Next Article in Journal
Design of pH Responsive Textile as a Sensor Material for Acid Rain
Previous Article in Journal
Investigation of the Adsorption Behavior of Jet-Cooked Cationic Starches on Pulp Fibers
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Mechanical Strength Enhancement of 3D Printed Acrylonitrile Butadiene Styrene Polymer Components Using Neural Network Optimization Algorithm

1
University Centre for Research and Development, Chandigarh University, Mohali-140413, India
2
Department of Mechanical Engineering, IKG Punjab Technical University, Kapurthala-144603, India
3
Center for Nanoscience and Technology, Institute of Science and Technology, Jawaharlal Nehru Technological University Hyderabad, Telangana State 500085, India
4
Department of Mechanical Engineering, Imperial College London, Exhibition Rd., London SW7 2AZ, UK
5
Department of Automated Mechanical Engineering, South Ural State University, Lenin Prosp. 76, 454080 Chelyabinsk, Russia
6
Department of Mechanical Engineering, G.L. Bajaj Institute of Technology and Management, Greater Noida 201308, India
*
Author to whom correspondence should be addressed.
Polymers 2020, 12(10), 2250; https://doi.org/10.3390/polym12102250
Submission received: 2 September 2020 / Revised: 18 September 2020 / Accepted: 26 September 2020 / Published: 30 September 2020
(This article belongs to the Section Polymer Processing and Engineering)

Abstract

:
Fused filament fabrication (FFF), a portable, clean, low cost and flexible 3D printing technique, finds enormous applications in different sectors. The process has the ability to create ready to use tailor-made products within a few hours, and acrylonitrile butadiene styrene (ABS) is extensively employed in FFF due to high impact resistance and toughness. However, this technology has certain inherent process limitations, such as poor mechanical strength and surface finish, which can be improved by optimizing the process parameters. As the results of optimization studies primarily depend upon the efficiency of the mathematical tools, in this work, an attempt is made to investigate a novel optimization tool. This paper illustrates an optimization study of process parameters of FFF using neural network algorithm (NNA) based optimization to determine the tensile strength, flexural strength and impact strength of ABS parts. The study also compares the efficacy of NNA over conventional optimization tools. The advanced optimization successfully optimizes the process parameters of FFF and predicts maximum mechanical properties at the suggested parameter settings.

Graphical Abstract

1. Introduction

Globalization has intensified the market scenario of manufacturing units due to rapidly changing customer demands, competition among peers and requirements for high quality and reliable products. The demand for low cost and customized products has led to a paradigm shift from traditional manufacturing techniques to additive manufacturing technologies by industries [1]. Additive manufacturing is a collection of non-conventional techniques that follow the principle of layer by layer manufacturing in contrast to traditional subtractive and joining techniques [2]. The last decade witnessed a marginal increase in the development and market share of various additive manufacturing techniques due to their implementation in medical, aerospace, automobile, military and ornamental industries [3]. Additive manufacturing enables direct fabrication of a product from three-dimensional computer-aided design (CAD) data through successive layer stacking of suitable material. These techniques are also popularly referred to as 3D printing, rapid prototyping, solid freeform fabrication, e-manufacturing and digital fabrication. There are more than thirty different additive manufacturing techniques available, which differ on fabrication principle, materials used, accuracy, bed size, part strength and applicability; however, fused filament fabrication (FFF) is the most recognized [4].
FFF has acquired considerable attention from researchers, material scientists, innovators and medical practitioners due to the unique advantages of this technique, such as material flexibility, minimum environmental degradation, low cost, portability and higher accuracy [5]. FFF uses CAD data as input, which is transferred to slicing software for tool path generation. These tool paths are coded instructions that control the three-dimensional motion of the nozzle head and build platforms to create the product within a few hours. The raw material used is a thin wire of thermoplastic material with a lower melting point and zero toxicity. This wire is pushed by rollers into the nozzle head, where heaters convert it into semi-molten filament. Finally, the material is deposited by a nozzle moving in X and Y direction on the build platform, as shown in Figure 1. As one layer is deposited, the build platform moves downwards (in Z direction), and the next layer of material is deposited. The process is repeated until the desired part is achieved. Sometimes, another filament of washable material is used to support the overhanging part, which is easily washed away after fabrication [6].
FFF supplies customized products with the minimum lead time and manufacturing cost, but the mechanical strength of the part is always a matter of interest for researchers as considerable variation in mechanical properties is experienced due to variation in design [7]. Moreover, issues related to the lower mechanical strength of FFF parts may hinder the usability of these products for certain applications. Thus, there is always a requirement for intelligent optimization tools for the prediction and maximization of the mechanical strength of FFF parts. There are several input parameters of FFF technology, which have a significant impact on the tensile strength, compressive strength, flexural and impact strength of FFF parts [5]. Although numerous studies have been conducted for optimization of process parameters of FFF, recent studies have focused on the development of conventional mathematical tools and algorithms which can optimize and forecast the mechanical strength of FFF parts.
Hambali et al. [2] tested the deformation behavior of acrylonitrile butadiene styrene (ABS) material parts made by FFF technology. The parts were fabricated at different orientations, and it was found that the maximum strength occurred at a 45° angle. The study was validated by finite element analysis, which predicted the mechanical strength with 95% accuracy. Other studies also indicated the significant impact of orientation angle [3] and infill density [8] on the mechanical strength of FFF parts. Ahn et al. [7] investigated the anisotropic behavior of FFF parts and found that the air gap and raster orientation significantly affected the tensile strength of FFF parts. The cross raster structure (0°/90°) yielded the maximum tensile strength due to its directional stability, and it was suggested that a negative air gap be maintained for higher strength and stiffness. In addition to conventional optimization studies, researchers have used mathematical models and algorithms for the analysis of process parameters. Multi-criteria genetic algorithm was used for the optimization and prediction of the surface finish and manufacturing time of FFF parts [4] and aluminum-based metal matrix composites [9]. The teaching–learning based optimization tool was utilized by Rao and Rai [1] to enhance the sliding wear resistance and strength of FFF parts; the experimental data was compared with genetic algorithm and advanced quantum-behaved particle swarm optimization algorithm, which found strong correlation between experimental and computational data. Rayegani and Onwubolu [5] developed a relationship between different factors, such as part orientation, raster angle, raster width and air gap, with tensile strength of FFF parts using differential evolution techniques along with the group method of data handling (GMDH). It was deduced that deposition and raster angle defined the FFF part strength. Moreover, the fine-tuning of input parameters was performed using advanced tools to achieve maximum mechanical strength. Natarajan et al. [10] also implemented a modified teaching–learning based optimization method (NSMTLBO), referred to as non-dominated sorting type, to acquire maximum finish and minimum material removal rate.
In another study, a hybrid version of particle swarm technique was applied to FFF input parameters, such as layer thickness, deposition angle, material type and infill strategy, and for improving the surface finish, hardness, flexural strength and tensile strength in combination with bacterial foraging optimization [11]. The tool yielded promising results as higher strength (more than 7%) was achieved using the hybrid optimization technique as compared to conventional algorithms. Recent studies have reported the impact of orientation angle and infill percentage in mechanical properties of ABS samples [12]. Moreover, in the case of polylactic acid material, the anisotropy of samples had a significant impact on tensile strength as compared to the orientation angle [13]. In addition to optimization tools, some advanced post-processing techniques, such as annealing and ultrasound treatment, have been recommended for strength enhancement [14].
Zhang et al. [15] found that residual stress and porosity were directly proportional to printing speed during the fabrication of virgin and composite ABS structures. Moreover, the raster angle of ±45° manifested lesser shrinkage and porosity, which further influenced dimensional accuracy and mechanical strength, respectively. Similarly, Rankouhi et al. [16] found a major impact of layer thickness and raster orientation on the mechanical strength of FFF parts, with a reduction in layer thickness and 0° raster angle strengthening the ABS structures. Another study reported the maximum impact strength of the ABS part at 0° orientation angle [17]. Christiyan et al. [18] evaluated the mechanical strength of magnesium silicate reinforced ABS composites and found maximum tensile and flexural strength at minimum values of layer thickness and printing speed. The increase in infill density also enhanced the tensile behavior of ABS test samples [19]. The flexural and impact strength of ABS samples under standard conditions was maximum with thinner layer thickness and 0° deposition angle [20,21].
The previous studies reported the impact of different input parameters on the mechanical properties of ABS parts made by FFF technology. Although smaller layer thickness is uniformly recommended by previous literature, the recommended settings of the raster angle, orientation angle and air gap are different for each study. These issues are due to conventional optimization algorithms and mathematical modeling tools used for forecasting optimum parameters, which yield conflicting results. Moreover, limited studies are performed where advanced optimization algorithms are used for prediction of the best parametric settings for mechanical strength enhancement. In the present work, the efficacy of neural network algorithm (NNA) is tested to solve the mechanical strength issues of FFF parts. As the introduction of advanced optimization algorithms have yielded significant improvements compared to previous studies performed by regular algorithms, investigating the optimization problems using this optimization and simulation technique is necessary.
In the next section, a detailed methodology of the formulation and implementation of NNA is elaborated, along with a selection of objective functions and process parameters. The third section presents a comparative analysis of different algorithms and a discussion of the simulation results. Finally, the fourth section includes confirmatory experiments that are conducted to validate the predicted results.

