Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter June 11, 2013

The filamentary growth of metals

  • Matthias Schamel , Carola Schopf , Dominic Linsler , Sabine T. Haag , Lisa Hofacker , Christian Kappel , Horst P. Strunk and Gunther Richter

Abstract

One-dimensional structures are starting to have impact in modern technological device design. A brief history of the fabrication of metal structures in such geometries is presented. At the dawn of modern science, in 1574, a recipe was published for the formation of “metallic grass”. This ancient recipe is reintroduced into modern technology using physical vapor deposition techniques to grow nanowhiskers. Defects in dewetting layers on various substrates are proven to act as nucleation sites for the whisker growth. This general approach is shown for Cu, Ag and Co nanostructures. The whiskers are of perfect crystal structure, devoid of defects and flaws and freestanding on the substrates. A phenomenological but energetically justified growth model is presented. The unique mechanical stability of these structures is shown by bending experiments. The theoretical limit of the mechanical strength is reached reproducibly.


* Correspondence address Dr. Gunther Richter Max-Planck-Institut für Intelligente Systeme (formerly Max Planck Institute for Metals Research) Heisenbergstr. 3, D-70569 Stuttgart, Germany Tel.: +49 711 3587 E-mail:

References

[1] W.Ostwald: Die Welt der vernachlässigten Dimensionen, Steinkopff Verlag, Dresden Leipzig (1915).Search in Google Scholar

[2] H.E.Schaefer: Nanoscience, Springer-Verlag, Berlin (2010).10.1007/978-3-642-10559-3Search in Google Scholar

[3] T.Graham: Philos. Trans. Royal Soc.151 (1861) 183.10.1098/rstl.1861.0011Search in Google Scholar

[4] R.Zsigmondy: Justus Liebig Annalen der Chemie301 (1898) 29.10.1002/jlac.18983010104Search in Google Scholar

[5] M.Faraday: Philos. Trans. Royal Soc.147 (1857) 145.10.1098/rstl.1857.0011Search in Google Scholar

[6] J.Kunckel: Ars Vitraria Experimentalis, oder Vollkommene Glasmacherkunst. Christoph Guntern, Leipzig (1679).Search in Google Scholar

[7] J.C.Orschall: Sol Sine Veste oder Dreyßig Experimenta dem Gold seinen Purpur auszuziehen…, Koppmayr, Augsburg (1684).Search in Google Scholar

[8] J.R.Glauber: Dess Teutschlands Wohlfahrt, Johann Jansson, Amsterdam (1656–61).Search in Google Scholar

[9] A.Cassius: De Extremo Illo Et Perfectissimo Naturae Opificio Ac Principe Terraenorum Sidere Auro. Georgus Wolffus, Hamburg (1685).Search in Google Scholar

[10] A.Neri: L'Arte Vetraria, Stamperia de'GiuntiFlorence (1612).Search in Google Scholar

[11] P.Heinzerling: Praxis der Naturwissenschaften/Chemie in der Schule55 (2006) 32.Search in Google Scholar

[12] D.Barber, I.C.Freestone: Archaeometry32 (1990) 33.10.1111/j.1475-4754.1990.tb01079.xSearch in Google Scholar

[13] D.B.Harden, J.M.C.Toynbee: Archaeologia97 (1959) 179.Search in Google Scholar

[14] R.Resch, C.Baur, A.Bugacov, B.E.Koel, A.Madhukar, A.A.G.Requicha, P.Will: Langmuir14 (1998) 6613.10.1021/la980386fSearch in Google Scholar

[15] J.Webster: Metallographia or History of Metals, Walter Kettilby, London (1671).Search in Google Scholar

[16] G.Agricola: De natura fossilium libri X, Chemnitz (1546).Search in Google Scholar

[17] R.Boyle: The Sceptical Chymist, J. Cadwell, London (1661).Search in Google Scholar

[18] J.Gerhard: Decas quaestionum physico-chymicarium de metallis, Phillipertii Brunnii, Tübingen (1643).Search in Google Scholar

[19] L.Ercker: Beschreibung allerfürnemisten Mineralischen Ertzt, unnd Bergwercksarten, wie dieselbigen, unnd eine jede insonderheit, der Natur und Eigenschafft nach, auff alle Metale Probirt… In fünff Bücher verfast, Georg Schwartz, Prag (1574).Search in Google Scholar

[20] P.R.Beierlein: Freiburger Forschungshefte D12 (1955) 143.Search in Google Scholar

[21] A.G.Sisco, C.S.Smith: Treaties on Ore and Assaying, University of Chicago, Chicago (1951).Search in Google Scholar

[22] J.Henkels: Flora Saturnizans die Verwandschaft des Pflanzen- mit dem Mineralreich nach der Naturalhistorie und Chymie, Leipzig (1755).10.5962/bhl.title.6121Search in Google Scholar

[23] H.T.de la Beche: The Geological Observer, Longman, London (1853).Search in Google Scholar

