Abstract
This work analyzed perovskite quantum dots, in this case, CsPbBr3 PQDs. The morphological and structural characterization shows three PQDs crystalline phases with an average particle size of 14 nm. On the other hand, the optical results show PQDs absorption at 487 nm, and PL is centered at 501 nm with excitation at 405 nm, indicating potential properties for photovoltaic and optoelectronic devices. The solar cell was fabricated and studied: FTO/c-TiO2/m-TiO2/PQDs/spiro-OMeTAD/Al. The JV curves suggested that the photocurrent was 0.196 mA cm−2 with FF and Voc values of 24.5% and 0.72 V, respectively. A solar cell was obtained at ambient conditions with future optimization to make it more efficient.
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The datasets generated during and/or analyzed during the current study are not publicly available due to the information is extremely a lot, but are available from the corresponding author on reasonable request.
References
L. Ahmad, N. Khordehgah, J. Malinauskaite, H. Jouhara, Recent advances and applications of solar photovoltaics and thermal technologies. Energy (2020). https://doi.org/10.1016/j.energy.2020.118254
A. Dey et al., State of the art and prospects for halide perovskite nanocrystals. ACS Nano 15(7), 10775–10981 (2021). https://doi.org/10.1021/acsnano.0c08903
The National Renewable Energy Laboratory (NREL), Best Research-Cell Efficiency Chart, (2022).
B. Weber, R. Magaña-López, I.G. Martínez Cienfuegos, M.D. Durán-García, E.A. Stadlbauer, Current status of photovoltaic plants in Mexico: An analysis based on online monitoring. Energy for Sustain. Dev. 57, 48–56 (2020). https://doi.org/10.1016/j.esd.2020.05.003
C. Rosiles-Perez, S. Sidhik, L. Ixtilico-Cortés, F. Robles-Montes, T. López-Luke, A.E. Jiménez-González, High short-circuit current density in a non-toxic Bi2S3 quantum dot sensitized solar cell. Mater. Today Energy (2021). https://doi.org/10.1016/j.mtener.2021.100783
Y. Zhang et al., A ‘tips and Tricks’ practical guide to the synthesis of metal halide perovskite nanocrystals. Chem. Mater. 32(13), 5410–5423 (2020). https://doi.org/10.1021/acs.chemmater.0c01735
H. Zhao, F. Rosei, Colloidal quantum dots for solar technologies. Chemistry 3(2), 229–258 (2017). https://doi.org/10.1016/j.chempr.2017.07.007
L. Protesescu et al., Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I): novel optoelectronic materials showing bright emission with wide color gamut. Nano Lett. 15(6), 3692–3696 (2015). https://doi.org/10.1021/nl5048779
H. Wu, J. Pi, D. Zhou, Q. Wang, Z. Long, J. Qiu, Effect of cation vacancy on lattice and luminescence properties in CsPbBr 3 quantum dots. Ceram Int 48(3), 3383–3389 (2022). https://doi.org/10.1016/j.ceramint.2021.10.114
T. Ma, S. Wang, Y. Zhang, K. Zhang, L. Yi, The development of all-inorganic CsPbX3 perovskite solar cells. J. Mater. Sci. 55(2), 464–479 (2020). https://doi.org/10.1007/s10853-019-03974-y
D. Ghosh, M.Y. Ali, D.K. Chaudhary, S. Bhattacharyya, Dependence of halide composition on the stability of highly efficient all-inorganic cesium lead halide perovskite quantum dot solar cells. Sol. Energy Mater. Sol. Cells 185, 28–35 (2018). https://doi.org/10.1016/j.solmat.2018.05.002
M.P. Montoya et al., Study of inverted planar CH3NH3PbI3 perovskite solar cells fabricated under environmental conditions. Sol. Energy 180, 594–600 (2019). https://doi.org/10.1016/j.solener.2019.01.061
A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka, Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 131(17), 6050–6051 (2009). https://doi.org/10.1021/ja809598r
A. Herez, H. el Hage, T. Lemenand, M. Ramadan, M. Khaled, Review on photovoltaic/thermal hybrid solar collectors: Classifications, applications and new systems. Sol. Energy 207, 1321–1347 (2020). https://doi.org/10.1016/j.solener.2020.07.062
M. Shekhirev, J. Goza, J.D. Teeter, A. Lipatov, A. Sinitskii, Synthesis of cesium lead halide perovskite quantum dots. J. Chem. Educ. 94(8), 1150–1156 (2017). https://doi.org/10.1021/acs.jchemed.7b00144
S. Panigrahi, S. Jana, T. Calmeiro, D. Nunes, R. Martins, E. Fortunato, Imaging the anomalous charge distribution inside CsPbBr 3 perovskite quantum dots sensitized solar cells. ACS Nano 11(10), 10214–10221 (2017). https://doi.org/10.1021/acsnano.7b04762
J. Chen, D. Liu, M.J. Al-Marri, L. Nuuttila, H. Lehtivuori, K. Zheng, Photo-stability of CsPbBr 3 perovskite quantum dots for optoelectronic application. Sci China Mater 59(9), 719–727 (2016). https://doi.org/10.1007/s40843-016-5123-1
H. Yu et al., Green light-emitting devices based on perovskite CsPbBr 3 quantum dots. Front Chem (2018). https://doi.org/10.3389/fchem.2018.00381
F. Xu et al., Quantum size effect and surface defect passivation in size-controlled CsPbBr 3 quantum dots. J Alloys Compd (2020). https://doi.org/10.1016/j.jallcom.2020.154834
A. Swarnkar, R. Chulliyil, V.K. Ravi, M. Irfanullah, A. Chowdhury, A. Nag, Colloidal CsPbBr 3 perovskite nanocrystals: Luminescence beyond traditional quantum dots. Angew. Chem. Int. Edn. 54(51), 15424–15428 (2015). https://doi.org/10.1002/anie.201508276
H. Chen, A. Guo, J. Zhu, L. Cheng, Q. Wang, Tunable photoluminescence of CsPbBr 3 perovskite quantum dots for their physical research. Appl. Surf. Sci. 465, 656–664 (2019). https://doi.org/10.1016/j.apsusc.2018.08.211
J. Chaudhary, R. Gautam, S. Choudhary, A.S. Verma, Inverted-heterostructure based device of CH3NH3PbBr 3for Schottky photodiode. EPJ Appl. Phys. (2019). https://doi.org/10.1051/epjap/2019190023
D. Kumar, J. Chaudhary, S. Kumar, S.R. Bhardwaj, M. Yusuf, A.S. Verma, Investigation of methylammonium lead bromide hybrid perovskite based photoactive material for the photovoltaic applications. Digest J. Mater. Nanostr. 16, 205–215 (2021)
B. Li et al., Pathways toward high-performance inorganic perovskite solar cells: Challenges and strategies. J. Mater. Chem. A 7(36), 20494–20518 (2019). https://doi.org/10.1039/c9ta04114a
A. Agrawal, S. Ahmed Siddiqui, A. Soni, G. D. Sharma, Device Modeling and Characteristics of Solution Processed Perovskite Solar Cell at Ambient Conditions, 2020. http://www.springer.com/series/7818
X. Zhang et al., α-CsPbBr 3 perovskite quantum dots for application in semitransparent photovoltaics. ACS Appl. Mater. Interfaces 12(24), 27307–27315 (2020). https://doi.org/10.1021/acsami.0c07667
S. Sidhik, C. Rosiles Pérez, M.A. Serrano Estrada, T. López-Luke, A. Torres, E. de la Rosa, Improving the stability of perovskite solar cells under harsh environmental conditions. Sol. Energy 202, 438–445 (2020). https://doi.org/10.1016/j.solener.2020.03.034
Acknowledgments
The authors would like to thank Ph.D. Scholarship from 2020-CONACYT, 2019 UC MEXUS-CONACYT Collaborative grants, Program Postdoctoral Stays for Mexico 2021-CONACYT, Instituto de Investigación en Metalurgia y Materiales from Universidad Michoacana de San Nicolás de Hidalgo, and CIC-UMSNH 2022.
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Ramírez-Ferreira, H.O., Aguilar, M.S., Zarazúa, I. et al. Synthesis and characterization of cesium lead bromide perovskite quantum dots with photovoltaic applications. MRS Advances 7, 1175–1179 (2022). https://doi.org/10.1557/s43580-022-00386-0
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DOI: https://doi.org/10.1557/s43580-022-00386-0