2. Materials and Methods

2.1. Neural Network Optimization Algorithm

Sadollah et al. [22] developed a metaheuristics based on neural networks (NNs) named neural network algorithm (NNA). The authors found that a metaheuristic optimization algorithm could be used to model artificial NNs (ANNs) to solve optimization problems. NNA was developed using the ANNs framework to solve optimization problems. NNA is a parameter-free optimization algorithm where users do not require any algorithm parameters to be adjusted.
ANNs iteratively update the ANN’s weights w i j to minimize the mean square error and map the input information according to the target information required at its output. ANNs are designed to produce new alternatives, where the population’s best search agent is considered as the target and all searching agents seek the solution through algorithm processes.
NNA draws on the concept and structure of ANN. NNA begins within a search space with an initial population of randomly generated solutions. Each individual in the population is referred to as a “pattern solution”, which is a vector of 1 × D, representing the input data of the NNA.
P a t t e r n S o l u t i o n i = [ x i , 1 , x i , 2 , x i , 3 , , x i , D ] .
To start the NNA optimization algorithm, within the boundaries of the search space, a pattern solution matrix X with size N p o p × D is generated randomly, given by:
X = [ X 1 X 2 . . . X N p o p ] = [ x 1 , 1 x 1 , 2 x 1 , D x 2 , 1 x 2 , 2 x 2 , D . . . . . . . . . x N p o p , 1 x N p o p , 2 x N p o p , D ]
where:
x i j = L B j + r a n d ( U B j L B j ) , i = 1 , 2 , , N p o p , j = 1 , 2 , , D
where L B and U B represent the search space’s lower and upper limits.
Similar to ANNs, every pattern solution X i in NNA will have its corresponding W i weight, where:
W i = [ w i , 1 , w i , 2 , w i , 3 , , w i , N p o p ] T
The weights array W is given by:
W = [ W 1 , W 2 , , W i , , W N p o p ] = [ w 11 w i 1 w N p o p 1 w 12 w i 2 w N p o p 2 . . . . . . . . . w 1 N p o p w i N p o p , 2 w N p o p N p o p ]
where W represents a matrix of a ( N p o p × N p o p ) randomly distributed number in [0, 1], used to generate new candidate solutions.
The initial weights in NNA are randomly generated and the network changes their weights according to the network error propagation as the iteration increases. The weight values are limited, as the overall weight of this pattern solution must not exceed one and the solution for the weight pattern is defined as:
w i j U ( 0 , 1 ) , i , j = 1 , 2 , 3 , , N p o p
j = 1 N p o p w i j = 1 , i = 1 , 2 , 3 , , N p o p
Such weight-value constraints are used to regulate bias movement and to generate new pattern solutions. NNA will get trapped in the local optimum without these constraints. The fitness f i of each solution is determined using the corresponding pattern solution X i by evaluating the objective function f o b j .
f i = f o b j ( X i ) = f o b j ( x i 1 , x i 2 , x i 3 , , x i D ) , i = 1 , 2 , 3 , , N p o p
After fitness calculation for all pattern solutions, the pattern solution with the best fitness is considered as the target solution, with a target location X T a r g e t , target fitness F T a r g e t and target weight W T a r g e t . The new pattern solution is created using the weight summation technique used in ANNs as follows:
X j N e w ( k + 1 ) = i = 1 N p o p w i j ( k ) . X i ( k ) , j = 1 , 2 , 3 , , N p o p
X i ( k + 1 ) = X i ( k ) + X i N e w ( k + 1 ) , i = 1 , 2 , 3 , , N p o p
where   k is an iteration index.
After the generation of the new pattern solutions, the weight matrix is also modified using the equation:
W i U p d a t e d ( k + 1 ) = W i ( k ) + 2 . r a n d . ( W T a r g e t ( k ) W i ( k ) , ) , i = 1 , 2 , 3 , , N p o p
where the constraints (3) and (4) during the optimization process must be satisfied.
A bias operator is used to better explore the search space by adjusting a fixed range of pattern solutions created in the new X i ( k + 1 ) population as well as using the updated weight matrix W i U p d a t e d ( k + 1 ) . This operator helps the algorithm prevent premature convergence by changing the few individuals in the population to investigate certain positions in the search space that were not explored yet.
An adjustment factor β N N A is used, using the bias operator, to determine the proportion of pattern solutions to be transformed. The value of β N N A is set to 1 initially, which means all the entities in the population are biased. At each iteration, the β N N A value will be reduced adaptively using any possible reduction technique, such as:
β N N A ( k + 1 ) = 1 ( k M a x _ i t e r a t i o n ) , k = 1 , 2 , 3 , , M a x _ i t e r a t i o n
β N N A ( k + 1 ) = β N N A ( k ) . α N N A , k = 1 , 2 , 3 , , M a x _ i t e r a t i o n
where α N N A is a positive number slightly smaller than 1. The flowchart of the NNA process is given in Figure 2.
Reduction in the value of   β N N A is done to enhance the algorithm’s exploitation during the final iterations. The transfer function operator is used in NNA (unlike ANNs) to generate better-quality solutions using the following equation:
X i ( k + 1 ) = T F ( X i ( k + 1 ) ) = X i ( k + 1 ) + 2 . r a n d . ( X T a r g e t ( k ) X i ( k + 1 ) ) i = 1 , 2 , 3 , , N p o p
In NNA, the bias operator has more chances to produce a new pattern solution at early iterations, meaning that there are more possibilities to find unvisited pattern solutions. As the number of iterations increases, the probability of applying the bias operator decreases. The transfer function ( T F ) operator has more chances of enhancing the exploitation, particularly at the final iterations.
The generation of a new updated solution in NNA does not depend solely on the preceding value of that solution but also depends on all the mathematically defined population (known as a dynamic optimization model), as follows:
X i ( k + 1 ) = f ( X i ( k ) , X ( k ) ) , i = 1 , 2 , 3 , , N p o p

2.2. Selection of Process Parameters

The materials selected for the present study were ABS commercial-grade P400 (Supplier: Stratasys Ltd., Eden Prairie, Minnesota, Inc., USA), which was manufactured by the polymerization of styrene (42–60%) and acrylonitrile (18–35%) in an atmosphere of butadiene (6–30%). The criss-cross bonding of long-chained butadiene with shorter styrene-acrylonitrile chains yields excellent toughness and heat resistance. The filament also contained mineral oil, tallow and wax in small concentrations (0–2%), as reported in the manufacturer’s datasheet [23]. The output of the case study performed by Panda et al. [24] was considered to identify the optimum parameter settings of the FFF process to enhance the mechanical properties of the test samples. The five input parameters considered for the present study and their units were as follows:
  • x 1 Layer thickness in mm.
  • x 2 Orientation in degrees.
  • x 3 Raster angle in degrees.
  • x 4 Raster width in mm.
  • x 5 Air gap in mm.
The major reason for the selection of the aforementioned process parameters was that previous studies found a strong correlation of these parameters with the mechanical strength of FFF parts [7]. The response parameters used for the present study were tensile strength (TS) in MPa, flexural strength (FS) in MPa and impact strength (IS) in MJ/m2. The primary motivation behind the selection of such response parameters was that FFF products withstand different types of loading conditions when used for automobile, aerospace and medical applications. Thus, it was obligatory to test each type of mechanical strength using the advanced optimization tool. These output parameters were taken as secondary data as reported by Panda et al. [24], and were designated as objective functions for the optimization study.
The objective functions are expressed by Equations (13)–(15) below:
Maximize   TS   =   13.5625   +   0.7156 x 1     1.3123 x 2   +   0.9760 x 3   +   0.5183 x 5   +   1.1671 x 1 2     1.3014 x 2 2     0.4363 x 1 x 3 +   0.4364 x 1 x 4     0.4364 x 1 x 5   +   0.4364 x 2 x 3   +   0.4898 x 2 x 5     0.5389 x 3 x 4   +   0.5389 x 3 x 5     0.5389 x 4 x 5
Maximize   FS   =   29.9178   +   0.8719 x 1     4.8741 x 2   +   2.4251 x 3     0.9096 x 4   +   1.6626 x 5     1.7199 x 1 x 3   +   1.7412 x 1 x 4     1.1275 x 1 x 5   +   1.0621 x 2 x 5   +   1.0621 x 3 x 5 +   1.0408 x 4 x 5
Maximize   IS   =   0.401992   +   0.034198 x 1   +   0.008356 x 2   +   0.013673 x 3   +   0.021383 x 1 2   +   0.008077 x 2 x 4
The upper and lower limits of these parameters are defined as per machine constraints, and most commercial FFF printers are capable of fabricating products within the following parameter limits [24]. The parameter bounds are expressed by Equations (16)–(20).
0.127     x 1     0.254
0     x 2     30
0     x 3     60
0.4064     x 4     0.5064
0     x 5     0.008

