doiSerbia

Catalytic growth of carbon nanotubes with large inner diameters

Yan JU. (Nanchang University - Department of Chemistry, Nanchang, China)
Feng LI.YI. (Nanchang University - Department of Chemistry, Nanchang, China)
Zhong Ren Wei (Nanchang University - Department of Chemistry, Nanchang, China)

Carbon nanotubes (2.4 g/g catalyst), with large inner diameters were successfully synthesized through pyrolysis of methane on a Ni-Cu-Al catalyst by adding sodium carbonate into the carbon nanotubes growth system. The inner diameter of the carbon nanotubes prepared by this method is about 20-60 nm, while their outer diameter is about 40-80 nm. Transmission electron microscopy and X-ray diffraction were employed to investigate the morphology and microstructures of the carbon nanotubes. The analyses showed that these carbon nanotubes have large inner diameters and good graphitization. The addition of sodium carbonate into the reaction system brings about a slight decrease in the methane conversion and the yield of carbon. The experimental results showed that sodium carbonate is a mildly toxic material which influenced the catalytic activity of the Ni-Cu-Al catalyst and resulted in the formation of carbon nanotubes with large inner diameters. The growth mechanism of the carbon nanotubes with large inner diameters is discussed in this paper.

Keywords: carbon nanotubes, Ni-Cu-Al catalyst, pyrolysis