Abstract
Results of an investigation of the intercalation potential of polyethylene glycol (PEG) with synthetic and pre-treated C-S-H are reported. The partial intercalation of PEG molecules in the interlayer of C-S-H is discussed. The effective and strong interaction of PEG molecules with the C-S-H surface was shown using XRD, 13C CP and 29Si MAS NMR, and DTGA. The position and character of the 002 low angle XRD peak of C-S-H are affected by drying procedures and concomitant chemical treatment preceding intercalation and the reaction temperature. Recovery of the initial 002 position after severe drying and intercalation with distilled water or PEG is incomplete but is accompanied by an increase in intensity. It is inferred that the stability of C-S-H binders in concrete can be impacted by a variation in nanostructure dependent on curing temperature and use of chemical admixtures.
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References
Brown PW, Taylor HFW (2000) The role of ettringite in external sulfate attack. In: Marchand J, Skalny JP (eds) Materials science of concrete: special volume on sulfate attack mechanisms. American Ceramic Society, Westerville, p 73
Marchand J (2001) Modeling the behavior of unsaturated cement systems exposed to aggressive chemical environments. Mater Struct 34:195–200. doi:10.1007/BF02480588
Taylor HFW, Famy C, Scrivener K (2001) Delayed ettringite formation. Cement Concr Res 31:683–693. doi:10.1016/S0008-8846(01)00466-5
Litvan GG (1980) Volume stability of porous solids. Part I. In: Proceedings of the 7th international congress on chemistry of cement, Paris, France, vol 3, pp VII-46-VII-46-VII-50
Raussell-Colom JA, Serraiosa MJ (1987) In: Newman ACD (ed) Chemistry of clays and clay minerals. Mineralogical Society, London, p 371
Pinnavaia TJ (1983) Intercalated clay catalysts. Science 220(4595):365–371
Okada A, Kawasumi M, Usuki AA, Kojima Y, Kurauchi T, Kamigaito O (1990) Synthesis and properties of nylon-6/clay hybrids. In: Schaefer DW, Mark JE (eds) Proceedings MRS symposium on polymer-based molecular composites, vol 171, pp 45–50
Vaia RA, Price G, Ruth PN, Nguyen HT, Lichtenhan J (1999) Polymer/layered silicate nanocomposites as high performance ablative materials. Appl Clay Sci 15:67–92. doi:10.1016/S0169-1317(99)00013-7
Biswas M, Sinha RS (2001) Recent progress in synthesis and evaluation of polymer-montmorillonite nanocomposites. Adv Polym Sci 155:167–221. doi:10.1007/3-540-44473-4_3
Sinha RS, Yamada K, Okamoto M, Ueda K (2002) New polylactide/layered silicate nanocomposite: a novel biodegradable material. Nano Lett 2:1093–1096. doi:10.1021/nl0202152
Van Olphen H (1977) An introduction to clay and colloid chemistry. Wiley, New York, p 318
Tunney JJ, Detellier C (1993) Interlammellar covalent grafting of organic units on kaolinite. Chem Mater 5:747–748. doi:10.1021/cm00030a002
Tunney JJ, Detellier C (1994) Preparation and characterization of an 8.4 Å hydrate kaolinite. Clays Clay Miner 42:552–560. doi:10.1346/CCMN.1994.0420506
Velde B (1992) Introduction to clay minerals, 1st edn. Chapman and Hall, London, p 195
Dosch W (1966) Interlamellar reaction of tetracalcium aluminate hydrates with water and organic compounds. In: Proceedings of the 15th national conference on clay and clay minerals, Pittsburgh, PA, pp 273–292
Terisse VH, Nonat A, Petit CJ (2001) Zeta potential study of calcium silicate hydrates interacting with alkaline cations. J Colloid Interface Sci 244:58–65. doi:10.1006/jcis.2001.7897
Richardson GI (2004) Tobermorite/jennite and tobermorite/calcium hydroxide-based models for the structure of C-S-H: applicability to hardened pastes of tricalcium silicate, β-dicalcium silicate, Portland cement and blends of Portland cement with blast furnace slag, metakaolin or silica fume. Cement Concr Res 34:1733–1777. doi:10.1016/j.cemconres.2004.05.034
Alizadeh R, Beaudoin JJ, Raki L (2007) C-S-H(I)—a nanostructural model for the removal of water from hydrated cement paste. J Am Ceram Soc 90:670–672. doi:10.1111/j.1551-2916.2006.01459.x
Allen AJ, Thomas JJ, Jennings H (2007) Composition and density of nanoscale calcium-silicate-hydrate in cement. Nat Mater 6:311–316. doi:10.1038/nmat1871
Feldman RF, Sereda PJ (1970) The new model for hydrated Portland cement and its practical implications. Engl J 53:53–57
Taylor HFW (1990) Cement chemistry. Academic Press, London, p 475
Hamid SA (1981) The crystal structure of the 11 Å tobermorite Ca2.25[Si3O7.5(OH)1.5] · 1H2O. Z Kristallogr 154:189–198
Feldman RF, Sereda PJ (1968) A model for hydrated Portland cement paste as deduced from sorption-length change and mechanical properties. Materiaux Constr 1:509–520. doi:10.1007/BF02473639
Beaudoin JJ (1999) Why engineers need materials science. Concr Int 21:86–89
Van Olphen H (1997) An introduction to clay colloid chemistry, 2nd edn. Wiley, New York, p 318
Mcbride MB (1994) Environmental chemistry of soils. Oxford University Press, Oxford, p 416
Velde B (1992) Introduction to clay minerals: chemistry, origins, uses and environmental significances, 1st edn. Chapman and Hall, London, p 195
Newman ACD (1987) Chemistry of clays and clay minerals. Monograph No. 6, Mineralogical Society, p 480
Luckham PF, Rossi S (1999) The colloidal and rheological properties of bentonite suspensions. Adv Colloid Interface Sci 82:43–92. doi:10.1016/S0001-8686(99)00005-6
Deuel H (1952) Organic derivatives of clay minerals. Clay Miner Bull 1:205–214. doi:10.1180/claymin.1952.001.7.04
Deuel H (1959) Reaktionen von silikaten mit organischen verbindungen. Makromol Chem 34:206–215. doi:10.1002/macp.1959.020340113
Evans B, White TE (1968) Adsorption and reaction of methylchlorosilane at an ‘Aerosil’ surface. J Catal 11:336–341. doi:10.1016/0021-9517(68)90056-0
Yanagisawa T, Kuroda K, Kato C (1988) Organic derivatives of layered polysilicates I. Trimethylsilylation of magadite and kenyaite. React Solids 5:167–175. doi:10.1016/0168-7336(88)80085-8
Vaia RA, Ishii H, Giannelis EP (1993) Synthesis and properties of two dimensional nanostructures by direct intercalation of polymer melts in layered silicates. Chem Mater 5:1694–1696. doi:10.1021/cm00036a004
Arnanda P, Ruitz-Hitzky E (1992) Poly(ethyleneoxide)-silicate intercalation materials. Chem Mater 4:1395–1413. doi:10.1021/cm00024a048
Lagaly G, Fernadez M, Weiss A (1976) Problems in layers-charge determination of montmorillonite. Clays Clay Miner 50:435–445
Jaynes WF, Boyd SA (1991) Clay minerals type and organic compound sorption by hexadecyletrymethyl-ammonium exchanged clays. Soil Sci Soc Am J 55:43–48
MacEwen DMC (1984) Complexes of clays with organic compounds: 1. Complex formation between montmorillonite and halloysite and certain organic liquids. Trans Faraday Soc 44:349–367. doi:10.1039/tf9484400349
