emission device. Carbon 49, 1614–1619 (2011).
X. Li, H. Zhu, K. Wang, A. Cao, J. Wei, C. Li, Y. Jia, Z. Li, X. Li, and D. Wu: Graphene-on-silicon schottky junction solar cells. Adv. Mater. 22, 2743–2748 (2010).
Y. Ye, Y. Dai, L. Dai, Z. Shi, N. Liu, F. Wang, L. Fu, R. Peng, X. Wen, Z. Chen, Z. Liu, and G. Qin: High-performance single CdS nanowire (nanobelt) schottky junction solar cells with Au/graphene schottky electrodes. ACS Appl. Mater. Interfaces 2, 3406–3410 (2010).
X. Miao, S. Tongay, M.K. Petterson, K. Berke, A.G. Rinzler, B.R. Appleton, and A.F. Hebard: High efficiency graphene solar cells by chemical doping. Nano Lett. 12, 2745–2750 (2012).
S. Tongay, K. Berke, M. Lemaitre, Z. Nasrollahi, D.B. Tanner, A.F. Hebard, and B.R. Appleton: Stable hole doping of graphene for low electrical resistance and high optical transparency. Nanotechnology 22, 425701 (2011).
I. Mora-Seró and J. Bisquert: Breakthroughs in the development of semiconductor-sensitized solar cells. J. Phys. Chem. Lett. 1, 3046–3052 (2010).
J.Y. Kim, K. Lee, N.E. Coates, D. Moses, T-Q. Nguyen, M. Dante, and A.J. Heeger: Efficient tandem polymer solar cells fabricated by all-solution processing. Science 317, 222–225 (2007).
A. Yella, H-W. Lee, H.N. Tsao, C. Yi, A.K. Chandiran, M.K. Nazeeruddin, E.W-G. Diau, C-Y. Yeh, S.M. Zakeeruddin, and M. Grätzel: Porphyrin-sensitized solar cells with cobalt (II/III)–based redox electrolyte exceed 12 percent efficiency. Science 334, 629–634 (2011).
A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, and H. Pettersson: Dye-sensitized solar cells. Chem. Rev. 110, 6595–6663 (2010).
D. Chen, H. Zhang, Y. Liu, and J. Li: Graphene and its derivatives for the development of solar cells, photoelectrochemical, and photocatalytic applications. Energy Environ. Sci. 6, 1362–1387 (2013).
H-X. Wang, Q. Wang, K-G. Zhou, and H-L. Zhang: Graphene in light: Design, synthesis and applications of photo-active graphene and graphene-like materials. Small 9, 1266–1283 (2013).
W. Tu, Y. Zhou, and Z. Zou: Versatile graphene-promoting photocatalytic performance of semiconductors: Basic principles, synthesis, solar energy conversion, and environmental applications. Adv. Funct. Mater. (2013). doi: 10.1002/adfm.201203547.
J. Zhang, F. Zhao, Z. Zhang, N. Chen, and L. Qu: Dimension-tailored functional graphene structures for energy conversion and storage. Nanoscale 5, 3112–3126 (2013).
H.N. Kim, H. Yoo, and J.H. Moon: Graphene-embedded 3D TiO2 inverse opal electrodes for highly efficient dye-sensitized solar cells: Morphological characteristics and photocurrent enhancement. Nanoscale 5, 4200–4204 (2013).
F. Gong, X. Xu, G. Zhou, and Z.S. Wang: Enhanced charge transportation in a polypyrrole counter electrode via incorporation of reduced graphene oxide sheets for dye-sensitized solar cells. Phys. Chem. Chem. Phys. 15, 546–552 (2013).
A. Chavez-Valdez, M.S. Shaffer, and A.R. Boccaccini: Applications of graphene electrophoretic deposition. A review. J. Phys. Chem. B 117, 1502–1515 (2013).
S. Morales-Torres, L.M. Pastrana-Martinez, J.L. Figueiredo, J.L. Faria, and A.M. Silva: Design of graphene-based TiO2 photocatalysts: A review. Environ. Sci. Pollut. Res. Int. 19, 3676–3687 (2012).
J.S. Lee, H.J. Ahn, J.C. Yoon, and J.H. Jang: Three-dimensional nano-foam of few-layer graphene grown by CVD for DSSC. Phys. Chem. Chem. Phys. 14, 7938–7943 (2012).
