Electrochemical Hydrogen Evolution over Hydrothermally Synthesized Re-Doped MoS2 Flower-Like Microspheres
Abstract
:1. Introduction
2. Results
2.1. Characterization of the Catalyst
2.1.1. Scanning Electron Microscopy Analysis
2.1.2. X-ray Diffraction Analysis
2.1.3. Raman Spectroscopy Analysis
2.1.4. Scanning Transmission Electron Microscopy Analysis
2.1.5. X-Ray Photoelectron Spectroscopy
2.2. Hydrogen Evolution Reaction (HER) Performance of Pristine MoS2 and Re-doped MoS2 Samples
3. Materials and Methods
3.1. Chemicals
3.2. Synthesis of Re-Doped MoS2 and Pristine MoS2
3.3. Characterization Techniques
3.4. Electrochemical Measurements
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | Mo 3d5/2 | S 2p3/2 | Re 4f7/2 | Composition |
---|---|---|---|---|
Pristine MoS2 | 229.3 | 161.8 | - | MoS1.64 |
14.7% Re-doped MoS2 | 229.7 | 162.6 | 42.4 | Mo0.85Re0.15S1.76 |
27.7% Re-doped MoS2 | 229.7 | 162.5 | 42.2 | Mo0.72Re0.28S1.73 |
39.2 % Re-doped MoS2 | 229.8, 228.8 | 162.8, 161.7 | 42.7, 41.6 | Mo0.61Re0.39S1.83 |
Sample | Onset Potential (mV) | η10 (mV) | Tafel Slope (mVdec−1) | Rct (Ωcm2) |
---|---|---|---|---|
Pristine MoS2 | 203 | 326 | 102 | 32.58 |
14.7% Re-doped MoS2 | 123 | 210 | 78 | 7.77 |
27.7% Re-doped MoS2 | 164 | 285 | 97 | 17.45 |
39.2% Re-doped MoS2 | 244 | 379 | 132 | 157.86 |
Pt/C 10% | 20 | 42 | 32 | - |
Sample | (NH4)2MoO4 | (NH4)ReO4 | CH4N2S |
---|---|---|---|
Pristine MoS2 | 2.0 mmol | - | 6.0 mmol |
14.7% Re-doped MoS2 | 1.8 mmol | 0.2 mmol | 6.0 mmol |
27.7% Re-doped MoS2 | 1.5 mmol | 0.5 mmol | 6.0 mmol |
39.2% Re-doped MoS2 | 1.0 mmol | 1.0 mmol | 6.0 mmol |
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Aliaga, J.; Vera, P.; Araya, J.; Ballesteros, L.; Urzúa, J.; Farías, M.; Paraguay-Delgado, F.; Alonso-Núñez, G.; González, G.; Benavente, E. Electrochemical Hydrogen Evolution over Hydrothermally Synthesized Re-Doped MoS2 Flower-Like Microspheres. Molecules 2019, 24, 4631. https://doi.org/10.3390/molecules24244631
Aliaga J, Vera P, Araya J, Ballesteros L, Urzúa J, Farías M, Paraguay-Delgado F, Alonso-Núñez G, González G, Benavente E. Electrochemical Hydrogen Evolution over Hydrothermally Synthesized Re-Doped MoS2 Flower-Like Microspheres. Molecules. 2019; 24(24):4631. https://doi.org/10.3390/molecules24244631
Chicago/Turabian StyleAliaga, Juan, Pablo Vera, Juan Araya, Luis Ballesteros, Julio Urzúa, Mario Farías, Francisco Paraguay-Delgado, Gabriel Alonso-Núñez, Guillermo González, and Eglantina Benavente. 2019. "Electrochemical Hydrogen Evolution over Hydrothermally Synthesized Re-Doped MoS2 Flower-Like Microspheres" Molecules 24, no. 24: 4631. https://doi.org/10.3390/molecules24244631