3. Results and Discussion

NNA was implemented in this work to solve the optimization problem of the FFF process. Because heuristic algorithms are stochastic optimization methods, to generate meaningful statistical results, they must be run more than 10 times at minimum.
Each simulation was carried out 30 times for this purpose, with population size varying from 20 to 40, and the maximum amount of iterations ranging from 100 to 500. Grey wolf optimization (GWO), novel bat algorithm (NBA), dragonfly algorithm (DA), salp swarm algorithm (SSA) and sine cosine algorithm (SCA) [25,26,27,28,29] were selected to check and compare the efficiency of NNA. The algorithm parameter settings used for comparison are shown in Table 1. The value of different parameters, such as the number of particles (NP), dimension size (D), maximum number of iterations (Gmax) and other algorithm variables (A, fmin, fmax, c1, c2, c3, w, s, c, e, α, γ and β) are shown in Table 1. It must be noted that for each of the algorithms, 20–40 search agents and 100–500 iterations for different setups were used.
The optimum solutions obtained by simulated algorithms are given in Table 2, Table 3 and Table 4 for TS, FS and IS estimation, respectively. It is evident from these outcomes that the optimum NNA’s fitness values are the same as that of competitive algorithms for TS, FS and IS fitness functions.
The performance of the simulated algorithms for FFF over 30 independent runs for 500 iterations and with a population size of 40 is given in Table 5, Table 6 and Table 7 for TS, FS and IS estimation, respectively. The results are presented in terms of best, worst, mean and standard deviation values over 30 runs.
The convergence rate of NNA, as shown in Figure 3, is also better than the competitive algorithms. The convergence characteristics for TS, FS and IS estimation are shown in Figure 3. It is found that for TS estimation, GWO, DA, SSA and NBA algorithms achieve optimum value, but overall, NNA has the capability to identify the best value with the least standard deviation. For FS estimation, GWO, SSA, SCA and NNA have the potential to reach global optimal solutions with the same standard deviation. For IS estimation, all algorithms are able to reach a near global optimal solution with the same standard deviation. Overall, the result demonstrates that NNA’s mean, median and standard deviation values are much better compared to competitive algorithms, which proves the enhanced exploration and exploitation capabilities of NNA for process parameter optimization of FFF, especially in TS estimation.
The box plots for TS, FS and IS evaluations are displayed in Figure 4a–c, respectively, for NBA, GWO, DA, SSA, SCA and NNA. These box plots are an excellent medium to ascertain the fitness values and compare the effectiveness of different algorithms. For TS estimation, it is clear that NNA yields the best fitness values as mean and median, along with the least standard deviation. As compared to other rival algorithms, the NNA performs better, and these results can be used for the fabrication of commercial products using ABS. From the box plots of FS estimation, it is clear that GWO, SSA, SCA and NNA have similar mean and median fitness values, and their standard deviation values are better in comparison to NBA and DA. Thus, the overall performance of GWO, SSA, SCA and NNA is found to be better for FS estimation compared to other algorithms. From the box plots of IS estimation, it is clear that all optimization algorithms have similar mean and median fitness values, their standard deviation values are almost the same, and the algorithms reach optimum values.
Further, the performance comparison of metaheuristic algorithms for FFF over 30 independent runs for 100 iterations and population size 40 are given in Table A1, Table A2 and Table A3 (see Appendix A) for TS, FS and IS estimation, respectively. The effect of the reduced total number of iterations clearly shows that NNA’s mean, median and standard deviation values for TS estimation are much better compared to competitive algorithms, which proves that NNA is able to find an optimum solution with reduced iterations for process parameter optimization of FFF. Similarly, for FS estimation, SSA, SCA and NNA are able to achieve global optimum with equal authority. However, in IS estimation, each algorithm shows a similar effect to achieve the optimum value.
The performance of optimization algorithms for FFF process parameter estimation was evaluated over 30 independent runs for 100 iterations with population size 20. The results are given in Table A4, Table A5 and Table A6 (see Appendix A) for TS, FS and IS estimation, respectively, which demonstrate that NNA’s mean, median and standard deviation values are much better compared to competitive algorithms for TS and FS estimation. This proves the enhanced exploration and exploitation capabilities of NNA for the process parameter optimization of FFF. However, each algorithm is able to achieve the optimum value for IS estimation, independent of the population size of variables and the given number of iterations. The maximum values of TS, FS and IS can be achieved by manufacturing FFF parts using the process parameters predicted by the NNA algorithm.
The optimum parameter settings to achieve maximum tensile strength of FFF parts are layer thickness of 0.127 mm, 9.55° orientation angle, 60° raster angle, 0.4064 mm raster width and 0.008 mm air gap. On the other hand, flexural strength can be maximized at 0.127 mm layer thickness, 0° orientation angle, 60° raster angle, 0.4064 mm raster width and 0.008 mm air gap. In order to obtain the maximum value of impact strength, the FFF process must be carried out at a layer thickness of 0.254 mm, 30° orientation angle, 60° raster angle, 0.5064 mm raster width and 0.0079 mm air gap. It can be observed that a raster angle of 60° results in the maximization of all three parameters of mechanical strength, i.e., tensile, flexural and impact strength. Thus, it is recommended to use the default setting of 60° raster angle for the best mechanical stability of FFF parts. In the case of layer thickness, a lower value results in better impact and tensile strength, while the opposite phenomenon is predicted for flexural strength. The air gap is also found to be constant for mechanical stability. In the case of orientation angle, the horizontal layer deposition (0°) strategy is the most successful in attaining maximum flexural strength, while 9.55° and 30° result in better tensile and impact strength, respectively, as suggested by NNA.