Z. Peining, A.S. Nair, P. Shengjie, Y. Shengyuan, and S. Ramakrishna: Facile fabrication of TiO2-graphene composite with enhanced photovoltaic and photocatalytic properties by electrospinning. ACS Appl. Mater. Interfaces 4, 581–585 (2012).
K.S. Lee, Y. Lee, J.Y. Lee, J.H. Ahn, and J.H. Park: Flexible and platinum-free dye-sensitized solar cells with conducting-polymer-coated graphene counter electrodes. ChemSusChem 5, 379–382 (2012).
L. Kavan, J.H. Yum, and M. Gratzel: Graphene nanoplatelets outperforming platinum as the electrocatalyst in co-bipyridine-mediated dye-sensitized solar cells. Nano Lett. 11, 5501–5506 (2011).
Z. He, G. Guai, J. Liu, C. Guo, J.S. Loo, C.M. Li, and T.T. Tan: Nanostructure control of graphene-composited TiO2 by a one-step solvothermal approach for high performance dye-sensitized solar cells. Nanoscale 3, 4613–4616 (2011).
L. Kavan, J.H. Yum, M.K. Nazeeruddin, and M. Gratzel: Graphene nanoplatelet cathode for Co(III)/(II) mediated dye-sensitized solar cells. ACS Nano 5, 9171–9178 (2011).
J. Song, Z. Yin, Z. Yang, P. Amaladass, S. Wu, J. Ye, Y. Zhao, W.Q. Deng, H. Zhang, and X.W. Liu: Enhancement of photogenerated electron transport in dye-sensitized solar cells with introduction of a reduced graphene oxide-TiO2 junction. Chem. Eur. J. 17, 10832–10837 (2011).
R. Bajpai, S. Roy, P. Kumar, P. Bajpai, N. Kulshrestha, J. Rafiee, N. Koratkar, and D.S. Misra: Graphene supported platinum nanoparticle counter-electrode for enhanced performance of dye-sensitized solar cells. ACS Appl. Mater. Interfaces 3, 3884–3889 (2011).
L. Kavan, J.H. Yum, and M. Gratzel: Optically transparent cathode for dye-sensitized solar cells based on graphene nanoplatelets. ACS Nano 5, 165–172 (2011).
J.D. Roy-Mayhew, D.J. Bozym, C. Punckt, and I.A. Aksay: Functionalized graphene as a catalytic counter electrode in dye-sensitized solar cells. ACS Nano 4, 6203–6211 (2010).
D.M. Guldi and V. Sgobba: Carbon nanostructures for solar energy conversion schemes. Chem. Commun. 47, 606–610 (2011).
D. Wei: Dye sensitized solar cells. Int. J. Mol. Sci. 11, 1103–1113 (2010).
Y.B. Tang, C.S. Lee, J. Xu, Z.T. Liu, Z.H. Chen, Z. He, Y.L. Cao, G. Yuan, H. Song, L. Chen, L. Luo, H.M. Cheng, W.J. Zhang, I. Bello, and S.T. Lee: Incorporation of graphenes in nanostructured TiO2 films via molecular grafting for dye-sensitized solar cell application. ACS Nano 4, 3482–3488 (2010).
N. Yang, J. Zhai, D. Wang, Y. Chen, and L. Jiang: Two-dimensional graphene bridges enhanced photoinduced charge transport in dye-sensitized solar cells. ACS Nano 4, 887–894 (2010).
N.J. Bell, Y.H. Ng, A. Du, H. Coster, S.C. Smith, and R. Amal: Understanding the enhancement in photoelectrochemical properties of photocatalytically prepared TiO2-reduced graphene oxide composite. J. Phys. Chem. C 115, 6004–6009 (2011).
T. Chen, W. Hu, J. Song, G.H. Guai, and C.M. Li: Interface functionalization of photoelectrodes with graphene for high performance dye-sensitized solar cells. Adv. Funct. Mater. 22, 5245–5250 (2012).
B. Tang and G. Hu: Two kinds of graphene-based composites for photoanode applying in dye-sensitized solar cell. J. Power Sources 220, 95–102 (2012).
C.Y. Neo and J. Ouyang: Graphene oxide as auxiliary binder for TiO2 nanoparticle coating to more effectively fabricate dye-sensitized solar cells. J. Power Sources 222, 161–168 (2013).
S. Sun, L. Gao, and Y. Liu: Enhanced dye-sensitized solar cell using graphene-TiO2 photoanode prepared by heterogeneous coagulation. Appl. Phys. Lett. 96, 083113 (2010).
