Abstract
The concept of using “self-assembled” and “force-engineered” nanostructures to enhance the thermoelectric figure of merit relative to bulk homogeneous and composite materials is presented in general terms. Specific application is made to the Si-Ge system for use in power generation at high temperature. The scientific advantages of the nanocomposite approach for the simultaneous increase in the power factor and decrease of the thermal conductivity are emphasized along with the practical advantages of having bulk samples for property measurements and a straightforward path to scale-up materials synthesis and integration of nanostructured materials into thermoelectric cooling and power generation devices.
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References
L. D. Hicks and M. S. Dresselhaus, Phys. Rev. B 47, 12727–12731 (1993).
L. D. Hicks, T. C. Harman, and M. S. Dresselhaus, Appl. Phys. Lett. 63, 3230 (1993).
Lon Bell report at the Industrial Physics Forum, of the American Vacuum Society and the American Institute of Physics, Seattle, WA, Oct 2007.
B.Y. Moyzhes and V. Nemchinsky, Appl. Phys. Lett., 73, 1895–1897 (1998).
T. Koga, X. Sun, S. B. Cronin, and M. S. Dresselhaus, Appl. Phys. Lett. 73, 2950–2952 (1998).
T. C. Harman, P. J. Taylor, M. P. Walsh, and B. E. LaForge, Science 297, 2229–2232 (2002).
Rama Venkatasubramanian, E. Siivola, Thomas Colpitts, and Brooks O’Quinn, Nature (London) 413, 597–602 (2001).
Kuei Fang Hsu, Sim Loo, Fu Guo, Wei Chen, Jeffrey S. Dyck, Ctirad Uher, Tim Hogan, E. K. Polychroniadis, and Mercouri G. Kanatzidis, Science 303, 818-821 (2004).
J. Androulakis, K. F. Hsu, R. Pcionek, H. Kong, C. Uher, J. J. D’Angelo, A. Downey, T. Hogan, and M. G. Kanatzidis, Advanced Materials 18, 1170–1173 (2006).
M. S. Dresselhaus, G. Chen, M. Y. Tang, R. G. Yang, H. Lee, D. Z. Wang, Z. F. Ren, J. P. Fleurial, and P. Gogna, Advanced Materials 19, 1043–1053 (2007).
Deyu Li, Yiying Wu, Philip Kim, Li Shi, Peidong Yang, and Arun Majumdar, Appl. Phys. Lett. 83, 2934–2936 (2003).
Deyu Li, Yiying Wu, Rong Fan, Peidong Yang, and Arun Majumdar, Appl. Phys. Lett. 83, 3186– 3188 (2003).
C. Dames and G. Chen, J. Appl. Phys. 95, 682–693 (2004).
C. Dames and G. Chen, “Thermal Conductivity of Nanostructured Thermoelectric Materials”, CRC Handbook, edited by M. Rowe, pp.42-1 to 42-16, (2006), Taylor and Francis, Boca Raton.
Ming-Shan Jeng, Ronggui Yang, David Song, and Gang Chen. In Proceedings of the ASME/Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems, pages HT2005-72780, American Society of Mechanical Engineers, New York, 2005.
Ronggui Yang, Gang Chen, and M. S. Dresselhaus, Phys. Rev. B 72, 125418 (2005).
Ronggui Yang. Nanoscale Heat Conduction with Applications in Thermoelectrics and Nanoelectronics. PhD thesis, Massachusetts Institute of Technology, December 2005. Department of Mechancial Engineering.
G. A. Slack, in Solid State Physics, page 1, edited by D. Turnbull and H. Ehrenreich (Academic, New York, 1979), Vol. 34.
A. Henry and G. Chen, Spectral Phonon Properties of Silicon Based Molecular Dynamics and Lattice Dynamics Simulations, Journal of Computational and Theoretical Nanosciences, accepted.
Vining C.B. and Fleurial J.P., “Silicon-Germanium: an Overview of Recent Developments”, A Critical Review of Space Nuclear Power and Propulsion 1984-1993, American Institute of Physics, ed. M. El-Genk, New-York, 87–120 (1994).
T. C. Harman, D. L. Spears, and M. J. Manfra, J. Electron. Mater. 25, 1121 (1996).
T. C. Harman, D. L. Spears, D. R. Calawa, S. H. Groves, and M. P. Walsh. In Sixteenth International Conference on Thermoelectrics: Proceedings, ICT’97; Dresden, Germany, edited by Armin Heinrich and Joachim Schumann, page 416, Institute of Electrical and Electronics Engineers, Inc., Piscataway, NJ 09955-1331, 1997.
L. D. Hicks, T. C. Harman, X. Sun, and M. S. Dresselhaus, Phys. Rev. B 53, 10493–10496 (1996).
G.D. Mahan and J.O. Sofo, Proc. Natl. Acad. Sci. USA 93, 7426 (1996).
K. Hoang, S. D. Mahanti, and P. Jena, Phys. Rev. B 76, 115432 (2007).
T. Geballe and R. N. Hall, Phys. Rev. 98, 940 (1955).
R. N. Hall, Solid-State Electronics 2, 115 (1958).
J. P. Dismukes, L. Ekstrom, E. F. Steigmeier, I. Kudman, and D. S. Beers, J. Appl. Phys. 35, 2899– 2907 (1964).
F.D. Rosi, J.P. Dismukes, and E.F. Hockings, Electrical Engineering 79(6), 450–459 (1960).
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Dresselhaus, M.S., Chen, G., Ren, Z. et al. Nanocomposites to Enhance Zt in Thermoelectrics. MRS Online Proceedings Library 1044, 204 (2007). https://doi.org/10.1557/PROC-1044-U02-04
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DOI: https://doi.org/10.1557/PROC-1044-U02-04