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Title: A process for determining radiohalogens

Technical Report ·
DOI:https://doi.org/10.2172/142508· OSTI ID:142508

Techniques for the separation and potential determination of chlorine-36 and iodine-129 were examined. Separation was based upon addition to the carbon-carbon double bond in 1-hexene. These specific organic halides formed an acceptable liquid scintillation counting cocktail with chlorine but not with iodine. The miscibility of 1,2-dichlorohexane should allow a larger mass of sample in a scintillation cocktail, lowering the detection limit of the determination of chlorine-36. Organic halides are also expected to be more receptive to waste treatment than metals such as silver. These techniques offer the potential for determination of chlorine-36 in groundwater samples while producing less mixed waste than current analytical techniques.

Research Organization:
Westinghouse Idaho Nuclear Co., Inc., Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC07-84ID12435
OSTI ID:
142508
Report Number(s):
WINCO-1169; ON: DE94008805; TRN: 94:006559
Resource Relation:
Other Information: PBD: Dec 1993
Country of Publication:
United States
Language:
English