H. Wang, S.L. Leonard, and Y.H. Hu: Promoting effect of graphene on dye-sensitized solar cells. Ind. Eng. Chem. Res. 51, 10613–10620 (2012).
B. Tang, G. Hu, H. Gao, and Z. Shi: Three-dimensional graphene network assisted high performance dye sensitized solar cells. J. Power Sources 234, 60–68 (2013).
X-Y. Zhang, H-P. Li, X-L. Cui, and Y. Lin: Graphene/TiO2 nanocomposites: Synthesis, characterization and application in hydrogen evolution from water photocatalytic splitting. J. Mater. Chem. 20, 2801–2806 (2010).
X. Xin, X. Zhou, J. Wu, X. Yao, and Z. Liu: Scalable synthesis of TiO2/graphene nanostructured composite with high-rate performance for lithium ion batteries. ACS Nano 6, 11035–11043 (2012).
J.N. Ding, C.T. Yu, N.Y. Yuan, Y.B. Liu, and Y Fan: High-quality GS/TiO2 composite for the photoanode of the dye-sensitized solar cells. In Proceedings of the International Conference on Materials for Renewable Energy & Environment (ICMREE), May 20–22, 2011; pp. 90–94.
A. Gs, S. Nair, S.V. Nair, and S. Vadukumpully: One-pot hydrothermal synthesis of TiO2/graphene nanocomposites for enhanced visible photocatalysis and photovoltaics. RSC Adv. 3(31), 12933–12938 (2013). doi: 10.1039/c3ra41388h.
J. Chang, J. Yang, P. Ma, D. Wu, L. Tian, Z. Gao, K. Jiang, and L. Yang: Hierarchical titania mesoporous sphere/graphene composite, synthesis and application as photoanode in dye sensitized solar cells. J. Colloid Interface Sci. 394, 231–236 (2013).
J. Fan, S. Liu, and J. Yu: Enhanced photovoltaic performance of dye-sensitized solar cells based on TiO2 nanosheets/graphene composite films. J. Mater. Chem. 22, 17027–17036 (2012).
L. Sun, Z. Zhao, Y. Zhou, and L. Liu: Anatase TiO2 nanocrystals with exposed {001} facets on graphene sheets via molecular grafting for enhanced photocatalytic activity. Nanoscale 4, 613–620 (2012).
X. Liu, L. Pan, T. Lv, G. Zhu, T. Lu, Z. Sun, and C. Sun: Microwave-assisted synthesis of TiO2-reduced graphene oxide composites for the photocatalytic reduction of Cr(vi). RSC Adv. 1, 1245–1249 (2011).
T.H. Tsai, S.C. Chiou, and S.M. Chen: Enhancement of dye-sensitized solar cells by using graphene-TiO2 composites as photoelectrochemical working electrode. Int. J. Electrochem. Sci. 6, 3333–3343 (2011).
A. Anish Madhavan, S. Kalluri, D.K. Chacko, T.A. Arun, S. Nagarajan, K.R.V. Subramanian, A. Sreekumaran Nair, S.V. Nair, and A. Balakrishnan: Electrical and optical properties of electrospun TiO2-graphene composite nanofibers and its application as DSSC photo-anodes. RSC Adv. 2, 13032–13037 (2012).
X. Zhang, P. Suresh Kumar, V. Aravindan, H.H. Liu, J. Sundaramurthy, S.G. Mhaisalkar, H.M. Duong, S. Ramakrishna, and S. Madhavi: Electrospun TiO2–graphene composite nanofibers as a highly durable insertion anode for lithium ion batteries. J. Phys. Chem. C 116, 14780–14788 (2012).
C.H. Kim, B-H. Kim, and K.S. Yang: TiO2 nanoparticles loaded on graphene/carbon composite nanofibers by electrospinning for increased photocatalysis. Carbon 50, 2472–2481 (2012).
J. Song, Z. Yin, Z. Yang, P. Amaladass, S. Wu, J. Ye, Y. Zhao, W-Q. Deng, H. Zhang, and X-W. Liu: Enhancement of photogenerated electron transport in dye-sensitized solar cells with introduction of a reduced graphene oxide–TiO2 junction. Chem. Eur. J. 17, 10832–10837 (2011).
J. Durantini, P.P. Boix, M. Gervaldo, G.M. Morales, L. Otero, J. Bisquert, and E.M. Barea: Photocurrent enhancement in dye-sensitized photovoltaic devices with titania–graphene composite electrodes. J. Electroanal. Chem. 683, 43–46 (2012).
