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A Kinetic Study of Copper Ion Extraction by P50 at the Oil-Water Interface

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Abstract

Data for the kinetics of Cu(II) extraction by P50 (5-nonyl-2-hydroxybenzaldoxime) obtained from the total internal reflectance (TIR) static transfer cell is presented. An interfacial mechanism involving two pararell initial addition steps is proposed and forward rate constants determined. These are discussed in relation to other data available for this system and clearly indicate further work is required in the identification of more general reaction mechanisms.

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References

  1. R. F. Dalton, The Canadian Mining and Metallurgical Bulletin, Special Volume ISEC 40 (1977).

    Google Scholar 

  2. J. Szymanowski, “Hydroxyoximes and Copper Hydro-metallurgy”, CRC Press, Boca Raton, 1993.

    Google Scholar 

  3. I. Komasawa, T. Otaka and T. Muraoka, J. Chem. Eng. Jpn., 13, 204 (1980).

    Article  CAS  Google Scholar 

  4. S. P. Carter and H. Freiser, Anal. Chem., 52, 511 (1980).

    Article  CAS  Google Scholar 

  5. J. D. Miller and R. L. Atwood, J. Inorg. Nucl. Chem., 37, 2539 (1975).

    Article  CAS  Google Scholar 

  6. D. S. Flett, D. N. Okuhara and D. R. Spink, J. Inorg. Nucl. Chem., 35, 2471 (1973).

    Article  CAS  Google Scholar 

  7. H. Watarai and K. Satoh, Langmuir, 10, 3913 (1994).

    Article  CAS  Google Scholar 

  8. W. J. Albery, R. A. Choudhery and P. R. Fisk, Faraday Discuss. Chem. Soc., 77, 53 (1984).

    Article  Google Scholar 

  9. W. J. Albery and R. A. Choudhery, J. Phys. Chem., 92, 1142 (1988).

    Article  CAS  Google Scholar 

  10. M. J. Nicol, J. S. Preston, J. A. Ramsden and M. Mooiman, Hydrometallurgy, 14, 83 (1985).

    Article  CAS  Google Scholar 

  11. J. M. Pratt and R. L. Tilley, Hydrometallurgy, 5, 29 (1985).

    Article  Google Scholar 

  12. W. Richmond, C. Tondre, E. Krzyzanowska and J. Szymanowski, J. Chem. Soc. Faraday Trans., 91, 657 (1995).

    Article  CAS  Google Scholar 

  13. R. Cierpiszewski, M. Hebrant, J. Szymanowski and C. Tondre, J. Chem. Soc. Farady Trans., 92, 249 (1996).

    Article  CAS  Google Scholar 

  14. J. M. Perera, J. K. McCulloch, B. S. Murray, F. Grieser and G. W. Stevens, Langmuir, 8, 366 (1992).

    Article  CAS  Google Scholar 

  15. J. K. McCulloch, D. Formasiero, J. M. Perera, B. S. Murray, G. W. Stevens and F. Grieser, J. Colloid Interface Sci., 157, 180 (1993).

    Article  CAS  Google Scholar 

  16. J. M. Perera, G. W. Stevens and F. Grieser, Colloids Surfaces A, 95, 185 (1995).

    Article  CAS  Google Scholar 

  17. J. K. McCulloch, J. M. Perera, F. Grieser and G. W. Stevens, Value Adding Through Solvent Extraction, Proceedings of the International Solvent Extraction Conference (ISEC ’96), Vol. II, p.1561.

  18. J. K. McCulloch, J. M. Perera, E. D. Kelly, L. R. White, G. W. Stevens and F. Grieser, J. Colloid Interface Sci., 184, 406 (1996).

    Article  CAS  Google Scholar 

  19. J. K. McCulloch, E. D. Kelly, J. M. Perera, L. R. White, G. W. Stevens and F. Grieser, J. Colloid Interface Sci., 184, 399 (1996).

    Article  CAS  Google Scholar 

  20. A. Hokura, J. M. Perera, F. Grieser and G. W. Stevens, Solvent Extr. Ion Exchange, in press.

  21. R. Price and J. A. Tumilty, “I Chem. E. Sysmposium Series”, No. 42, 1971.

    Google Scholar 

  22. M. A. Hughes, P. D. Middlebrook and R. J. Whewell, J. Inorg. Nucl. Chem., 39, 1679 (1977).

    Article  CAS  Google Scholar 

  23. P. W. Atkins, “Physical Chemistry”, 2nd ed, Oxford University Press, Oxford, 1986.

    Google Scholar 

  24. A. J. van der Zeeuw, Hydrometallurgy, 17, 295 (1987).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, University of Melbourne, Parkville, Victoria, 3052, Australia

    Meri Yamada, Jilska M. Perera & Geoffrey W. Stevens

  2. School of Chemistry, University of Melbourne, Parkville, Victoria, 3052, Australia

    Franz Grieser

  3. Department of Chemistry, Science University of Tokyo, Kagurazaka, Shinkuku, Tokyo, 162, Japan

    Meri Yamada

Authors
  1. Meri Yamada
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  2. Jilska M. Perera
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  3. Franz Grieser
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  4. Geoffrey W. Stevens
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Yamada, M., Perera, J.M., Grieser, F. et al. A Kinetic Study of Copper Ion Extraction by P50 at the Oil-Water Interface. ANAL. SCI. 14, 225–229 (1998). https://doi.org/10.2116/analsci.14.225

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  • DOI: https://doi.org/10.2116/analsci.14.225

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