Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access July 31, 2014

Silicon solar cells with Al2O3 antireflection coating

  • Leszek Dobrzański EMAIL logo , Marek Szindler , Aleksandra Drygała and Magdalena Szindler
From the journal Open Physics

Abstract

The paper presents the possibility of using Al2O3 antireflection coatings deposited by atomic layer deposition ALD. The ALD method is based on alternate pulsing of the precursor gases and vapors onto the substrate surface and then chemisorption or surface reaction of the precursors. The reactor is purged with an inert gas between the precursor pulses. The Al2O3 thin film in structure of the finished solar cells can play the role of both antireflection and passivation layer which will simplify the process. For this research 50×50 mm monocrystalline silicon solar cells with one bus bar have been used. The metallic contacts were prepared by screen printing method and Al2O3 antireflection coating by ALD method. Results and their analysis allow to conclude that the Al2O3 antireflection coating deposited by ALD has a significant impact on the optoelectronic properties of the silicon solar cell. For about 80 nm of Al2O3 the best results were obtained in the wavelength range of 400 to 800 nm reducing the reflection to less than 1%. The difference in the solar cells efficiency between with and without antireflection coating was 5.28%. The LBIC scan measurements may indicate a positive influence of the thin film Al2O3 on the bulk passivation of the silicon.

[1] L. A. Dobrzański et al., J. Mater. Process. Tech. 201, 291 (2008) http://dx.doi.org/10.1016/j.jmatprotec.2007.11.27810.1016/j.jmatprotec.2007.11.278Search in Google Scholar

[2] L. A. Dobrzański, A. Drygała, JAMME 31, 77 (2008) Search in Google Scholar

[3] J. Zhao, M. A. Green, IEEE T. Electron Dev. 38, 1925 (1991) http://dx.doi.org/10.1109/16.11903510.1109/16.119035Search in Google Scholar

[4] S. K. Dhungel et al., J. Korean Phys. Soc. 49, 885 (2006) 10.5124/jkma.2006.49.10.885Search in Google Scholar

[5] K. Jinkuk et al., 30, 41 (2013) 10.3917/civit.030.0041Search in Google Scholar

[6] R. Kishore, S. N. Singh, B. K. Das, Renew. Ener. 12, 131 (1997) http://dx.doi.org/10.1016/S0960-1481(97)00030-X10.1016/S0960-1481(97)00030-XSearch in Google Scholar

[7] C. C. Johnson, T. Wydeven, K. Donohoe, Sol. Energy. 31, 355 (1983) http://dx.doi.org/10.1016/0038-092X(83)90133-010.1016/0038-092X(83)90133-0Search in Google Scholar

[8] C. R. Lin, D. H. Wei, C. K. Chang, W. H. Liao, Phys. Procedia 18, 46 (2011) http://dx.doi.org/10.1016/j.phpro.2011.06.05510.1016/j.phpro.2011.06.055Search in Google Scholar

[9] P. Violet, E. Blanquet, D. Monnier, I. Nuta, C. Chatillon, Surf. Coat. Technol. 204, 882 (2009) http://dx.doi.org/10.1016/j.surfcoat.2009.08.02210.1016/j.surfcoat.2009.08.022Search in Google Scholar

[10] A. Szeghalmi et al, Appl. Opt. 48, 1727 (2009) http://dx.doi.org/10.1364/AO.48.00172710.1364/AO.48.001727Search in Google Scholar PubMed

[11] B. Brennan, H. Dong, D. Zhernokletov, J. Kim, R. M. Wallace, Appl. Phys. Express 4, 125701 (2011) http://dx.doi.org/10.1143/APEX.4.12570110.1143/APEX.4.125701Search in Google Scholar

[12] L. A. Dobrzański, K. Lukaszkowicz, D. Pakuła, J. Mikuła, AMSE 28, 12 (2007) Search in Google Scholar

[13] M. Chwastek, J. Weszka, J. Jurusik, B. Hajduk, P. Jarka, AMSE 48, 69 (2011) Search in Google Scholar

[14] J. Weszka et al., JAMME 49, 224 (2011) Search in Google Scholar

[15] J. Weszka, M. Śzindler, A. Sliwa, B. Hajduk, J. Jurusik, AMSE 48, 40 (2011) Search in Google Scholar

[16] W. Liang et al., Phot. IEEE J. 3, 678 (2013) http://dx.doi.org/10.1109/JPHOTOV.2012.223552510.1109/JPHOTOV.2012.2235525Search in Google Scholar

[17] S.-K. Oh et al., J. Semicond. Sci. Tech. 13, 581 (2013) http://dx.doi.org/10.5573/JSTS.2013.13.6.58110.5573/JSTS.2013.13.6.581Search in Google Scholar

[18] V. Naumann et al., Energy Procedia 27, 312 (2012) http://dx.doi.org/10.1016/j.egypro.2012.07.06910.1016/j.egypro.2012.07.069Search in Google Scholar

[19] K.-H. Kim et al., Phys. Status Solidi Rapid Res. Lett. 5, 202 (2011) http://dx.doi.org/10.1002/pssr.20110518810.1002/pssr.201105188Search in Google Scholar

Published Online: 2014-7-31
Published in Print: 2014-9-1

© 2014 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 30.4.2024 from https://www.degruyter.com/document/doi/10.2478/s11534-014-0500-9/html
Scroll to top button