4. Confirmatory Experiments

The optimum parameters for each output suggested by NNA must be validated before recommendation; hence, confirmatory experiments were conducted. The ABS samples were prepared using commercial P400 material (supplied by Stratasys Inc. Ltd., Eden Prairie, Minnesota, USA) and an open-source FFF printer (supplied by Prusa Research, Prague, Czech Republic). The technical data sheet [23] of thermoplastic materials was referred to when deciding printing parameters. The three samples were prepared for tensile strength, flexural strength and impact strength using ASTM D638, ASTM D790 and ASTM D256, respectively. The test samples were prepared at a constant printing speed, infill method, extrusion temperature, bed temperature and environmental temperature, as shown in Table 8.
Fixed values of temperature were used to eliminate error as the significant impact of temperature on the bonding strength of ABS layers has been noticed. As the semi-molten thermoplastic beads are laid down, excessive temperature at the nozzle may increase flowability and cause deformation. On the other hand, faster cooling may lead to shrinkage, which would exhibit dimensional variation. Thus, the optimum values of temperature were selected as the thermoplastic polymer layers must be cooled slowly to avoid deformation and dimensional variability [19]. The printing and testing of samples was performed under controlled environmental conditions and using three replications of each experiment to avoid random errors (Figure 5).
The variable parameters used for fabrication and experimentation are shown in Table 9. The values of each parameter are taken from predictions made by NNA for tensile strength, flexural strength and impact strength. It can be observed that there is minimal variation between the predicted and experimental value of each output. The maximum variation of 2.92% occurs in sample no. 3, which undergoes impact testing, and the minimum variation (1.3%) occurs in sample no. 2 during flexural testing. The average variation of three experiments is 1.94%, which is much less compared to previous studies. Hence, the NNA predicted results are validated with high accuracy, meaning it is suitable for solving optimization issues in manufacturing processes.
The NNA results achieved in the present study are compared with the percentage error (experimental vs. predicted) of previous studies in Figure 6. The response parameter and prediction tool used by each author is also indicated in the graph. It can be observed that the minimum variation between experimental and predicted results is achieved in the present study as compared to previous studies that implemented advanced optimization algorithms. The maximum variation was found for finite element analysis (FEA) [2], while the average error was found using artificial neural networks (ANN) [30] and response surface methodology (RSM) [31].
The comparative analysis indicates the higher efficacy of NNA as compared to other optimization algorithms and prediction tools. The predicted parameters can be recommended for commercial production of functional prototypes and end-use components manufactured using FFF. Moreover, the NNA must be implemented to solve surface roughness and dimensional variability issues of FFF technology when used for complex designs.

5. Conclusions

Despite an efficient additive manufacturing technique, mechanical strength is one of the major obstructions against the applicability of FFF polymer products for end-use components. Thus, the selection of optimum parameter settings is required to obtain the best mechanical properties of ABS parts. The optimization was conducted employing NBA, GWO, DA, SSA, SCA and NNA algorithms for the maximization of mechanical strength (TS, FS and IS) of parts with varying population size and number of iterations. From the statistical and convergence results, it was found that the NNA algorithm was highly competitive with respect to NBA, GWO, DA, SSA and SCA algorithms and was able to achieve optimum results for FFF products. The endorsed input parameters indicated the manifestation of enhanced mechanical strength among the test parts. In the future, researchers can also implement a hybrid metaheuristic algorithm for the enhancement of quality and accuracy along with a reduction in convergence time.

Author Contributions

Conceptualization, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma), J.S., K.V.R., M.M., D.Y.P.; methodology, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma) and M.M.; investigation, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma); resources, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma), J.S., K.V.R., M.M., D.Y.P. and S.P.D.; writing—original draft preparation, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma) and M.M.; writing—review and editing, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma); supervision, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma) and M.M.; project administration, J.S.C., N.M., R.K., S.S. (Sandeep Singh), S.S. (Shubham Sharma), J.S., K.V.R., M.M., D.Y.P. and S.P.D. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Acknowledgments

The authors wish to acknowledge the resources of IK Gujral Punjab Technical University, Main Campus, Kapurthala and Chandigarh University, Mohali for carrying out the research work.

Conflicts of Interest

The authors declare no conflict of interest.

Appendix A

Table A1. The performance of simulated algorithms for TS estimation over 30 independent runs for 100 iterations and population size 40.
Table A1. The performance of simulated algorithms for TS estimation over 30 independent runs for 100 iterations and population size 40.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA174.6234301174.9214992174.9011405174.9214587.52 × 10−2
GWO174.623429174.9214992174.8620095174.92143861.05 × 10−1
DA174.6234301174.9214992174.8394289174.92017191.18 × 10−1
SSA174.6324965174.9214992174.8028863174.81699219.99 × 10−2
SCA174.4505185174.9200412174.6821489174.62821991.24 × 10−1
NNA174.8553077174.9214939174.9100097174.92001541.98 × 10−2
Table A2. The performance of simulated algorithms for FS estimation over 30 independent runs for 100 iterations and population size 40.
Table A2. The performance of simulated algorithms for FS estimation over 30 independent runs for 100 iterations and population size 40.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA162.1491001162.6744472162.5693778162.67444722.14 × 10−1
GWO162.674447162.6744472162.6744472162.67444723.38 × 10−8
DA162.6627456162.6744472162.6740571162.67444722.14 × 10−3
SSA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
SCA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
NNA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
Table A3. The performance of simulated algorithms for IS estimation over 30 independent runs for 100 iterations and population size 40.
Table A3. The performance of simulated algorithms for IS estimation over 30 independent runs for 100 iterations and population size 40.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
GWO1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
DA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
SSA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
SCA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
NNA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
Table A4. The performance of simulated algorithms for TS estimation over 30 independent runs for 100 iterations and population size 20.
Table A4. The performance of simulated algorithms for TS estimation over 30 independent runs for 100 iterations and population size 20.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA174.6234263174.9214936174.8372247174.91968521.27 × 10−1
GWO174.6242344174.921498174.8359942174.92001141.11 × 10−1
DA171.631808174.9214992174.1513635174.63163911.04
SSA174.5267321174.9214992174.7720952174.75175881.25 × 10−1
SCA174.1631947174.921241174.5762605174.58856362.10 × 10−1
NNA174.6348368174.9214885174.8893958174.91632916.93 × 10−2
Table A5. The performance of simulated algorithms for FS estimation over 30 independent runs for 100 iterations and population size 20.
Table A5. The performance of simulated algorithms for FS estimation over 30 independent runs for 100 iterations and population size 20.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA162.1491001162.6744472162.6044009162.67444721.82 × 10−1
GWO162.6734733162.6744472162.6743693162.67444722.15 × 10−4
DA162.4635226162.6744472162.6453716162.67444724.66 × 10−2
SSA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
SCA162.1491001162.6744472162.6569356162.67444729.59 × 10−2
NNA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
Table A6. The performance of simulated algorithms for IS estimation over 30 independent runs for 100 iterations and population size 20.
Table A6. The performance of simulated algorithms for IS estimation over 30 independent runs for 100 iterations and population size 20.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
GWO1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
DA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
SSA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
SCA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
NNA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16

