Skip to main content
SpringerLink
Log in

From Hybrid Films to Mesoorganized Multi-metal-oxide Nanocrystalline Films (M3NF), preparation and characterization.

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

High quality and reproducible thin silica and non-silica mesoporous films were obtained with mono-oriented organised mesoporosity, fitting various symmetry groups (i.e. p6m, Pm3n, Im3m, …). The Evaporation Induced Self Assembly (EISA) mechanism of structuration was studied through in-situ time-resolved SAXS, interferometry and spectroscopic ellipsometry investigations during dip-coating. A Modulable Steady State (MSS) was found during which the system is in quasi-equilibrium with its environment and during which the final structure is formed. The corresponding Self-Assembly mechanism was found to be governed by a competition between evaporation, micellization and condensation that depend on various critical chemical and processing parameters the influence of which have been summarized into directly usable phase diagrams. Calcined SiO2 and TiO2 mesoporous films structure (pore size and anisotropy, porous volume and surface) and mechanical properties (young modulus) were investigated by UV-Visible spectroscopic ellipsometry. Finally, thanks to a specially designed block copolymer, one further step was accomplished by achieving the dip coating and controlled nano-crystallisation of various metallic and multi-metal-oxides films (M3NF) of composition CoxTi(1-x)O(2-x) with ilmenite or doped Anatase structure, and SrTiO3 and MgTa2O6 with perovskite structure. Attending the well known magnetic, dielectric and catalytic properties of these structures, M3NF are highly compatible with high technology applications in microelectronic, energy transfer devices, spintronic, nano-mechanical adjustments, data storage, oxide fuel cells …

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. Sanchez, G. J. A. A. Soler-Hlia, F. Ribot, T. Lalot, C. R. Mayer and V. Cabuil, Chem. Mater., 13, 3061. (2001)

    Article  CAS  Google Scholar 

  2. (a) C. T. Kresge, M. F. Lenowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 359, 710 (1992); (b) G. J. A. A. Soler-Illia, C. Sanchez, B. Lebeau and J. Patarin, Chem. Rev., 102, 4093 (2002).

    Article  CAS  Google Scholar 

  3. (a) S. Besson, T. Gacoin, C. Ricolleau, C. Jacquiod and J. P. Boilot, J. Mater. Chem., 13, 404 (2003); (b) F. Cagnol, D. Grosso, G. J. A. A. Soler-Illia, E. L. Crepaldi, F. Babonneau, H. Amenitsch and C. Sanchez, J. Mater. Chem., 13, 61 (2003); (c) A. Gibaud, D. Grosso, B. Smarsly, A. Baptiste, J. F. Bardeu, F. Babonneau, D. A. Doshi, Z. Chen, C. J. Brinker and C. Sanchez, J. Phys. Chem. B, 107, 6114 (2003); (d) D. A. Doshi, A. Gibaud, N. Liu, D. Sturmayr, A. P. Malanoski, D. R. Dunphy, H. Chen, S. Narayan, A. MacPhee, J. Wang, S. T. Reed, A. J. Hurd, F. Van Swol and C. J. Brinker, J. Phys. Chem. B, 107, 7683 (2003); (e) P. Innocenzi, P. Falcaro, D. Grosso and F. Babonneau, J. Phys. Chem. B, 107, 4711 (2003).

    Article  CAS  Google Scholar 

  4. (a) A. Stein, B. J. Melde and R. C. Schroden, Adv. Mater., 12, 1403 (2000); (b) A. Sayari and S. Hamoudi, Chem. Mater., 13, 3151 (2001).

    Article  CAS  Google Scholar 

  5. K. Moller and T. Bein, Chem. Mater., 10, 2950 (1998).

    Article  CAS  Google Scholar 

  6. C. J. Brinker, Y. Lu, A. Sellinger and H. Fan, Adv. Mater., 11, 579 (1999).

    Article  CAS  Google Scholar 

  7. Fullerenes: From Synthesis to Optoelectronic Properties, Vol. 4, ed. D. M. Guldi and N. Martin, Kluwer Academic Publishers, Dordrecht, NL, (2002).

