鉄と鋼
Online ISSN : 1883-2954
Print ISSN : 0021-1575
ISSN-L : 0021-1575
クヌーセン・セル質量分析法による溶融Fe-P-Si, Al, Ti, V, Cr, Co, Ni, NbおよびMo中のりんの活量の測定
山田 啓作加藤 栄一
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ジャーナル フリー

1979 年 65 巻 2 号 p. 273-280

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The interaction coefficients for phosphorus have been determined in the Fe-P-i systems at 1600°C. The experimental technique is the same as described in the paper on the Fe-P systems which was reported previously. The measured systems are Fe-P-Si, Fe-P-Al, Fe-P-Ti, Fe-P-V, Fe-P-Cr, Fe-P-Co, Fe-P-Ni, Fe-P-Nb, and Fe-P-Mo.
The experimental results show that the interaction coefficients for phosphorus with the elements in the fourth and fifth periods increase with the atomic number of the elements.
The results obtained are summarized as follows:
εSlP=12.6±0.6 (11.9±0.6)
εTlP=-8±2
εCrP= -3.8±0.7
εNlP= 0.7±0.7
εMoP= 0.4±0.7
εAlP= 4.6±0.7
εVP= -4.9±0.7
εCoP= 0.9±0.7
εNbP= -5.4±1.2

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