The Removal of Impurity Silicon from Aluminum Melt by the Addition of K2TiF6

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Abstract:

A novel method to remove impurity silicon from aluminum melt by the addition of K2TiF6 was studied. The mechanism for silicon removal is the formation and sedimentation of Ti(Al1-x,Six)3 phase and the removal efficiency is mostly decided by the solubility of silicon in TiAl3 phase, which increases with the increasing of the initial silicon concentration in aluminum melt. The effect of holding temperature on the impurity Si purification efficiency was investigated and the result indicated that the effect of holding temperature is very finite.

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192-196

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August 2017

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[1] R.A. Ramadan, S.W. Sharkawy, M.A. El-Zeky, Effect of silicon addition on the microstructure constituents of Al-9Zn-2. 5 Mg alloy, Scripta Metallurgica et Materialia., 27 (1992) 821-826.

DOI: 10.1016/0956-716x(92)90399-y

Google Scholar

[2] S.P. Yuan, G. Liu et al, Coupling effect of multiple precipitates on the ductile fracture of aged Al–Mg–Si alloys, Scripta Materialia 57 (2007) 865-868.

DOI: 10.1016/j.scriptamat.2007.06.063

Google Scholar

[3] L.F. Mondolfo, Aluminum Alloys: Structure and Properties, Butterworth, London, (1976).

Google Scholar

[4] T.S. Srivatsan, The high-cycle fatigue and fracture behavior of aluminum alloy 7055, Materials Science and Engineering A 281 (2000) 292-304.

DOI: 10.1016/s0921-5093(99)00716-9

Google Scholar

[5] M. Nagao, K. Oosumi, T. Nakamura, Removal of impurity silicon from molten aluminum ally with compound method, Journal of Japan Institute of Light Metals, 46 (1996) 488-491.

Google Scholar

[6] Guoliang Zhu, Yongbing Dai, Da Shu, Yanping Xiao, Yongxiang Yang, Jun Wang, Baode Sun, Rob Boom, Diffusion mechanisms of vacancy and doped Si in Al3Ti from first-principles calculations, Intermetallics 19 (2011) 1036-1040.

DOI: 10.1016/j.intermet.2011.03.012

Google Scholar

[7] Guoliang Zhu, Yongbing Dai, Da Shu, Yanping Xiao, Yongxiang Yang, Jun Wang, Baode Sun, Rob Boom, First-principles study of point defects and Si site preference in Al3Ti, Computational Materials Science 50 (2011) 2636-2639.

DOI: 10.1016/j.commatsci.2011.04.008

Google Scholar

[8] P.S. Mohanty, J.E. Gruzleski, Grain refinement mechanisms of hypoeutectic Al-Si alloys, Acta Materialia 44 (1996) 3749-3760.

DOI: 10.1016/1359-6454(96)00021-3

Google Scholar

[9] Y. Birol, Production of Al–Ti–B grain refining master alloys from B2O3and K2TiF6, Journal of Alloys and Compounds 443 (2007) 94-98.

DOI: 10.1016/j.jallcom.2006.10.009

Google Scholar