References

  1. Rao, R.; Rai, D. Optimization of fused deposition modeling process using teaching-learning-based optimization algorithm. Eng. Sci. Technol. Int. J. 2016, 19, 587–603. [Google Scholar] [CrossRef] [Green Version]
  2. Hambali, R.; Smith, P.; Rennie, A. Determination of the effect of part orientation to the strength value on additive manufacturing FFF for end-use parts by physical testing and validation via three-dimensional finite element analysis. Int. J. Mat. Eng. Innov. 2012, 3, 269–281. [Google Scholar] [CrossRef]
  3. Kim, G.; Oh, Y. A benchmark study on rapid prototyping processes and machines: Quantitative comparisons of mechanical properties, accuracy, roughness, speed, and material cost. Proc. Inst. Mech. Eng. B J. Eng. Manuf. 2008, 222, 201–215. [Google Scholar] [CrossRef]
  4. Pandey, P.; Thrimurthulu, K.; Reddy, N. Optimal part deposition orientation in FFF by using a multicriteria genetic algorithm. Int. J. Prod. Res. 2004, 42, 4069–4089. [Google Scholar] [CrossRef]
  5. Rayegani, F.; Onwubolu, G. Fused deposition modelling (FFF) process parameter prediction and optimization using group method for data handling (GMDH) and differential evolution (DE). Int. J. Adv. Manuf. Technol. 2014, 73, 509–519. [Google Scholar] [CrossRef]
  6. Rane, R.; Kulkarni, A.; Prajapati, H.; Taylor, R.; Jain, A.; Chen, V. Post-process effects of isothermal annealing and initially applied static uniaxial loading on the ultimate tensile strength of fused filament fabrication parts. Materials 2020, 13, 352. [Google Scholar] [CrossRef] [Green Version]
  7. Ahn, S.; Montero, M.; Odell, D.; Roundy, S.; Wright, P. Anisotropic material properties of fused deposition modeling ABS. Rapid. Prototyp. J. 2002, 8, 248–257. [Google Scholar] [CrossRef] [Green Version]
  8. Srinivasan, R.; Babu, B.; Annamalai, P.; Sivasankaran, S.; Tharaan, M. An experimental on the influence of process parameters on the tensile properties of carbon fiber reinforced PLA FFF parts. TEST Eng. Manag. 2019, 81, 4606–4611. [Google Scholar]
  9. Rao, V.; Geethika, V.; Krishnaveni, P. Multi-objective optimization of mechanical properties of aluminium 7075-based hybrid metal matrix composite using genetic algorithm. In Advances in 3D Printing and Additive Manufacturing Technologies, 1st ed.; Kumar, L., Ed.; Springer: Singapore, 2017. [Google Scholar]
  10. Natarajan, E.; Kaviarasan, V.; Lim, W.; Tiang, S.; Parasuraman, S.; Elango, S. Non-dominated sorting modified teaching–learning-based optimization for multi-objective machining of polytetrafluoroethylene (PTFE). J. Intell. Manuf. 2020, 31, 911–935. [Google Scholar] [CrossRef]
  11. Raju, M.; Gupta, M.; Bhanot, N.; Sharma, V. A hybrid PSO–BFO evolutionary algorithm for optimization of fused deposition modelling process parameters. J. Intell. Manuf. 2019, 30, 2743–2758. [Google Scholar] [CrossRef]
  12. García-Domínguez, A.; Claver, J.; Camacho, A.M.; Sebastián, M.A. Considerations on the applicability of test methods for mechanical characterization of materials manufactured by FDM. Materials 2020, 13, 28. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  13. Yao, T.; Ye, J.; Deng, Z.; Zhang, K.; Ma, Y.; Ouyang, H. Tensile failure strength and separation angle of FDM 3D printing PLA material: Experimental and theoretical analyses. Compos. Part B Eng. 2020, 188, 107894. [Google Scholar] [CrossRef]
  14. Wickramasinghe, S.; Do, T.; Tran, P. FDM-based 3D printing of polymer and associated composite: A review on mechanical properties, defects and treatments. Polymers 2020, 12, 1529. [Google Scholar] [CrossRef] [PubMed]
  15. Zhang, W.; Wu, A.S.; Sun, J.; Quan, Z.; Gu, B.; Sun, B.; Cotton, C.; Heider, D.; Chou, T.-W. Characterization of residual stress and deformation in additively manufactured ABS polymer and composite specimens. Comp. Sci. Technol. 2017, 150, 102–110. [Google Scholar] [CrossRef]
  16. Rankouhi, B.; Javadpour, S.; Delfanian, F.; Letcher, T. Failure analysis and mechanical characterization of 3D printed ABS with respect to layer thickness and orientation. J. Fail. Anal. Prev. 2016, 16, 467–481. [Google Scholar] [CrossRef]
  17. Górski, F.; Kuczko, W.; Wichniarek, R. Impact strength of ABS parts manufactured using Fused Deposition Modeling technology. Arch. Mech. Technol. Autom. 2014, 31, 3–12. [Google Scholar]
  18. Christiyan, K.J.; Chandrasekhar, U.; Venkateswarlu, K. A study on the influence of process parameters on the Mechanical Properties of 3D printed ABS composite. IOP Conf. Mater. Sci. Eng. 2016, 114, 1–8. [Google Scholar] [CrossRef]
