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Local Structure and Magnetic Properties of LixFePO4 Glasses

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Abstract

A series of LixFePO4 samples (0=x=1) have been synthesized in the vitreous state by fast quenching technique. Characterization methods include XRD, TG, FTIR, magnetic susceptibility and electrical measurements. FTIR studies reveal that in the entire composition range the local structure is identical to the olivine lattice including PO4 3- oxo-anions linked to FeO6 octahedra. Magnetic susceptibility data show that the antiferromagnetic ordering does not exist so far and the paramagnetic behaviour follows the Curie-Weiss law above 30 K. Both the Curie parameter and the Weiss temperature suggest a strong weakness of the superexchange interactions that are consistent with the analysis of infrared spectra. Electrical conductivity shows an activated conduction mechanism with Ea =0.67 eV.

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References

  1. A. Manthiram, J.B. Goodenough, J. Solid State Chem. 71, 349 (1987).

    Article  CAS  Google Scholar 

  2. A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc. 144, 1188 (1997).

    Article  CAS  Google Scholar 

  3. N. Ravet, A. Abouimrane, M. Armand, Nat. Mater. 2, 702 (2003).

    Article  CAS  Google Scholar 

  4. H. Huang, S.C. Yin, L.F. Nazar, Electrochem. Solid-State Lett. 4, A170 (2001).

    Article  CAS  Google Scholar 

  5. K. Zaghib, K. Striebel, A. Guerfi, J. Shim, M. Armand, M. Gauthier, Electrochim. Acta 50, 263 (2004).

    Article  CAS  Google Scholar 

  6. A Streltsov, E.L. Belokoneva, V.G. Tsirelson, N.K. Hansen, Acta. Cryst. B 49, 147 (1993).

    Article  Google Scholar 

  7. A. Ait-Salah, P. Jozwiak, J.E. Garbarczyk, K. Benkhouja, K. Zaghib, F. Gendron, C.M. Julien, J. Power Sources 140, 370 (2005).

    Article  Google Scholar 

  8. N. Machida, H. Tanaka, T. Shigematsu, N. Nakanishi, T. Minami, Solid State Ionics 70–71, 328 (1994).

    Article  Google Scholar 

  9. M. Wasiucionek, J. Garbarczyk, P. Kurek, W. Jakubowski, Solid State Ionics 70–71, 346 (1994).

    Article  Google Scholar 

  10. P. Jozwiak, J.E. Garbarczyk, F. Gendron, C.M. Julien, Electrochem. Soc. Proc. 11, 79 (2005).

    Google Scholar 

  11. A. Ait-Salah, P. Jozwiak, J.E. Garbarczyk, F. Gendron, M. Massot, C.M. Julien, Electrochem. Soc. Proc. 11, 173 (2005).

    Google Scholar 

  12. J.E. Garbarczyk, P. Machowski, M. Wasiucionek, L. Tykarski, R. Bacewicz, and A. Aleksiejuk, Solid State Ionics 136–137, 1077 (2000).

    Article  Google Scholar 

  13. R.P. Santoro, R.E. Newnham, S. Nomura, J. Phys. Chem. Solids. 27, 655 (1966).

    Article  CAS  Google Scholar 

  14. R.P. Santoro, D.J. Segal, R.E. Newnham, J. Phys. Chem. Solids. 27, 1192 (1966).

    Article  CAS  Google Scholar 

  15. R.P. Santoro, R.E. Newnham, Acta Crystallogr. 22, 344 (1967).

    Article  CAS  Google Scholar 

  16. J.M. Mays, Phys. Rev. 131, 38 (1963).

    Article  CAS  Google Scholar 

  17. A. Ait-Salah, A. Mauger, F. Gendron, C.M. Julien, Mater. Sci. Eng. B 129, 232 (2006).

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00662, Warsaw, Poland

    Pawel Jozwiak & Jerzy Garbarczyk

  2. INSP, University Paris 6, 140 rue de Lourmel, 75015, Paris, France

    François Gendron & M. Julien Christian

  3. MPPU, CNRS, 140 rue de Lourmel, 75015, Paris, France

    Alain Mauger

Authors
  1. Pawel Jozwiak
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  2. Jerzy Garbarczyk
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  3. François Gendron
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  4. Alain Mauger
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  5. M. Julien Christian
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Jozwiak, P., Garbarczyk, J., Gendron, F. et al. Local Structure and Magnetic Properties of LixFePO4 Glasses. MRS Online Proceedings Library 972, 615 (2006). https://doi.org/10.1557/PROC-0972-AA06-15

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  • DOI: https://doi.org/10.1557/PROC-0972-AA06-15

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