H. Han, P. Sudhagar, T. Song, Y. Jeon, I. Mora-Sero, F. Fabregat-Santiago, J. Bisquert, Y.S. Kang, and U. Paik: Three dimensional-TiO2 nanotube array photoanode architectures assembled on a thin hollow nanofibrous backbone and their performance in quantum dot-sensitized solar cells. Chem. Commun. 49, 2810–2812 (2013).
M. Gratzel: Photoelectrochemical cells. Nature 414, 338–344 (2001).
M. Grätzel: Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells. J. Photochem. Photobiol., A 164, 3–14 (2004).
J.E. Trancik, S.C. Barton, and J. Hone: Transparent and catalytic carbon nanotube films. Nano Lett. 8, 982–987 (2008).
G.R. Li, F. Wang, Q.W. Jiang, X.P. Gao, and P.W. Shen: Carbon nanotubes with titanium nitride as a low-cost counter-electrode material for dye-sensitized solar cells. Angew. Chem. Int. Ed. 49, 3653–3656 (2010).
M.K. Wang, A.M. Anghel, B. Marsan, N.L.C. Ha, N. Pootrakulchote, S.M. Zakeeruddin, and M. Gratzel: CoS supersedes Pt as efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells. J. Am. Chem. Soc. 131, 15976 (2009).
T.N. Murakami, S. Ito, Q. Wang, M.K. Nazeeruddin, T. Bessho, I. Cesar, P. Liska, R. Humphry-Baker, P. Comte, P. Pechy, and M. Graetzel: Highly efficient dye-sensitized solar cells based on carbon black counter electrodes. J. Electrochem. Soc. 153, A2255–A2261 (2006).
A. Reina, X. Jia, J. Ho, D. Nezich, H. Son, V. Bulovic, M.S. Dresselhaus, and J. Kong: Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett. 9, 30–35 (2008).
M. Acik, G. Lee, C. Mattevi, M. Chhowalla, K. Cho, and Y.J. Chabal: Unusual infrared-absorption mechanism in thermally reduced graphene oxide. Nat. Mater. 9, 840–845 (2010).
L. Kavan, J.H. Yum, and M. Gratzel: Optically transparent cathode for dye-sensitized solar cells based on graphene nanoplatelets. ACS Nano 5, 165–172 (2010).
S. Das, P. Sudhagar, S. Nagarajan, E. Ito, S.Y. Lee, Y.S. Kang, and W. Choi: Synthesis of graphene-CoS electro-catalytic electrodes for dye sensitized solar cells. Carbon 50, 4815–4821 (2012).
S. Das, P. Sudhagar, E. Ito, D-Y. Lee, S. Nagarajan, S.Y. Lee, Y.S. Kang, and W. Choi: Effect of HNO3 functionalization on large scale graphene for enhanced tri-iodide reduction in dye-sensitized solar cells. J. Mater. Chem. 22, 20490–20497 (2012).
C. Xu, J. Li, X. Wang, J. Wang, L. Wan, Y. Li, M. Zhang, X. Shang, and Y. Yang: Synthesis of hemin functionalized graphene and its application as a counter electrode in dye-sensitized solar cells. Mater. Chem. Phys. 132, 858–864 (2012).
Y. Xue, J. Liu, H. Chen, R. Wang, D. Li, J. Qu, and L. Dai: Nitrogen-doped graphene foams as metal-free counter electrodes in high-performance dye-sensitized solar cells. Angew. Chem. Int. Ed. 51, 12124–12127 (2012).
W. Hong, Y. Xu, G. Lu, C. Li, and G. Shi: Transparent graphene/PEDOT–PSS composite films as counter electrodes of dye-sensitized solar cells. Electrochem. Commun. 10, 1555–1558 (2008).
K.S. Lee, Y. Lee, J.Y. Lee, J-H. Ahn, and J.H. Park: Flexible and platinum-free dye-sensitized solar cells with conducting-polymer-coated graphene counter electrodes. ChemSusChem 5, 379–382 (2012).
F. Gong, H. Wang, and Z-S. Wang: Self-assembled monolayer of graphene/Pt as counter electrode for efficient dye-sensitized solar cell. Phys. Chem. Chem. Phys. 13(39), 17676–17682 (2011). doi: 10.1039/c1cp22542a.