  8. P. Innocenzi and G. Brusatin, Chem. Mater., 13, 3126 (2001).

    Article  CAS  Google Scholar 

  9. F. Rachdi, L. Hajji, C. Goze, D. J. Jones, P. Maireles-Torres and J. Roziere, Solid State Commun., 100, 2377 (1996).

    Article  Google Scholar 

  10. Huo {etet al.}, Chem. Mater. 6, 1176 (1994)

    Article  CAS  Google Scholar 

  11. C.T. Kresge, M.E. Leoniwicz, W.J. Vartuli, J.S. Beck, Nature, 359, 710 (1992).

    Article  CAS  Google Scholar 

  12. a) A. Galarneau, D. Lerner, M.F. Ottaviani, F. Di-Renzo, F. Fajula, Stud. Surf. Sci. Catal., 117, 405 (1998). b) J. Frasch, B. Lebeau, M. Soulard, J. Patarin, Langmuir, 16, 9049 (2000)

    Article  CAS  Google Scholar 

  13. D. Grosso, F. Babonneau {etet al.}, Chem, Mater, 2, 931 (2002)

    Article  Google Scholar 

  14. C. Boissiere, A. Larbot, C. Bourgaux, E. Prouzet, C.A. Bunton, Chem. Mater, 13, 3580 (2001)

    Article  CAS  Google Scholar 

  15. Q. Huo, D.I. Margolese, U. Ciesa, D.G. Demuth, P. Feng, T.E. Gier, P. Sieger, A. Firouzi, B.F. Chmelka, G.D. Stucky, Chem, Mater, 6, 1176 (1994)

    Article  CAS  Google Scholar 

  16. D. Grosso, Florence Cagnol, G.A de A.A. Soler-Illia, E. Crepaldi, H. Amenitsch, A. Brunet-Bruneau, A. Bourgeois, C. Sanchez, Adv. Funct. Mater, 14, 311 (2004).

    Article  Google Scholar 

  17. E. Crepaldi {etet al.} J. AM. Chem. Soc., 125, 9770 (2003)

    Article  CAS  Google Scholar 

  18. E. Crepaldi {etet al.} N. J. Chem., 27, 9 (2003)

    Article  CAS  Google Scholar 

  19. E. Crepaldi, D. Grosso, G.J. de A.A. Soler-Illia, P.A. Albouy, H. Amenitsch, C. Sanchez, Chem. Mater, 14, 3316 (2002)

    Article  CAS  Google Scholar 

  20. D. Grosso, C. Boissiere, B. Smarsly, T. Brezesinski, N. Pinna, P.A. Albouy, H. Amenitsch, M. Antonietti, C. Sanchez, Nat. Mater, 3, 787 (2004)

    Article  CAS  Google Scholar 

  21. M.R. Baklanov, K.P. Mogilnikov, V.G. Polovinkin, F.N. Dultsev, J. Vac. Sci. Technol. B, 18, 3,1385–1391(2000)

    Article  Google Scholar 

  22. K.P. Mogilnikov, M.R. Baklanov, Electrochem. And Sol. Stat. Let., 5, 12, F29–F31 (2002)

    Article  CAS  Google Scholar 

  23. A. Galarneau, D. Desplantier-Giscard, F. Di-Renzo, F. Fajula, Catalysis Today, 68, 191 (2001)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chimie de la Matière Condensée, UPMC- CNRS UMR 7574, 4 place Jussieu, 75252, Paris Cedex 05, France

    Cédric Boissière, David Grosso, Sophie Lepoutre, Lionel Nicole, J.C. Valle Marcos & Clément Sanchez

  2. Max Planck Institute of Colloids and Interfaces, Research Campus Golm, D-14424, Potsdam, Germany

    Bernt Smarsly, Torsten Brezesinski & Marcus Antonietti

Authors
  1. Cédric Boissière
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. David Grosso
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bernt Smarsly
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Torsten Brezesinski
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sophie Lepoutre
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Lionel Nicole
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. J.C. Valle Marcos
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Marcus Antonietti
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Clément Sanchez
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Boissière, C., Grosso, D., Smarsly, B. et al. From Hybrid Films to Mesoorganized Multi-metal-oxide Nanocrystalline Films (M3NF), preparation and characterization.. MRS Online Proceedings Library 847, 308–319 (2004). https://doi.org/10.1557/PROC-847-EE2.2

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-847-EE2.2

Search

Navigation