Skip to main content
Log in

Flow Injection Determination of Iron Ions with Green Tea Extracts as a Natural Chromogenic Reagent

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

A green chemistry system that utilizes natural extract as an alternative reagent for determination of metal ions has been investigated. The extract of green tea, a common beverage, is used for quantification of iron. The green tea extract was prepared in acetate buffer pH 4.8 and could be used without further purification with a simple flow injection (FI) system. The intensity of iron-green tea extract complexes was monitored using a green LED photometer. The use of natural reagent combined with the simple FI-LED photometer set up offers an alternative low cost and rapid system for the determination of metal ions. Detection limit of 0.05 ppm of Fe(III) ion and sampling rate of 180 injections h−1 were achieved. Application of this system to the analysis of iron in pharmaceutical samples was demonstrated, and the results agreed well with those from the AOAC method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. P. T. Anastas, Crit. Rev. Anal. Chem., 1999, 29, 167.

    Article  CAS  Google Scholar 

  2. S. Armenta, S. Garrigues, and M. de la Guardia, TrAC, 2008, 27, 497.

    CAS  Google Scholar 

  3. S. Gao, G. Tan, H. Yuan, D. Xiao, and M. F. Choi, Microchim. Acta, 2006, 153, 159.

    Article  CAS  Google Scholar 

  4. I. R. W. Z. de Oliveira and I. C. Vieira, Enzyme Microb. Technol., 2006, 38, 449.

    Article  Google Scholar 

  5. T. Settheeworrarit, S. K. Hartwell, S. Lapanatnoppakhun, J. Jakmunee, G. D. Christian, and K. Grudpan, Talanta, 2005, 68, 262.

    Article  CAS  PubMed  Google Scholar 

  6. K. Grudpan, Talanta, 2004, 64, 1084.

    Article  CAS  PubMed  Google Scholar 

  7. O. Fatibello-Filho and I. da Cruz Vieira, Anal. Chim. Acta, 1997, 354, 51.

    Article  CAS  Google Scholar 

  8. F. V. Silva, A. R. A. Nogueira, G. B. Souza, B. F. Reis, A. N. Araújo, M. C. M. B. S. Montenegro, and J. L. F. C. Lima, Talanta, 2000, 53, 331.

    Article  CAS  PubMed  Google Scholar 

  9. N. Khan and H. Mukhtar, Life Sci., 2007, 81, 519.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  10. J. Frank, T. W. George, J. K. Lodge, A. M. Rodriguez-Mateos, J. P. E. Spencer, A. M. Minihane, and G. Rimbach, J. Nutr., 2009, 139, 58.

    Article  CAS  PubMed  Google Scholar 

  11. P. D. B. Ribaldo, D. S. Souza, S. K. Biswas, K. Block, J. M. Lopes de Faria, and J. B. Lopes de Faria, J. Nutr., 2009, 139, 96.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  12. M. R. Sartippour, R. Pietras, D. C. Marquez-Garban, H. W. Chen, D. Heber, S. M. Henning, G. Sartippour, L. Zhang, M. Lu, O. Weinberg, J. Y. Rao, and M. N. Brooks, Carcinogenesis, 2002, 27, 2424.

    Article  Google Scholar 

  13. P. Ryan and M. J. Hynes, J. Inorg. Biochem., 2007, 101, 585.

    Article  CAS  PubMed  Google Scholar 

  14. M. J. Hynes and M. Ó. Coinceanainn, J. Inorg. Biochem., 2001, 85, 131.

    Article  CAS  PubMed  Google Scholar 

  15. M. Elhabiri, C. Carër, F. Marmolle, and H. Traboulsi, Inorg. Chim. Acta, 2007, 360, 353.

    Article  CAS  Google Scholar 

  16. S. Khokhar and R. K. O. Apenten, Food Chem., 2003, 81, 133.

    Article  CAS  Google Scholar 

  17. C. S. Yang, Nutrition, 1999, 15, 946.

    Article  CAS  PubMed  Google Scholar 

  18. C. S. Yang and J. M. Landau, J. Nutr., 2000, 130, 2409.

    Article  CAS  PubMed  Google Scholar 

  19. S. Somnam, K. Grudpan, and J. Jakmunee, Mj. Int. J. Sci. Tech., 2008, 2, 172.

    CAS  Google Scholar 

  20. N. Schweigert, A. J. B. Zehnder, and R. I. L. Eggen, Environ. Microbiol., 2001, 3, 81.

    Article  CAS  PubMed  Google Scholar 

  21. P. Cunniff, “Official Methods of Analysis of AOAC International”, 16th, 1995, Vol. 1, Chap. 18, AOAC International, Gaitherburg, 11.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Supaporn Kradtap Hartwell.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pinyou, P., Hartwell, S.K., Jakmunee, J. et al. Flow Injection Determination of Iron Ions with Green Tea Extracts as a Natural Chromogenic Reagent. ANAL. SCI. 26, 619–623 (2010). https://doi.org/10.2116/analsci.26.619

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.26.619

Navigation