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Licensed Unlicensed Requires Authentication Published by De Gruyter November 3, 2016

Improved corrosion inhibition of 3-amino-1,2,4-triazole on mild steel electrode in HCl solution using surface nanocrystallization

  • Sadegh Pour-Ali , Alireza Kiani-Rashid and Abolfazl Babakhani

Abstract

A nanocrystalline surface layer with average grain size of 77 nm was produced on mild steel through a wire brushing process. Its corrosion behavior was studied in the absence and presence of 3-amino-1,2,4-triazole (3-AT) as corrosion inhibitor. Although the increase in the inhibitor concentration shows a positive effect on inhibition efficiency of micro- and nano-grained surfaces, this effect is more remarkable for the sample with a nanocrystalline surface layer. In addition, in the presence of the optimum concentration of 3-AT, temperature increment has a more negative effect on the sample with a microcrystalline surface layer. The results also revealed that due to enhanced adsorption of 3-AT inhibitor and formation of a protective layer with a high polarization resistance, the inhibition effect of 3-AT increased as the grain size decreased from microcrystalline to nanocrystalline.


*Correspondence address, Dr. Sadegh Pour-Ali, Materials and Metallurgical Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad, 91775-1111, Mashhad, Iran, Tel.: +985138817182, Fax: +985138807182, E-mail: ,

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Received: 2016-05-09
Accepted: 2016-08-11
Published Online: 2016-11-03
Published in Print: 2016-11-10

© 2016, Carl Hanser Verlag, München

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