Abstract
Chelating resins containing a macrocyclic ligand, 1,4,8, 11-tetraazacyclotetradecane-5,7-dione, were prepared by ligand reactions with two different crosslinked copolymer beads of the macroreticular type: chloromethylated styrene-divinylbenzene (RCS) and glycidyl methacrylate-divinylbenzene (RG) copolymers. Although both resins have nearly equal amounts of the fixed ligand, the RG-based resin (RGD) shows a much higher uptake of Cu(II) than does the RCS-based resin (RCSD). This indicates that the complexing ability of the fixed ligand is strongly influenced by copolymer matrices. A further detailed study of RGD revealed that the characteristics of RGD include high selectivity toward Cu(II) and a rapid elution rate of Cu(II) with an aqueous solution of strong acid. The usefulness of RGD in the separation of Cu(II) has been demonstrated by means of column operation.
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References
M. Kodatna and E. Kimura, J. Chem. Soc, Dalton Trans., 1979, 325.
M. Kodama, T. Yatsunami and E. Kimura, J. Chem. Soc, Dalton Trans., 1979, 1783.
K. Ishizu, J. Hirai, M. Kodama and E. Kimura, Chem. Lett., 1979, 1045.
M. Kodama and E. Kimura, J. Chem. Soc, Dalton Trans., 1981, 694.
R. Machida, E. Kimura and M. Kodama, Inorg. Chem., 22, 2055.
E. Kimura, T. Koike, R. Machida, R. Nagai and M. Kodama, Inorg. Chem., 23, 4181 (1984).
E. Kimura, R. Machida and M. Kodama, J. Am. Chem. Soc, 106, 5497.
E. Kimura, C. A. Dalimunte, A. Yamashita and R. Machida, J. Chem. Soc, Chem. Commun., 1985, 1041.
E. Kimura, Y. Lin, R. Machida and H. Zenda, J. Chem. Soc, Chem. Commun. 1986, 1020.
T. Kumamaru, Y. Nitta, H. Matsuo and E. Kimura, Bull. Chem. Soc. Jpn., 60, 1930.
E. Kimura, S. Korenari, M. Shionoya and M. Shiro, J. Chem. Soc, Chem. Commun., 1988, 1166.
E. Kimura, Y. Kurogi and T. Takahashi, Inorg. Chem., 30, 4117(1991).
L. Fabbrizzi and A. Poggi, J. Chem. Soc, Chem. Commun., 1980, 646.
L. Fabbrizzi, A. Perotti and A. Poggi, Inorg. Chem., 22, 1411(1983).
L. Fabbrizzi, F. Forlini, A. Perotti and B. Seghi, Inorg. Chem., 23, 807 (1984).
R. W. Hay, M. P. Pujari and F. Mclaren, Inorg. Chem., 23, 3033 (1984).
A. Buttafava, L. Fabbrizzi, A. Perotti, A. Poggi and B. Seghi, Inorg. Chem., 23, 3917 (1984).
M. D. Casa, L. Fabbrizzi, A. Perotti, A. Poggi and P. Tundo, Inorg. Chem., 24, 1610.
L. Fabbrizzi, T. A. Kaden, A. Perotti, B. Seghi and L. Siegfried, Inorg. Chem., 25, 321 (1986).
A. Marchi, R. Rossi, L. Magon, A. Duatti, U. Casellato, R. Graziani, M. Vidal and F. Riche, J. Chem. Soc, Dalton Trans., 1990, 1935.
H. Kato, Doctoral Thesis, Kyushu University, 1977, Chapter 2.
I. Tabushi, H. Kato, Y. Taniguchi and Y. Kuroda, Japan Patent Application 24884 (1977); [Chem. Abstr., 89, 215451w (1978)].
Private communication, I. Tabushi, Sept. 2, 1986.
I. Tabushi, Y. Taniguchi and H. Kato, Tetrahedron Lett, 1977, 1049.
H. Egawa, T. Nonaka and H. Maeda, Nippon Kagaku Kaishi, 1979, 1756.
H. Egawa, T. Nonaka and H. Maeda, J. Appl. Polym. Sci., 30, 3239 (1985).
A. Buttafava, L. Fabbrizzi, A. Perotti and B. Seghi, J. Chem. Soc, Chem. Commun., 1982, 1166.
Y. Ishikawa, K. Tajima, K. Mukai, O. Ochi, K. Ishizu and H. Sakurai, Chem. Lett., 1984, 813.
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Jyo, A., Hiwatashi, I., Weber, R. et al. Chelating Resins Containing 1,4,8,11-Tetraazacyclotetradecane-5,7-dione Based on Crosslinked Copolymer Beads of the Macroreticular Type. ANAL. SCI. 8, 195–200 (1992). https://doi.org/10.2116/analsci.8.195
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DOI: https://doi.org/10.2116/analsci.8.195