[24] J.Percy: Metallurgy, John Murray, London (1861).Search in Google Scholar

[25] A.Liversidge: Chem. News35 (1877) 68.Search in Google Scholar

[26] T.A.Readwin: Chem. News13 (1877) 144.Search in Google Scholar

[27] T.A.Readwin: Chem. News13 (1877) 186.Search in Google Scholar

[28] T.A.Readwin: Chem. News13 (1877) 195.Search in Google Scholar

[29] V.Kohlschütter, E.Eydmann: Justus Liebig Annalen der Chemie390 (1912) 340.Search in Google Scholar

[30] A.Beutell: Centralblatt für Mineralogie, Geologie und Palaontologie (1919) 14.Search in Google Scholar

[31] W.Ostwald: Kolloid-Zeitschrift102 (1943) 35.10.1007/BF01556420Search in Google Scholar

[32] W.Ostwald: Kolloid-Zeitschrift102 (1943) 181.10.1007/BF01521394Search in Google Scholar

[33] G.Bischof: Annalen der Physik und Chemie LX (1843) 285.10.1002/andp.18431361007Search in Google Scholar

[34] K.Friedrich, A.Leroux: Metallurgie3 (1906) 361.Search in Google Scholar

[35] R.Schenk, R.Fricke, G.Brinkmann: Zeitschrift für physikalische Chemie139 (1928) 32.Search in Google Scholar

[36] F.C.Frank: Dis. Faraday Soc.5 (1949) 48.10.1039/df9490500048Search in Google Scholar

[37] G.W.Sears: Acta Met.3 (1955) 367.10.1016/0001-6160(55)90042-0Search in Google Scholar

[38] S.S.Brenner: Acta Met.4 (1956) 62.10.1016/0001-6160(56)90111-0Search in Google Scholar

[39] F.R.N.Nabarro, P.J.Jackson, in: R.H.Doremus, B.Roberts, D.Turnbull (Eds.), Growth and Perfection of Crystals, John Wiley, London (1958) 11.Search in Google Scholar

[40] D.Shoenberg: Nature183 (1959) 171.10.1038/183171a0Search in Google Scholar

[41] R.W.DeBlois, C.D.Graham: J. Appl. Phys.29 (1958) 931.10.1063/1.1723334Search in Google Scholar

[42] O.S.Lutes: Phys. Rev.105 (1957) 1451.10.1103/PhysRev.105.1451Search in Google Scholar

[43] R.S.Wagner, W.C.Ellis: Appl. Phys. Lett.4 (1964) 89.10.1063/1.1753975Search in Google Scholar

[44] G.W.Sears: J. Chem. Phys.33 (1960) 563.10.1063/1.1731184Search in Google Scholar

[45] A.J.Melmed, R.Gomer: J. Chem. Phys.34 (1960) 1802.10.1063/1.1701081Search in Google Scholar

[46] V.Ruth, J.P.Hirth: J. Chem. Phys.41 (1964) 3139.10.1063/1.1725687Search in Google Scholar

[47] G.Richter, K.Hillerich, D.S.Gianola, R.Mönig, O.Kraft, C.A.Volkert: Nano Lett.9 (2009) 3048.Search in Google Scholar

[48] M.Kolb, G.Richter, in: E. Zschech, P.S. Ho, S. Ogawa (Eds.), Stress-induced Phenomena in Metallization, AIP Conference Proceedings 1300 (2010) 98.Search in Google Scholar

[49] D.Linsler: Cobalt-Whisker – Herstellung und magnetische Eigenschaften, UniversitätStuttgart, 2010.Search in Google Scholar

[50] M.Schamel: Mechanical properties and composite formation of metallic whiskers, UniversitätStuttgart, 2009.Search in Google Scholar

[51] C.Schopf: Mechanische Eigenschaften von metallischen Whiskern, UniversitätStuttgart, 2010.Search in Google Scholar

[52] O.Kraft, P.A.Gruber, R.Mönig, D.Weygand: Annu. Rev. Mater. Res40 (2010) 293.10.1146/annurev-matsci-082908-145409Search in Google Scholar

[53] G.Richter: Scripta Mater.63 (2010) 933.10.1016/j.scriptamat.2010.07.007Search in Google Scholar

[54] E.K.Kroner: Einfluss des Substrates auf das Kontraktionsverhalten von Herzmuskelzellen, UniversitätStuttgart, 2007.Search in Google Scholar

[55] L.Hofacker: Whiskerwachstum auf strukturierten Oberflächen, UniversitätStuttgart, 2010.Search in Google Scholar

[56] H.Strunk: Phys. Stat. Sol. A11 (1972) K105.10.1002/pssa.2210110249Search in Google Scholar

[57] R.Gomer, in: R.H.Doremus, B.W.Roberts, D.Turnbull (Eds.), Growth and Perfection of Crystals, John Wiley, London (1958) 126.Search in Google Scholar

[58] J.A.Venables: Phil. Mag.27 (1973) 697.10.1080/14786437308219242Search in Google Scholar

Received: 2011-2-18
Accepted: 2011-4-15
Published Online: 2013-06-11
Published in Print: 2011-07-01

© 2011, Carl Hanser Verlag, München

Downloaded on 14.5.2024 from https://www.degruyter.com/document/doi/10.3139/146.110541/html
Scroll to top button