High Temperature CO2 Capture by Regenerable Calcium Aluminates Carbonates Sorbents

Ching Tsung Yu; Han Wen Cheng; Wei Chin Chen

doi:10.4028/www.scientific.net/AMR.779-780.56

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 779-780High Temperature CO2 Capture by Regenerable...

High Temperature CO₂ Capture by Regenerable Calcium Aluminates Carbonates Sorbents

Abstract:

The calcium aluminates carbonates are prepared as mediumhigh temperature CO₂ sorbents. The sorbent exhibited excellent performance with 53 wt% capacity and 99% stability in TGA test for 15 h. However, using the sorbent in a fixed-bed reactor, it was found that the stability rapidly decreased to about 35% after 10 cycles. Hence, development of regeneration methods for reusing this spent sorbents is critical to economic consideration toward CO₂ capture technology. The calcium aluminates carbonates sorbent makes up layered structure including cations formation (Ca²⁺, Al³⁺) and lamella anions (CO₃^2-, OH), which can be re-constructed under aqueous conditions. Aqueous hydrolysis provides an efficient route to reactive sorbent. The results showed that CO₂ capacity could be recovered to around 50 wt% with 98% stability in TGA test for 15 h for spent sorbents. The reactive mechanism of sorbent is worthy to further discussing.

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Periodical:

Advanced Materials Research (Volumes 779-780)

Pages:

56-59

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.779-780.56

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Cite this paper

Online since:

September 2013

Authors:

Ching Tsung Yu, Han Wen Cheng, Wei Chin Chen

Keywords:

CaO, CO₂ Capture, Mediumhigh Temperature, Regeneration, Sorbent

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References

[1] A. Samanta, A. Zhao, G.K.H. Shimizu, P. Sarkar, R. Gupta, Post-Combustion CO2 Capture Using Solid Sorbents: A Review, Ind. Eng. Chem. Res. 51 (2012) 1438–1463.

DOI: 10.1021/ie200686q

Google Scholar

[2] Q. Wang, J. Luo, Z. Zhong, A. Borgna, CO2 capture by solid adsorbents and their applications: current status and new trends, Energy Environ. Sci. 4 (2011) 42–55.

DOI: 10.1039/c0ee00064g

Google Scholar

[3] B. Feng, H. An, E. Tan, Screening of CO2 Adsorbing Materials for Zero Emission Power Generation Systems, Energy Fuels 21 (2007) 426–434.

DOI: 10.1021/ef0604036

Google Scholar

[4] C.T. Yu, C.H. Wang, M.J. Hsu, Y.P. Chyou, Development of a novel Ca/Al carbonates for medium-high temperature CO2 capture, Energy Procedia, 4 (2011) 787–794.

DOI: 10.1016/j.egypro.2011.01.120

Google Scholar

[5] Andrew M. Fogg*, Amal J. Freij, Allan Oliveira, Andrew L. Rohl, Mark I. Ogden, Gordon M. Parkinson, Morphological control of Ca3Al2(OH)12, J. Cryst. Growth 234 (2002) 255–262.

DOI: 10.1016/s0022-0248(01)01663-3

Google Scholar

[6] P.H. Chang, Y.P. Chang, S.Y. Chen, C.T. Yu, Y.P. Chyou, Ca-rich ca–Al-oxide, high-temperature-stable sorbents prepared from hydrotalcite precursors: synthesis, characterization, and CO2 capture capacity, ChemSusChem 4 (2011) 1844–1851.

DOI: 10.1002/cssc.201100357

Google Scholar