  19. Rodríguez-Panes, A.; Claver, J.; Camacho, A.M. The influence of manufacturing parameters on the mechanical behaviour of PLA and ABS pieces manufactured by FDM: A comparative analysis. Materials 2018, 11, 1333. [Google Scholar] [CrossRef] [Green Version]
  20. Shubham, P.; Sikidar, A.; Chand, T. The influence of layer thickness on mechanical properties of the 3D printed ABS polymer by fused deposition modeling. Key Eng. Mater. 2016, 706, 636–637. [Google Scholar] [CrossRef]
  21. Vidakis, N.; Petousis, M.; Vairis, A.; Savvakis, K.; Maniadi, A. A parametric determination of bending and Charpy’s impact strength of ABS and ABS-plus fused deposition modeling specimens. Prog. Add. Manuf. 2019, 4, 323–330. [Google Scholar] [CrossRef]
  22. Sadollah, A.; Sayyaadi, H.; Yadav, A. A dynamic metaheuristic optimization model inspired by biological nervous systems: Neural network algorithm. Appl. Soft Comput. 2018, 71, 747–782. [Google Scholar] [CrossRef]
  23. Available online: http://groups.csail.mit.edu/drl/wiki/images/3/3b/MSDS_P400ABSModel_1062730A.pdf (accessed on 27 January 2020).
  24. Panda, S.; Padhee, S.; Anoop, S.; Mahapatra, S. Optimization of fused deposition modelling (FFF) process parameters using bacterial foraging technique. Intell. Inf. Manag. 2009, 1, 89. [Google Scholar]
  25. Meng, X.; Gao, X.; Liu, Y.; Zhang, H. A novel bat algorithm with habitat selection and Doppler effect in echoes for optimization. Exp. Syst. Appl. 2015, 42, 6350–6364. [Google Scholar] [CrossRef]
  26. Mirjalili, S.; Mirjalili, S.; Lewis, A. Grey wolf optimizer. Adv. Eng. Soft 2014, 69, 46–61. [Google Scholar] [CrossRef] [Green Version]
  27. Mirjalili, S. Dragonfly algorithm: A new meta-heuristic optimization technique for solving single-objective, discrete, and multi-objective problems. Neural Comput. Appl. 2015, 27, 1053–1073. [Google Scholar] [CrossRef]
  28. Mirjalili, S.; Gandom, A.; Mirjalili, S.; Saremi, S.; Faris, H.; Mirjalili, S. Salp Swarm Algorithm: A bio-inspired optimizer for engineering design problems. Adv. Eng. Soft 2017, 114, 163–191. [Google Scholar] [CrossRef]
  29. Mirjalili, S. SCA: A Sine cosine algorithm for solving optimization problems. Know Base Syst. 2016, 96, 120–133. [Google Scholar] [CrossRef]
  30. Boschetto, A.; Giordano, V.; Veniali, F. Surface roughness prediction in fused deposition modelling by neural networks. Int. J. Adv. Manuf. Technol. 2013, 67, 2727–2742. [Google Scholar] [CrossRef]
  31. Samykano, M.; Selvamani, S.K.; Kadirgama, K.; Ngui, W.K.; Kanagaraj, G.; Sudhakar, K. Mechanical property of FDM printed ABS: Influence of printing parameters. Int. J. Adv. Manuf. Technol. 2019, 102, 2779–2796. [Google Scholar] [CrossRef]
Figure 1. Schematic of the fused filament fabrication (FFF) process used for 3D printing of thermoplastics.
Figure 1. Schematic of the fused filament fabrication (FFF) process used for 3D printing of thermoplastics.
Polymers 12 02250 g001
Figure 2. Flowchart adopted during implementation neural network algorithm (NNA) (NFE, number of function evaluations; TF, transfer function).
Figure 2. Flowchart adopted during implementation neural network algorithm (NNA) (NFE, number of function evaluations; TF, transfer function).
Polymers 12 02250 g002
Figure 3. The convergence graph of simulated algorithm estimations over 30 independent runs for 500 iterations and population size 40 for (a) TS (b) FS and (c) IS.
Figure 3. The convergence graph of simulated algorithm estimations over 30 independent runs for 500 iterations and population size 40 for (a) TS (b) FS and (c) IS.
Polymers 12 02250 g003
Figure 4. The box plot of simulated algorithm estimations over 30 independent runs for 500 iterations and population size 40 for (a) TS (b) FS and (c) IS.
Figure 4. The box plot of simulated algorithm estimations over 30 independent runs for 500 iterations and population size 40 for (a) TS (b) FS and (c) IS.
Polymers 12 02250 g004
Figure 5. (a) FFF printer used for experimentation (b) Universal Testing Machine used for mechanical testing.
Figure 5. (a) FFF printer used for experimentation (b) Universal Testing Machine used for mechanical testing.
Polymers 12 02250 g005
Figure 6. Comparison of percentage error of NNA results with previous studies.
Figure 6. Comparison of percentage error of NNA results with previous studies.
Polymers 12 02250 g006
Table 1. Parameter settings for different algorithms.
Table 1. Parameter settings for different algorithms.
AlgorithmParameters
NBANP = 20–40; D = 5; Gmax = 100–500; A = 0.5; r = 0.5; α = γ = 0.9; f m i n = 0 ; f m a x = 1.5
GWONP = 20–40; D = 5; Gmax = 100–500; a = [0,1,2]
DA
SSA
SCA
