@article{ART001950038},
author={ 노선균 and 한신 },
title={다양한 pH 용액에서 네자리 Schiff base 착물이 수식된 유리질탄소 전극의 산소환원 촉매적 특성},
journal={공학기술논문지},
issn={2005-3142},
year={2014},
volume={7},
number={3},
pages={113-119},
doi={10.35272/jaet.2014.7.3.113},
url={http://dx.doi.org/10.35272/jaet.2014.7.3.113}

TY - JOUR
AU - 노선균
AU - 한신
TI - 다양한 pH 용액에서 네자리 Schiff base 착물이 수식된 유리질탄소 전극의 산소환원 촉매적 특성
T2 - 공학기술논문지
PY - 2014
VL - 7
IS - 3
PB - 조선대학교 공학기술연구원
SP - 113-119
SN - 2005-3142
AB - The electrocatalytic effect of oxygen reduction was investigated at glassy carbon electrodecoated with tetradentate Schiff base transition metal(II) complexes ; Co(II)(SOPD), Co(II)2(SMPD)2 andCo(II)2(SPPD)2 in the 1 M KOH solution. The reduction current of oxygen measured by cyclic voltammetrywas increased by about 150 % more than that of bare glassy carbon electrode and the reduction potentialwas shifted about 140 mV to the positive direction. The reduction current of oxygen was increased byraising scan rate and reduction potential was shifted to the negative potential direction. Theelectrocatalytic effect of oxygen reduction was investigated in various pH solutions by cyclic voltammetryat the glassy carbon electrode coated with tetradentate Schiff base transition metal(II) complexes. Thereduction current of oxygen at glassy carbon electrode coated with Co(II)(SOPD) was increased by about200 % more than that of bare glassy carbon electrode and the reduction potential was shifted about300~350 mV to the positive direction, compared to those of bare glassy carbon electrode in the pH 4, 7,and 10 solution. In the pH 10 solution, especially, the reduction current of oxygen at the electrode coatedwith Co(II)2(SMPD)2 complex was increased by about 200 % and peak potential was shifted about 500 mVto the positive direction .
KW - Oxygen Reduction, Cyclic voltammetry, Electrocatalytic effect, glassy carbon, tetradentate Schiff base Complexes
DO - 10.35272/jaet.2014.7.3.113
UR - http://dx.doi.org/10.35272/jaet.2014.7.3.113
ER -

노선균 and 한신 . 2014, “다양한 pH 용액에서 네자리 Schiff base 착물이 수식된 유리질탄소 전극의 산소환원 촉매적 특성”, 공학기술논문지, vol. 7, no. 3, pp. 113-119. Available from: doi:10.35272/jaet.2014.7.3.113

노선균 한신 et al. “다양한 pH 용액에서 네자리 Schiff base 착물이 수식된 유리질탄소 전극의 산소환원 촉매적 특성” 공학기술논문지 7.3 pp. 113-119 (2014): 113.

노선균 , 한신 . 다양한 pH 용액에서 네자리 Schiff base 착물이 수식된 유리질탄소 전극의 산소환원 촉매적 특성 공학기술논문지 [Internet]. 2014; 7( 3), : 113-119. Available from: doi:10.35272/jaet.2014.7.3.113

노선균 and 한신 . “다양한 pH 용액에서 네자리 Schiff base 착물이 수식된 유리질탄소 전극의 산소환원 촉매적 특성” 공학기술논문지 7, no.3 (2014): 113-119. doi: 10.35272/jaet.2014.7.3.113