To detect the amount of Oxygen (O2), existing in conventional incandesent lamps as impurity, we have investigated light spectra with discharging them. The total pressure is 93000 Pa (Ar90%, N210%) and O2 content is iess than 250PPM.
Though any significant dependence of spectrum decaytime on the O2 content is not found from Ar and N2 gas, large dependence on the O2 is found from O (1S) Ar excimer formed in the discharge, i. e., while 02 content is less than 50 PPM, R (R; attenuation constant [1/sec]) of the spectrum from the excimer increases in proportion to O2 content. The measured decaytime fits a calculaion using the equation of Welge and Atkinson. While O2 content becomes more than 50 PPM, R increases with the third power of O2 content. The reason of this higher rate may be related to production of 03.
With checking time dependent behaviour of the excimer spectrum, it becomes possible to detect the amount of O2 in conventional incandescent lamps without destruction of envelopes.