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A New Lithium Iron Phosphate LiFe2P3O10 Synthesized at 600 °C from Precursor Obtained by Wet Chemistry

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Abstract

We present the synthesis and characterization of a novel lithium iron polyphosphate LiFe2P3O10 prepared by wet-chemical technique from nitrate precursors. The crystal system is shown to be monoclinic (P21/m space group) and the refined cell parameters are a=4.596 Å b=8.566 Å, c=9.051 Å and β97.46°. LiFe2P3O10 has a weak antiferromagnetic ordering below the Néel temperature TN=19 K. Electrochemical measurements carried out at 25 °C in lithium cell with LiPF6-EC-DEC electrolyte show a capacity 70 mAh/g in the voltage range 2.7–3.9 V.

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References

  1. A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc. 144, 1188 (1997).

    Article  CAS  Google Scholar 

  2. N. Ravet, Y. Chouinard, J.F. Magnan, S. Besner, M. Gauthier, M. Armand, J. Power Sources 97, 503 (2001).

    Article  Google Scholar 

  3. K. Zaghib, K. Striebel, A. Guerfi, J. Shim, M. Armand, M. Gauthier, Electrochim. Acta 50, 263 (2004).

    Article  CAS  Google Scholar 

  4. A. Ait-Salah, A. Mauger, C.M. Julien, F. Gendron, Mater. Sci. Eng. B 129, 232 (2006).

    Article  Google Scholar 

  5. A. Ait-Salah, A. Mauger, K. Zagib, J.B. Goodenough, N. Ravet, M. Gauthier, F. Gendron, C.M. Julien, J. Electrochem. Soc. 153, A1692 (2006).

    Article  CAS  Google Scholar 

  6. N. Ravet, Y. Chouinard, J.F. Magnan, S. Besner, M. Gauthier, M. Armand, J. Power Sources 97–98 (2001) 403.

    Google Scholar 

  7. B.H. Toby, J. Appl. Cryst. 34 (2001) 210

    Article  CAS  Google Scholar 

  8. F. Erragh, A. Boukhari, E.M. Holt, Acta Cryst. C 52, 1867 (1996).

    Article  Google Scholar 

  9. C.V. Ramana, A. Ait-Salah, S. Utsunomiya, J.F. Morhange, A. Mauger, F. Gendron, C.M. Julien, J. Phys. Chem. C 111, 1049 (2007).

    Article  CAS  Google Scholar 

  10. K. Rissouli, K. Benkhouja, A. Sadel, M. Bettach, M. Zahir, M. Giorgi, M. Pierrot, M. Drillon, Eur. J. Solid State Inorg. Chem. 34, 221 (1997).

    CAS  Google Scholar 

  11. A. Ait-Salah, P. Jozwiak, J. Garbarczyk, K. Benkhouja, K. Zaghib, F. Gendron, C.M. Julien, J. Power Sources 140, 370 (2005).

    Article  Google Scholar 

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Authors and Affiliations

  1. INSP, University Paris 6, 140 rue de Lourmel, 75015, Paris, France

    Atmane Ait-Salah, Jean-François Morhange, Mohamed Selmane & M. Julien Christian

  2. Dept of Geological Sciences, University of Michigan, 48109, Ann Arbor, MI, USA

    V. Ramana Chintalapalle

  3. INSP, University Parisd 6, 140 rue de Lourmel, 75015, Paris, France

    François Gendron

  4. MPPU, CNRS, 140 rue de Lourmel, 75015, Paris, France

    Alain Mauger

Authors
  1. Atmane Ait-Salah
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  2. V. Ramana Chintalapalle
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  3. François Gendron
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  4. Jean-François Morhange
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  5. Alain Mauger
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  6. Mohamed Selmane
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  7. M. Julien Christian
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Ait-Salah, A., Chintalapalle, V.R., Gendron, F. et al. A New Lithium Iron Phosphate LiFe2P3O10 Synthesized at 600 °C from Precursor Obtained by Wet Chemistry. MRS Online Proceedings Library 972, 613 (2006). https://doi.org/10.1557/PROC-0972-AA06-13

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  • DOI: https://doi.org/10.1557/PROC-0972-AA06-13

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