Removal of Fe (II) from aqueous solution by Calotropis Procera: Kinetics, isotherm s tudies, and measurement of competitive adsorption with UV-Visible spectrophotometer

Volume 6, Issue 02, Pages 18-30, Jun 2023 *** Field: Analytical Method in Plant

  • Yashu Verma, Corresponding Author, Bhilai In s titute of Technology, Durg, Chhattisgarh, India
  • Piyush Kant Pandey Amity University, Raipur, Chhattisgarh, India
  • Shweta Choubey Government Engineering College, Raipur, Chhattisgarh, India
DOI: https://doi.org/10.24200/amecj.v6.i02.218
Keywords: Fe(II) Adsorption, Leached biomass, Calotropis Procera, Indu s trial effluents, UV-Visible spectrophotometer

Abstract

Iron is essential heavy metal in trace quantities, but its excessive concentration as Fe2+ is present in effluents from steel mills, iron ore mines, and metal processing industries, which pollute the groundwater. Among other conventional methods, sorption by natural biomass is a low-cost alternative for iron sequestration from an aqueous solution. The root of a native weed plant Calotropis Procera was used to optimize the adsorption parameters like pH, contact time, sorbent dose, and initial adsorbate concentration. Competitive adsorption of Fe2+ in the presence of cations (Ni2+, Cd2+, Cr3+, Zn2+, Ca2+, Mg2+, As3+) and anions (Cl-, SO42- , F-) was also studied. Batch adsorption studies were carried out to evaluate adsorption isotherm by Langmuir and Freundlich isotherm models. Leaching of biomass significantly improved iron uptake capacity from 15 mg g-1 to 80 mg g-1. The kinetics of the reaction was fast, with equilibrium conditions attaining in 30 minutes. FTIR study of the biomass revealed the presence of -COOH, -NH groups responsible for the metal binding mechanism. The biomass could be regenerated with 0.1 M HNO3 for further use. Iron removal from simulated acidic water was done under optimum conditions and absorbance was measured by a UV-Visible spectrophotometer.

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Published
2023-06-30
How to Cite
Verma, Y., Pandey, P., & Choubey, S. (2023). Removal of Fe (II) from aqueous solution by Calotropis Procera: Kinetics, isotherm s tudies, and measurement of competitive adsorption with UV-Visible spectrophotometer. Analytical Methods in Environmental Chemistry Journal, 6(02), 18-30. https://doi.org/10.24200/amecj.v6.i02.218
Issue
Vol 6 No 02 (2023): Issue No. Two
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