Electroless Ni-P/Diamond/Graphene Composite Coatings and Characterization of their Wear and Corrosion Resistance in Sodium Chloride Solution

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Abstract:

The purpose of the present study is to evaluate the effect of the electroless Ni-P/diamond/graphene composite coating on the structure and surface hardness of 2024-T6 aluminum alloy as well as their effect on the corrosion and wear resistance of the alloy in 3.5 % NaCl solution. The electroless Ni-P plating solution was prepared by adding different size diamond (6-12 μm and 0.2 μm) and nanographene into the electroless Ni-P plating solution to obtain Ni-P/diamond, Ni-P/graphene and Ni-P/daimond/graphene composite coatings for comparison. Experimental results indicated that the Ni-P/diamond, Ni-P/graphene and Ni-P/daimond/graphene composite coatings can be successfully electroless deposited on anodized 2024-T6 aluminum alloy. The anodically oxidized films, that formed on the aluminum alloy using phosphoric acid as the electrolyte, was porous with high density of pores, and thus could enhance the adhesion of the composite coatings. The Ni-P/daimond/graphene hybrid coating had a higher hardness as well as better corrosion and wear resistance of 2024-T6 alloy in 3.5 wt.% NaCl solution as compared with other composite coatings. When the combination of nanographene and smaller diamond particles added this beneficial effect was significantly raised, especially the composite coating was further vacuum annealed at 400 °C for 24 h to obtain a more smooth and defect-free coating structure.

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Periodical:

Key Engineering Materials (Volumes 656-657)

Pages:

51-56

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Online since:

July 2015

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[1] J.L. Cavazos, R. Cola's, Precipitation in a heat-treatable aluminum alloy cooled at different rates, Mater. Charact. 47 (2001) 175-179.

DOI: 10.1016/s1044-5803(01)00164-4

Google Scholar

[2] V. Guillaumin, G. Mankowski, Localized corrosion of 2024-T351 aluminum alloy in chloride media, Corros. Sci. 41 (1999) 421-438.

DOI: 10.1016/s0010-938x(98)00116-4

Google Scholar

[3] C.K. Lee, Electroless Ni-Cu-P/nano-graphite composite coatings for bipolar plates of proton exchange membrane fuel cells, J. Power Sources 220 (2012) 130-137.

DOI: 10.1016/j.jpowsour.2012.07.022

Google Scholar

[4] G. Sabatini, L. Ceschini, C. Martini, J.A. Williams, I.M. Hutchings, Improving sliding and abrasive wear behavior of cast A356 and wrought AA7075 aluminum alloys by plasma electrolytic oxidation, Mater. Des. 31 (2010) 816-828.

DOI: 10.1016/j.matdes.2009.07.053

Google Scholar

[5] F. Bigdeli, S.R. Allahkaram, An investigation on corrosion resistance of as-applied and heat treated Ni-P/nanoSiC coatings, Mater. Des. 30 (2009) 4450-1153.

DOI: 10.1016/j.matdes.2009.04.020

Google Scholar

[6] V.V.N. Reddy, B. Ramamoorthy, P. Kesavan Nair, A study on the wear resistance of electroless Ni–P/Diamond composite coatings , Wear 239 (2000) 111-116.

DOI: 10.1016/s0043-1648(00)00330-6

Google Scholar

[7] Y. Wu, B. Shen, L. Liu, W. Hu, The tribological behavior of electroless Ni-P-Gr-SiC composite, Wear 261 (2006) 201-207.

DOI: 10.1016/j.wear.2005.09.008

Google Scholar

[8] N.W. Pu, C.A. Wang, Y.M. Liu, Y. Sung, D.S. Wang, M.D. Ger, Dispersion of graphene in aqueous solutions with different types of surfactants and the production of graphene films by spray or drop coating, J. Taiwan Inst. Chem. E. 43 (2012) 140-146.

DOI: 10.1016/j.jtice.2011.06.012

Google Scholar