P-J. Li, K. Chen, Y-F. Chen, Z-G. Wang, X. Hao, J-B. Liu, J-R. He, and W-L. Zhang: Low platinum loading PtNPs/graphene composite catalyst with high electrocatalytic activity for dye-sensitized solar cells. Chin. Phys. B 21, 118101 (2012).
M. Al-Mamun, J-Y. Kim, Y-E. Sung, J-J. Lee, and S-R. Kim: Pt and TCO free hybrid bilayer silver nanowire–graphene counter electrode for dye-sensitized solar cells. Chem. Phys. Lett. 561–562, 115–119 (2013).
R. Bajpai, S. Roy, N. Koratkar, and D.S. Misra: NiO nanoparticles deposited on graphene platelets as a cost-effective counter electrode in a dye sensitized solar cell. Carbon 56, 56–63 (2013).
Y.Y. Dou, G.R. Li, J. Song, and X.P. Gao: Nickel phosphide-embedded graphene as counter electrode for dye-sensitized solar cells. Phys. Chem. Chem. Phys. 14, 1339–1342 (2012).
Z. Wen, S. Cui, H. Pu, S. Mao, K. Yu, X. Feng, and J. Chen: Metal nitride/graphene nanohybrids: General synthesis and multifunctional titanium nitride/graphene electrocatalyst. Adv. Mater. 23, 5445–5450 (2011).
H. Choi, H. Kim, S. Hwang, M. Kang, D-W. Jung, and M. Jeon: Electrochemical electrodes of graphene-based carbon nanotubes grown by chemical vapor deposition. Scr. Mater. 64, 601–604 (2011).
J. Velten, A.J. Mozer, D. Li, D. Officer, G. Wallace, R. Baughman, and A. Zakhidov: Carbon nanotube/graphene nanocomposite as efficient counter electrodes in dye-sensitized solar cells. Nanotechnology 23, 085201 (2012).
G. Zhu, L. Pan, T. Lu, T. Xu, and Z. Sun: Electrophoretic deposition of reduced graphene-carbon nanotubes composite films as counter electrodes of dye-sensitized solar cells. J. Mater. Chem. 21, 14869–14875 (2011).
L. Wan, S. Wang, X. Wang, B. Dong, Z. Xu, X. Zhang, B. Yang, S. Peng, J. Wang, and C. Xu: Room-temperature fabrication of graphene films on variable substrates and its use as counter electrodes for dye-sensitized solar cells. Solid State Sci. 13, 468–475 (2011).
A. Kaniyoor and S. Ramaprabhu: Thermally exfoliated graphene based counter electrode for low cost dye sensitized solar cells. J. Appl. Phys. 109, 124308–124316 (2011).
D.W. Zhang, X.D. Li, H.B. Li, S. Chen, Z. Sun, X.J. Yin, and S.M. Huang: Graphene-based counter electrode for dye-sensitized solar cells. Carbon 49, 5382–5388 (2011).
C-T. Hsieh, B-H. Yang, and J-Y. Lin: One- and two-dimensional carbon nanomaterials as counter electrodes for dye-sensitized solar cells. Carbon 49, 3092–3097 (2011).
H. Choi, H. Kim, S. Hwang, Y. Han, and M. Jeon: Graphene counter electrodes for dye-sensitized solar cells prepared by electrophoretic deposition. J. Mater. Chem. 21, 7548–7551 (2011).
R. Cruz, D.A. Pacheco Tanaka, and A. Mendes: Reduced graphene oxide films as transparent counter-electrodes for dye-sensitized solar cells. Solar Energy 86, 716–724 2012.
M. Stefik, J-H. Yum, Y. Hu, and M. Gratzel: Carbon-graphene nanocomposite cathodes for improved Co(ii/iii) mediated dye-sensitized solar cells. J. Mater. Chem. A 1, 4982–4987 (2013).
H. Choi, H. Kim, S. Hwang, W. Choi, and M. Jeon: Dye-sensitized solar cells using graphene-based carbon nano composite as counter electrode. Sol. Energy Mater. Sol. Cells 95, 323–325 (2011).
X.B. Xu, D.K. Huang, K. Cao, M.K. Wang, S.M. Zakeeruddin, and M. Gratzel: Electrochemically reduced graphene oxide multilayer films as efficient counter electrode for dye-sensitized solar cells. Sci. Rep. 3, 7 (2013).
W. Sun, T. Peng, Y. Liu, S. Xu, J. Yuan, S. Guo, and X-Z. Zhao: Hierarchically porous hybrids of polyaniline nanoparticles anchored on reduced graphene oxide sheets as counter electrodes for dye-sensitized solar cells. J. Mater. Chem. A 1, 2762–2768 (2013).
P.V. Kamat: Quantum dot solar cells. Semiconductor nanocrystals as light harvesters. J. Phys. Chem. C 112, 18737–18753 (2008).
A.M. Smith and S. Nie: Semiconductor nanocrystals: Structure, properties, and band gap engineering. Acc. Chem. Res. 43, 190–200 (2009).
W.A. Tisdale, K.J. Williams, B.A. Timp, D.J. Norris, E.S. Aydil, and X-Y. Zhu: Hot-electron transfer from semiconductor nanocrystals. Science 328, 1543–1547 (2010).
O.E. Semonin, J.M. Luther, S. Choi, H-Y. Chen, J. Gao, A.J. Nozik, and M.C. Beard: Peak external photocurrent quantum efficiency exceeding 100% via MEG in a quantum dot solar cell. Science 334, 1530–1533 (2011).
B. Farrow and P.V. Kamat: CdSe quantum dot sensitized solar cells. Shuttling electrons through stacked carbon nanocups. J. Am. Chem. Soc. 131, 11124–11131 (2009).
H. Lee, M. Wang, P. Chen, D.R. Gamelin, S.M. Zakeeruddin, M. Gratzel, and M.K. Nazeeruddin: Efficient CdSe quantum dot-sensitized solar cells prepared by an improved successive ionic layer adsorption and reaction process. Nano Lett. 9, 4221–4227 (2009).
H.J. Lee, P. Chen, S.J. Moon, F. Sauvage, K. Sivula, T. Bessho, D.R. Gamelin, P. Comte, S.M. Zakeeruddin, S.I. Seok, M. Gratzel, and M.K. Nazeeruddin: Regenerative PbS and CdS quantum dot sensitized solar cells with a cobalt complex as hole mediator. Langmuir 25, 7602–7608 (2009).
S. Ruhle, M. Shalom, and A. Zaban: Quantum-dot-sensitized solar cells. ChemPhysChem 11, 2290–2304 (2010).
M. Samadpour, S. Gimenez, A.I. Zad, N. Taghavinia, and I. Mora-Sero: Easily manufactured TiO2 hollow fibers for quantum dot sensitized solar cells. Phys. Chem. Chem. Phys. 14, 522–528 (2012).
N. Zhou, Y. Yang, X. Huang, H. Wu, Y. Luo, D. Li, and Q. Meng: Panchromatic quantum-dot-sensitized solar cells based on a parallel tandem structure. ChemSusChem 6, 687–692 (2013).
G. Hodes: Comparison of dye- and semiconductor-sensitized porous nanocrystalline liquid junction solar cells. J. Phys. Chem. C 112, 17778–17787 (2008).
C.X. Guo, H.B. Yang, Z.M. Sheng, Z.S. Lu, Q.L. Song, and C.M. Li: Layered graphene/quantum dots for photovoltaic devices. Angew. Chem. Int. Ed. 49, 3014–3017 (2010).
S. Sun, L. Gao, Y. Liu, and J. Sun: Assembly of CdSe nanoparticles on graphene for low-temperature fabrication of quantum dot sensitized solar cell. Appl. Phys. Lett. 98, 093112 (2011). doi: 10.1063/1.3558732.
I. Mora-Seró, S. Giménez, F. Fabregat-Santiago, R. Gómez, Q. Shen, T. Toyoda, and J. Bisquert: Recombination in quantum dot sensitized solar cells. Acc. Chem. Res. 42, 1848–1857 (2009).
J.W. Lee, D.Y. Son, T.K. Ahn, H.W. Shin, I.Y. Kim, S.J. Hwang, M.J. Ko, S. Sul, H. Han, and N.G. Park: Quantum-dot-sensitized solar cell with unprecedentedly high photocurrent. Sci. Rep. 3, 1050 (2013). doi: 10.1038/srep01050.
P. Sudhagar, K. Asokan, E. Ito, and Y.S. Kang: N-ion-implanted TiO2 photoanodes in quantum dot-sensitized solar cells. Nanoscale 4, 2416–2422 (2012).
