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Adsorption Behavior of Divalent Metal Ions onto Surface-functionalized Mesoporous Silicate MCM-41 Having Schiff Base Structure

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Abstract

Surface functionalized mesoporous silicates, MCM-41s, having 3-(2-pyridylmethylideneimino)propyl group (PI-MCM-41) or 3-(2-quinolylmethylideneimino)propyl group (QI-MCM-41) were prepared via Schiff base reaction, and the adsorption behavior of metal ions onto the modified MCM-41s was investigated. The function groups on the modified MCM-41 surface were confirmed by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and elemental analysis. The metal ions examined, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, and Pb2+, were quantitatively adsorbed on the PI-MCM-41 and QI-MCM-41, except for Mn2+. In the complexation with these metal ions, it was suggested that imine-N and heterocyclic-N atoms act as donor atoms. In addition, it was considered that the hydrophobicity derived from the organo-functional groups modified on MCM-41 contributed to improving the adsorption ability.

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Authors and Affiliations

  1. College of Bioscience and Chemistry, Kanazawa Institute of Technology, Ishikawa, 921-8501, Japan

    Syunichi Oshima, Takushi Matsuno, Kenta Takasawa, Kaoru Fujinaga & Yu Komatsu

  2. Technology Planning Div., Nomura Micro Science Co., Ltd., Kanagawa, 243-0021, Japan

    Hidekazu Ohinata

  3. Faculty of Bioscience and Applied Chemistry, Hosei University, Tokyo, 184-8584, Japan

    Yujiro Watanabe

  4. Department of Chemical Engineering, The University of Melbourne, Victoria, 3010, Australia

    Geoffrey W. Stevens

Authors
  1. Syunichi Oshima
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  2. Hidekazu Ohinata
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  3. Takushi Matsuno
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  4. Kenta Takasawa
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  5. Yujiro Watanabe
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  6. Kaoru Fujinaga
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  7. Geoffrey W. Stevens
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  8. Yu Komatsu
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Correspondence to Syunichi Oshima.

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Oshima, S., Ohinata, H., Matsuno, T. et al. Adsorption Behavior of Divalent Metal Ions onto Surface-functionalized Mesoporous Silicate MCM-41 Having Schiff Base Structure. ANAL. SCI. 37, 613–617 (2021). https://doi.org/10.2116/analsci.20P090

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  • DOI: https://doi.org/10.2116/analsci.20P090

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