NP = 20–40; D = 5; Gmax = 100–500; w = [0.4–0.9], s = 0.1, a = 0.1, c = 0.7, f = 1, e = 1
NP = 20–40; D = 5; Gmax = 100–500; c1, c2, c3 = [0,1]
NP = 20–40; D = 5; Gmax = 100–500; a = 2
NNANP = 20–40; D = 5; Gmax = 100–500; β N N A = [1–0.05]; α N N A = 0.99
Table 2. Optimum solutions obtained by optimization algorithms for tensile strength (TS) estimation for 500 iterations with population size 40.
Table 2. Optimum solutions obtained by optimization algorithms for tensile strength (TS) estimation for 500 iterations with population size 40.
Process ParametersUnitsNBAGWODASSASCANNA
x1mm0.1270.1270.1270.1270.1270.127
x2degrees9.5572230759.5563020419.5552643229.5548163129.4186075099.557224815
x3degrees606060606060
x4mm0.40640.40640.40640.40640.40640.4064
x5mm0.0080.0080.0080.0080.0080.008
y---1.6058236221.6058236221.6058236221.6058236221.6058236221.605823622
Table 3. Optimum solutions obtained by optimization algorithms for flexural strength (FS) estimation for 500 iterations with population size 40.
Table 3. Optimum solutions obtained by optimization algorithms for flexural strength (FS) estimation for 500 iterations with population size 40.
Process ParametersUnitsNBAGWODASSASCANNA
x1mm0.1270.1270.1270.1270.1270.127
x2degrees000000
x3degrees606060606060
x4mm0.40640.40640.40640.40640.40640.4064
x5mm0.0080.0080.0080.0080.0080.008
y-162.6744472162.6744472162.6744472162.6744472162.6744472162.6744472
Table 4. Optimum solutions obtained by optimization algorithms for impact strength (IS) estimation for 500 iterations with population size 40.
Table 4. Optimum solutions obtained by optimization algorithms for impact strength (IS) estimation for 500 iterations with population size 40.
Process ParametersUnitsNBAGWODASSASCANNA
x1mm0.2540.2540.2540.2540.2540.254
x2degrees303030303030
x3degrees606060606060
x4mm0.50640.50640.50640.50640.50640.5064
x5mm0.0079517410.0079517410.0079517410.0079517410.0079517410.007951741
y-1.6058236221.6058236221.6058236221.6058236221.6058236221.605823622
Table 5. The performance of simulated algorithms for TS estimation over 30 independent runs for 500 iterations and population size 40.
Table 5. The performance of simulated algorithms for TS estimation over 30 independent runs for 500 iterations and population size 40.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA174.6234301174.9214992174.9016279174.92149927.56 × 10−2
GWO174.6234298174.9214992174.911563174.92149915.44 × 10−2
DA174.6234301174.9214992174.8800297174.92149929.72 × 10−2
SSA174.6761253174.9214992174.8844652174.92149927.32 × 10−2
SCA174.6177085174.9214213174.7818994174.87887811.44 × 10−1
NNA174.9214992174.9214992174.9214992174.92149921.89 × 10−10
Table 6. The performance of simulated algorithms for FS estimation over 30 independent runs for 500 iterations and population size 40.
Table 6. The performance of simulated algorithms for FS estimation over 30 independent runs for 500 iterations and population size 40.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA162.1491001162.6744472162.6044009162.67444721.82 × 10−1
GWO162.6744472162.6744472162.6744472162.67444725.78 × 10−15
DA162.6278193162.6744472162.6727806162.67444728.51 × 10−3
SSA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
SCA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
NNA162.6744472162.6744472162.6744472162.67444725.78 × 10−14
Table 7. The performance of simulated algorithms for IS estimation over 30 independent runs for 500 iterations and population size 40.
Table 7. The performance of simulated algorithms for IS estimation over 30 independent runs for 500 iterations and population size 40.
AlgorithmWorstBestAverageMedianStd. Dev.
NBA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
GWO1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
DA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
SSA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
SCA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
NNA1.6058236221.6058236221.6058236221.6058236222.26 × 10−16
Table 8. Fixed parameters used for confirmatory experiments.
Table 8. Fixed parameters used for confirmatory experiments.
S. No.Fixed ParameterValue
1Extrusion temperature230 °C
2Bed temperature80 °C
3Ambient temperature25 °C
4Infill typeRectilinear
5Printing speed50 mm/s
Table 9. Variable parameters and results.
Table 9. Variable parameters and results.
Sample No.Layer Thickness
(mm)
Orientation Angle
(°)
Raster Angle
(°)
Raster Width
(mm)
Air Gap
(mm)
Predicted ValueExperimental ValueError
(%)
10.1279.55600.40640.00817.4917.231.61
20.1270600.40640.00816.2616.051.3
30.25430600.50640.00792.462.392.92