Weiss A (1963) Organic derivatives of mica-type layer silicates. Angew Chem Int Ed Engl 2:134–144. doi:10.1002/anie.196301341
Wang Z, Lan T, Pinnavaia J (1996) Hybrid organic-inorganic nanocomposites formed from an epoxy polymer and a layered silicic acid (magadrite). Chem Mater 8:2200–2204. doi:10.1021/cm960263l
Sugahara Y, Sugimoto M, Yanagisawa T, Nomizu Y, Kuroda K, Kato CJ (1987) The preparation of magadite-polyacrylonitrite intercalation compound and its conversion to silicon carbide. J Ceram Soc Jpn 95:117–123
Wang Z, Lan T, Pinnavaia TJ (1998) Hybrid organic-inorganic nanocomposites: exfoliation of magadite nanolayers in an elastomeric epoxy polymer. Chem Mater 10:1820–1826. doi:10.1021/cm970784o
Blumstein A (1965) Polymerization of adsorbed monolayers: II Thermal degradation of the inserted polymers. J Polym Sci A 3:2665–2673. doi:10.1002/pol.1965.100030721
Krishnamoorti R, Vaia RA, Giannelis EP (1996) Structure and dynamics of polymer-layered silicate nanocomposites. Chem Mater 8:1728–1734. doi:10.1021/cm960127g
Sinha RS, Okamoto K, Okamoto M (2003) Structure property relationship in biodegradable poly (butylene succinate)/layered silicate nanocomposites. Macromolecules 36:2355–2367. doi:10.1021/ma021728y
Dramé H, Beaudoin JJ, Raki L (2007) Structure property relationship in biodegradable poly (butylene succinate)/layered silicate nanocomposites. J Mater Sci 42:6846–6848. doi:10.1007/s10853-006-1328-5
Taylor HFW (1986) Proposed structure of calcium silicate gel. J Am Ceram Soc 69(6):464–467. doi:10.1111/j.1151-2916.1986.tb07446.x
Cong X, Kirkpatrick RJ (1995) Effects of the temperature and relative humidity on the structure of C-S-H gel. Cement Concr Res 25:1237–1245. doi:10.1016/0008-8846(95)00116-T
Raupach M, Barron PF, Thompson JG (1987) Nuclear Magnetic Resonance, Infrared and X-ray powder diffraction study of dimethylsulfoxide and dimethylselenoxide intercalates with kaolinite. Clays Clay Miner 35:208–219. doi:10.1346/CCMN.1987.0350307
Thompson JG, Cuff C (1985) Crystal structure of kaolinite: dimethylsulfoxide intercalate. Clays Clay Miner 33:490–500. doi:10.1346/CCMN.1985.0330603
Alemany LB, Grant DM, Alger TD, Pugmire RJ (1983) Cross-polarization and magic angle spinning NMR spectra of model organic compounds 3. Effect of 13C-1H dipolar interaction on cross-polarization and carbon proton dephasing. J Am Chem Soc 105:6697–6704. doi:10.1021/ja00360a025
Opella SJ, Frey MH (1979) Selection of protonated carbon resonances in solid state nuclear magnetic resonance. J Am Chem Soc 101:5954–5956
Ripmeester JA, Burlinson NE (1985) Chiral discrimination and solid state 13C NMR. Application to tri-o-thymotide clathrates. J Am Chem Soc 107:3713–3714. doi:10.1021/ja00298a049
Franceschini A, Abramson S, Bresson B, Vandamme H, Lequeux N (2007) Cement-silylated polymers nanocomposites. In: Proc. 12th Int. Cong. Chem. Cem. Theme ST5, Montreal, July 08–13, 2007
Matsuyama H, Young JF (1999) Intercalation of polymers in calcium silicate hydrate: a new synthetic approach to biocomposites. Chem Mater 11:16–19. doi:10.1021/cm980549l
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Beaudoin, J.J., Dramé, H., Raki, L. et al. Formation and properties of C-S-H–PEG nano-structures. Mater Struct 42, 1003–1014 (2009). https://doi.org/10.1617/s11527-008-9439-x
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DOI: https://doi.org/10.1617/s11527-008-9439-x