Z. Tachan, I. Hod, M. Shalom, L. Grinis, and A. Zaban: The importance of the TiO2/quantum dots interface in the recombination processes of quantum dot sensitized solar cells. Phys. Chem. Chem. Phys. 15, 3841–3845 (2013).
M.S. De La Fuente, R.S. Sánchez, V. González-Pedro, P.P. Boix, S.G. Mhaisalkar, M.E. Rincón, J. Bisquert, and I. Mora-Seró: Effect of organic and inorganic passivation in quantum-dot-sensitized solar cells. J. Phys. Chem. Lett. 4, 1519–1525 (2013).
P. Sudhagar, E. Ramasamy, W-H. Cho, J. Lee, and Y.S. Kang: Robust mesocellular carbon foam counter electrode for quantum-dot sensitized solar cells. Electrochem. Commun. 13, 34–37 (2011).
A. Braga, S. Giménez, I. Concina, A. Vomiero, and I. Mora-Seró: Panchromatic sensitized solar cells based on metal sulfide quantum dots grown directly on nanostructured TiO2 electrodes. J. Phys. Chem. Lett. 2, 454–460 (2011).
J. Zhao, J. Wu, F. Yu, X. Zhang, Z. Lan, and J. Lin: Improving the photovoltaic performance of cadmium sulfide quantum dots-sensitized solar cell by graphene/titania photoanode. Electrochim. Acta 96, 110–116 (2013).
I.V. Lightcap and P.V. Kamat: Fortification of CdSe quantum dots with graphene oxide. Excited state interactions and light energy conversion. J. Am. Chem. Soc. 134, 7109–7116 (2012).
L.S. Li and X. Yan: Colloidal graphene quantum dots. J. Phys. Chem. Lett. 1, 2572–2576 (2010).
Y. Li, Y. Hu, Y. Zhao, G. Shi, L. Deng, Y. Hou, and L. Qu: An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Adv. Mater. 23, 776–780 (2011).
I.P. Hamilton, B. Li, X. Yan, and L.S. Li: Alignment of colloidal graphene quantum dots on polar surfaces. Nano Lett. 11, 1524–1529 (2011).
K.J. Williams, C.A. Nelson, X. Yan, L-S. Li, and X. Zhu: Hot electron injection from graphene quantum dots to TiO2. ACS Nano 7, 1388–1394 (2013).
X. Yan, X. Cui, and B. Li, L-S. Li: Large, solution-processable graphene quantum dots as light absorbers for photovoltaics. Nano Lett. 10, 1869–1873 (2010).
F.C. Krebs: Fabrication and processing of polymer solar cells: A review of printing and coating techniques. Sol. Energy Mater. Sol. Cells 93, 394–412 (2009).
Y-W. Su, S-C. Lan, and K-H. Wei: Organic photovoltaics. Mater. Today 15, 554–562 (2012).
V. Yong and J.M. Tour: Theoretical efficiency of nanostructured graphene-based photovoltaics. Small 6, 313–318 (2010).
L. Gomez De Arco, Y. Zhang, C.W. Schlenker, K. Ryu, M.E. Thompson, and C. Zhou: Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics. ACS Nano 4, 2865–2873 (2010).
V. Gupta, N. Chaudhary, R. Srivastava, G.D. Sharma, R. Bhardwaj, and S. Chand: Luminscent graphene quantum dots for organic photovoltaic devices. J. Am. Chem. Soc. 133, 9960–9963 (2011).
G. Jo, S.I. Na, S.H. Oh, S. Lee, T.S. Kim, G. Wang, M. Choe, W. Park, J. Yoon, D.Y. Kim, Y.H. Kahng, and T. Lee: Tuning of a graphene-electrode work function to enhance the efficiency of organic bulk heterojunction photovoltaic cells with an inverted structure. Appl. Phys. Lett. 97, 213301 (2010). doi: 10.1063/1.3514551.
Y.Y. Lee, K.H. Tu, C.C. Yu, S.S. Li, J.Y. Hwang, C.C. Lin, K.H. Chen, L.C. Chen, H.L. Chen, and C.W. Chen: Top laminated graphene electrode in a semitransparent polymer solar cell by simultaneous thermal annealing/releasing method. ACS Nano 5, 6564–6570 (2011).
Z. He, C. Zhong, S. Su, M. Xu, H. Wu, and Y. Cao: Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure. Nat. Photonics 6, 591–595 (2012).
