日本レオロジー学会誌
Online ISSN : 2186-4586
Print ISSN : 0387-1533
ISSN-L : 0387-1533
界面活性剤紐状ミセル水溶液の粘弾性挙動
―添加物の効果1―
今井 真一郎國本 栄起四方 俊幸
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2000 年 28 巻 2 号 p. 61-65

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The effects of additives in aqueous threadlike micellar systems formed with cetyltrimethylammonium bromide (CTAB) were studied by means of dynamic viscoelastic and 1H-NMR techniques. An additive used was an ionic aromatic compound, sodium p-toluenesulfonate (NapTS). Viscoelastic behaviors of an aqueous CTAB and NapTS system essentially agreed with those of an aqueous system sodium salicylate (NaSal). When a ratio of NapTS concentration (CS) to CTAB concentration (CD) was higher than unity, the CTAB:NapTS/W system possessed the single relaxation viscoelasticity. The longest relaxation times (τm) depended on the concentration (CS*) of NapTS in the bulk aqueous phase, whereas τm was independent of CD.

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