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Effect of Phase Transformations on Hardness of Semiconductors

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Abstract

Models that describe hardness of materials do not account for stress-induced phase transformations that occur under sharp indenters. However, experimental work shows that some materials can be transformed under the indenter into new, high-pressure phases with properties that differ significantly from those of the pristine material. In particular, semiconductors (Si, Ge and other) experience Herzfeld-Mott transition (metallization). Significant volume changes can accompany these transformations. In the present paper, Tanaka’s model [1] has been modified to account for reversible phase transformations under contact loading.

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References

  1. K. Tanaka, J. Mater. Sci. 22, 1501–1508 (1987).

    Article  Google Scholar 

  2. I. V. Gridneva, Yu.V. Milman and V. I. Trefilov, {utPhys. Stat. Sol. (a)}, 14, 177–182 (1972).

    Article  CAS  Google Scholar 

  3. R. W. Cahn, Nature, 357, 645–646 (1992).

    Article  Google Scholar 

  4. J. J. Gilman, J. Mater. Res. 7, 535–538 (1992).

    Article  CAS  Google Scholar 

  5. D. L. Callahan and J. C. Morris, J. Mater. Res., 7 1614–1617 (1992).

    Article  CAS  Google Scholar 

  6. G. M. Pharr, W. C. Oliver, and D. R. Clarke, Scripta Metall. 23, 1949 (1989).

    Article  CAS  Google Scholar 

  7. Y. G. Gogotsi, A. Kailer, K. G. Nickel, Materials Research Innovations, 1 (1) 3–9 (1997).

    Article  CAS  Google Scholar 

  8. A. Kailer, Y. G. Gogotsi, K. G. Nickel, J. Appl. Phys. 81 (7), 3057–3063 (1997).

    Article  CAS  Google Scholar 

  9. B. Lawn, R. Wilshaw, J. Mater. Sci. 10, 1049–1081 (1975).

    Article  Google Scholar 

  10. I. J. McHolm, Ceramic Hardness (Plenum Press, New York, 1990).

    Google Scholar 

  11. K.L. Johnson, Contact Mechanics (Cambridge University Press, England, 1985).

    Book  Google Scholar 

  12. R. Hill, The Mathematical Theory of Plasticity (Oxford University Press, London, 1959).

    Google Scholar 

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Galanov, B.A., Grigor‘ev, O.N. & Gogotsi, Y.G. Effect of Phase Transformations on Hardness of Semiconductors. MRS Online Proceedings Library 481, 249–254 (1997). https://doi.org/10.1557/PROC-481-249

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  • DOI: https://doi.org/10.1557/PROC-481-249

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