L. Dou, J. You, J. Yang, C.C. Chen, Y. He, S. Murase, T. Moriarty, K. Emery, G. Li, and Y. Yang: Tandem polymer solar cells featuring a spectrally matched low-bandgap polymer. Nat. Photonics 6, 180–185 (2012).
C.E. Small, S. Chen, J. Subbiah, C.M. Amb, S.W. Tsang, T.H. Lai, J.R. Reynolds, and F. So: High-efficiency inverted dithienogermole-thienopyrrolodione-based polymer solar cells. Nat. Photonics 6, 115–120 (2012).
H. Park, P.R. Brown, V. Bulović, and J. Kong: Graphene as transparent conducting electrodes in organic photovoltaics: Studies in graphene morphology, hole transporting layers, and counter electrodes. Nano Lett. 12, 133–140 (2011).
P. Lin, W.C.H. Choy, D. Zhang, F. Xie, J. Xin, and C.W. Leung: Semitransparent organic solar cells with hybrid monolayer graphene/metal grid as top electrodes. Appl. Phys. Lett. 102, 113303 (2013). doi: 10.1063/1.4798254.
G. Eda, G. Fanchini, and M. Chhowalla: Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nat. Nanotechnol. 3, 270–274 (2008).
X. Wan, G. Long, L. Huang, and Y. Chen: Graphene: A promising material for organic photovoltaic cells. Adv. Mater. 23, 5342–5358 (2011).
S. Abdulalmohsin and J.B. Cui: Graphene-enriched P3HT and porphyrin-modified ZnO nanowire arrays for hybrid solar cell applications. J. Phys. Chem. C 116, 9433–9438 (2012).
Y.Y. Choi, S.J. Kang, H.K. Kim, W.M. Choi, and S.I. Na: Multilayer graphene films as transparent electrodes for organic photovoltaic devices. Sol. Energy Mater. Sol. Cells 96, 281–285 (2012).
C.L. Hsu, C.T. Lin, J.H. Huang, C.W. Chu, K.H. Wei, and L.J. Li: Layer-by-layer graphene/TCNQ stacked films as conducting anodes for organic solar cells. ACS Nano 6, 5031–5039 (2012).
S. Lee, J.S. Yeo, Y. Ji, C. Cho, D.Y. Kim, S.I. Na, B.H. Lee, and T. Lee: Flexible organic solar cells composed of P3HT: PCBM using chemically doped graphene electrodes. Nanotechnology 23, 344013 (2012). doi: 10.1088/0957-4484/23/34/344013.
Z. Liu, J. Li, Z.H. Sun, G. Tai, S.P. Lau, and F. Yan: The application of highly doped single-layer graphene as the top electrodes of semitransparent organic solar cells. ACS Nano 6, 810–818 (2012).
H. Park, R.M. Howden, M.C. Barr, V. Bulović, K. Gleason, and J. Kong: Organic solar cells with graphene electrodes and vapor printed poly(3,4-ethylenedioxythiophene) as the hole transporting layers. ACS Nano 6, 6370–6377 (2012).
S. Zhong, J.Q. Zhong, H.Y. Mao, R. Wang, Y. Wang, D.C. Qi, K.P. Loh, A.T.S. Wee, Z.K. Chen, and W. Chen: CVD graphene as interfacial layer to engineer the organic donor-acceptor heterojunction interface properties. ACS Appl. Mater. Interfaces 4, 3134–3140 (2012).
H.P. Kim, A.R.B. Mohd Yusoff, and J. Jang: Organic solar cells using a reduced graphene oxide anode buffer layer. Sol. Energy Mater. Sol. Cells 110, 87–93 (2013).
H. Park, S. Chang, M. Smith, S. Gradečak, and J. Kong: Interface engineering of graphene for universal applications as both anode and cathode in organic photovoltaics. Sci. Rep. 3, 1581 (2013). doi: 10.1038/srep01581.
A. Iwan and A. Chuchmała: Perspectives of applied graphene: Polymer solar cells. Prog. Polym. Sci. 37, 1805–1828 (2012).
ACKNOWLEDGMENTS
The authors acknowledge the support of the WCU (World Class University) program through the Korea Science and Engineering Foundation funded by the Ministry of Education, Science and Technology (Grant No. R31-2008-000-10092) and Engineering Research Center Program (Grant No. 2012-0000591).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Das, S., Sudhagar, P., Kang, Y.S. et al. Graphene synthesis and application for solar cells. Journal of Materials Research 29, 299–319 (2014). https://doi.org/10.1557/jmr.2013.297
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2013.297