Share and Cite

MDPI and ACS Style

Chohan, J.S.; Mittal, N.; Kumar, R.; Singh, S.; Sharma, S.; Singh, J.; Rao, K.V.; Mia, M.; Pimenov, D.Y.; Dwivedi, S.P. Mechanical Strength Enhancement of 3D Printed Acrylonitrile Butadiene Styrene Polymer Components Using Neural Network Optimization Algorithm. Polymers 2020, 12, 2250. https://doi.org/10.3390/polym12102250

AMA Style

Chohan JS, Mittal N, Kumar R, Singh S, Sharma S, Singh J, Rao KV, Mia M, Pimenov DY, Dwivedi SP. Mechanical Strength Enhancement of 3D Printed Acrylonitrile Butadiene Styrene Polymer Components Using Neural Network Optimization Algorithm. Polymers. 2020; 12(10):2250. https://doi.org/10.3390/polym12102250

Chicago/Turabian Style

Chohan, Jasgurpreet Singh, Nitin Mittal, Raman Kumar, Sandeep Singh, Shubham Sharma, Jujhar Singh, Kalagadda Venkateswara Rao, Mozammel Mia, Danil Yurievich Pimenov, and Shashi Prakash Dwivedi. 2020. "Mechanical Strength Enhancement of 3D Printed Acrylonitrile Butadiene Styrene Polymer Components Using Neural Network Optimization Algorithm" Polymers 12, no. 10: 2250. https://doi.org/10.3390/polym12102250

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop