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Photocatalysis by Nanoparticles of Titanium Dioxide for Drinking Water Purification: A Conceptual and State-of-Art Review
Abstract:
To overcome the water pollution problems, and to meet stringent environmental regulations, scientist and researchers have been focusing on the development of new water purification processes. One such group of new technologies is advanced oxidation processes (AOPs). Among the AOPs, titanium dioxide photocatalysis has been widely studied on lab scale by the researchers for decontamination of drinking water. In the present chapter, a conceptual as well as state-of-art review of titanium dioxide photocatalysis for water purification has been discussed.
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[1] Ternes, T., 1998. Occurrence of drugs in German sewage treatment plants and rivers. Water Research, 32, 3245–3260.
[2] Kolpin, D. W., Furlong, E. T., Meyer, M. T., Thurman, E., Zaugg, S. D., Buxton, L. B., 2002. Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999–2000: A national reconnaissance. Environmental Science and Technology, 36, 1202–1211.
DOI: 10.1021/es011055j
[3] Boyd, G. R., Reemtsma, H., Grimm, D. A., Mitra, S., 2003. Pharmaceuticals and personalcare products (PPCPs) in surface and treated waters of Louisiana, USA and Ontario, Canada. Science of the Total Environment, 311, 135–149.
[4] Jasim, S. Y., Irabell, A., Yang, P., Ahmed, S., Schweitzer, L. 2006. Presence of pharmaceuticals and pesticides in Detroit river water and the effect of Ozone on removal. Ozone: Science & Engineering, 28, 415–423.
[5] Na, T., Fang, Z., Zhanqi, G., Cheng, Z., Ming, S., 2006. The status of pesticide residues in the drinking water sources in Meiliangwan bay, Taihu lake of China. Environmental Monitoring and Assessment, 123, 351–370.
[6] Pasternak, J., 2006. Agricultural pesticide residues in farm ditches of the lower Fraser Valley, British Columbia, Canada. Journal of Environmental Science and Health, Part B: Pesticides, Food Contaminants, and Agricultural Wastes, 41, 647–669.
[7] Oppenlander, T., 2004. Photochemical purification of water and air. Weinheim, Wiley–VCH.
[8] Poyatos, J., Munio, M., Almecija, M., Torres, J., Hontoria, E., Osorio, F., 2009. Advanced oxidation processes for wastewater treatment: state of the art. Water, Air and Soil Pollution , 205, 187–204.
[9] Legrini, O., Oliveros, E., Braun, M., 1993. Photochemical processes for water treatment. Chemical Reviews, 93, 671-698.
DOI: 10.1021/cr00018a003
[10] Oppenlander T. 2003. Photochemical purification of water and air. Advanced oxidation processes (AOPs): principles, reaction mechanisms, reactor concepts. Weinheim, Wiley-VCH.
[11] Kisch, H., 1989. What is Photocatalysis, in photocatalysis: Fundamentals and applications, ed by N. Serpone and E. Pelizzetti, 1-7. New York, Wiley.
[12] Fenton H. J. J., 1894. Oxidation of tartaric acid in the presence of iron. Journal of Chemical Society, 65, 899-901.
[13] Litter, M. I., 1999. Heterogeneous photocatalysis: Transitiion metal ions in photocatalytic systems. Applied Catalysis B: Environmental, 23, 89-114.
[14] Mills, A., Davies, R. H., Worsley, D. 1993. Water purification by semiconductor photocatalysis. Chemical Society Reviews, 22, 417–425.
DOI: 10.1039/cs9932200417
[15] Matthews, R. W., 1988. Kinetics of photocatalytic oxidation of organic solutes over titanium dioxide. Journal of Catalysis, 111, 264–272.
[16] Linsebigler, A. L., Lu, G., Yates, J. T., 1995. Photocatalysis on TiO2 surfaces: Principles, mechanisms, and selected results. Chemical Reviews, 95, 735–758.
DOI: 10.1021/cr00035a013
[17] Minero, C., Pelizzetti, E., Malato, S., Blanco, J., 1996. Large solar plant photocatalytic water decontamination: Degradation of atrazine. Solar Energy, 56, 411-419.
[18] Ollis, D. F., Pelizzetti, E., Serpone, N., 1989. Heterogeneous photocatalysis in environment: Application to water purification. In photocatalysis: Fundamentals and applications, ed by N. Serpone and E. Pelizzetti, Willey Interscience, New York, 603-637.
[19] Mills, A., Hunte, S. L., 1997. An overview of semiconductor photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 108, 1–35.
[20] Carraway, E. R., Hoffmann, A. J., Hoffmann, M. R., 1994. Photocatalytic oxidation of organic acids on quantum-sized semiconductor colloids. Environmental Science and Technology, 28, 786-793.
DOI: 10.1021/es00054a007
[21] Hoffmann, M. R., Martin, S. T., Choi W., Bahnemannt, D. W., 1995. Environmental applications of semiconductor photocatalysis. Chemical Reviews, 95, 69–96.
[22] Khalil, L. B., Mourad, W. E., Rophael, M. W., 1998. Photocatalytic reduction of environmental pollutant Cr (VI) over some semiconductors under UV/visible light illumination. Applied Catalysis B: Environmental, 17, 267-273.
[23] Ohno, T., Tsubota, T., Toyofuku, M., Inaba, R., 2004. Photocatalytic activity of a TiO2 photocatalyst doped with C4+ and S4+ ions have a rutile phase under visible light. Catalysis Letters, 98, 255-258.
[24] Fox, M. A., Dulay, M. T., 1993. Heterogeneous Photocatalysis. Chemical Reviews, 93, 341–357.
[25] Davis, A. P., Huang, C, P., 1991. The photocatalytic oxidation of sulfur-containing organic compounds using cadmium sulfide and the effect on CdS photocorrosion. Water Research, 25, 1273-1278.
[26] Reutergardh, L. B., Iangphasuk, M., 1997. Photocatalytic decolorization of reactive Azo dye: A comparison between TiO2 and CdS Photocatalysis. Chemosphere, 35, 585- 596.
[27] Deng, N. S., Wu, F., Luo, F., Xiao, M., 1998. Ferric citrate-induced photodegradation of dyes in aqueous solution. Chemosphere, 36, 3101-3112.
[28] Bahnemann, D. W., Kholuiskaya, S. N., Dillert, R., Kulak A. I., Kokorin, A. I., 2002. Photodestruction of dichloroacetic acid catalyzed by nano-sized TiO2 particles. Applied Catalysis B: Environmental, 36, 161-169.
[29] Arabatzis, I. M., Antonaraki, S., Stergiopoulos, T., Hiskia, A., Papaconstantinou, E., Bernard, M. C., Falaras, P., 2002. Preparation, characterization and photocatalytic activity of nanocrystalline thin film TiO2 catalysts towards 3,5-dichlorophenol degradation. Journal of Photochemistry and Photobiology A: Chemistry, 149, 237-245.
[30] Turchi, C. S., Ollis, D. F., 1989. Mixed reactant photocatalysis : Intermediates and mutual rate inhibition. Journal of Catalysis, 119, 483- 496.
[31] Pelizzetti, E., Minero, C., Maurino, V., Sclafani, A., Hidaka, H., Serpone, N., 1993. Photocatalytic degradation of nonylphenol ethoxylated surfactants. Environmental Science and Technology, 23, 1380-1385.
DOI: 10.1021/es00069a008
[32] Matthews, R. W., 1984. Hydroxylation reactions induced by near-ultraviolet photocatalysis of aqueous titanium dioxide suspensions. Journal of the Chemical Society, Faraday Transactions, 80, 457-471.
DOI: 10.1039/f19848000457
[33] Turchi, C. S., Ollis, D, F., 1990. Photocatalytic degradation of organic water contaminants: Mechanisms involving hydroxyl radical attack. Journal of Catalysis, 122, 178-192.
[34] Serpone, N., Sauve, G., Koch, R., Tahiri, H., Pichat, P., Piccinini, P., Pelizzetti, E., Hidaka, H., 1996. Standadization protocol of process efficiencies and activation parameters in heterogeneous photocatalysis: Relative photonic efficiencies. Journal of Photochemistry and Photobiology A: Chemistry, 106, 191-203.
[35] Augugliaro, V., Davi, E., Palmisano, L., Schiavello, M., Sclafani, A., 1990. Influence of hydrogen peroxide on the kinetics of phenol photodegradation in aqueous titanium dioxide dispersion. Applied Catalysis, 65, 101-116.
[36] Sclafani, A., Herrmann, J, M., 1996. Comparison of the photoelectronic and photocatalytic activities of various anatase and rutile forms of titania in pure liquid organic phases and in aqueous solution. Journal of Physical Chemistry, 100, 13655-13661.
DOI: 10.1021/jp9533584
[37] Carp, O., Huisman, C. L., Reller, A., 2004. Induced reactivity of titanium dioxide. Progress in Solid State Chemistry, 32, 33-177.
[38] Fujishima, A., Rao, T. N., Tryk, D. A., 2000. Titanium dioxide photocatalysis. Journal of. Photochemistry and Photobiology C: Photochemistry Reviews. 1, 1-21.
[39] Cheng, H., Ma, J., Zhao, Z., Qi, L., 1995. Hydrothermal preparation of uniform nanosize rutile and anatase particles. Chemistry of Materials, 7, 663-671.
DOI: 10.1021/cm00052a010
[40] So, W. W., Park, S. B., Kim, K. J., Shin, C. H., Moon, S. J., 2001. The crystalline phase stability of titania particles prepared at room temperature by the sol-gel method. Journal of Materials Science, 36, 4299-4305.
[41] Xu, T., Song, C., Liu, Y., Han, G., 2006. Band structures of TiO2 doped with N, C and B. Journal of Zhejiang University Science B, 7, 299–303.
[42] Corma, A., 1997. From microporous to mesoporous molecular sieve materials and their use in catalysis, Chemical Reviews, 97, 2373-2419.
DOI: 10.1021/cr960406n
[43] Yin, H., Wada, Y., Kitamura, T., Kambe, S., Murasawa, S., Mori, H., Sakata, T., Yanagida, S., 2001. Hydrothermal synthesis of nanosized anatase and rutile TiO2 using amorphous phase TiO2, Journal of Materials Chemistry, 11, 1694-1703.
DOI: 10.1039/b008974p
[44] Zhang, Z. B., Wang, C. C., Zakaria, R., Ying, J. Y., 1998. Role of particle size in nanocrystalline TiO2 based photocatalysts. Journal of Physical Chemistry B, 102, 10871-10878.
DOI: 10.1021/jp982948+
[45] Xu, Z., Shang, J., Liu, C., Kang, C., Guo, H., Du, Y., 1999. The preparation and characterization of TiO2 ultrafine particles. Material Science and Engineering: B, 56, 211-216.
[46] Maira, A. J., Yeung, K. L., Lee, C. Y., Yue, P. L., Chan, C. K., 2000. Size effect in gas-phase photo-oxidation of trichloroethylene using nanometer-sized TiO2 catalysts. Journal of Catalysis, 192, 185-196.
[47] Almquist, C. B., Biswas, P., 2002. Role of synthesis method and particle size of nanostructures TiO2 on its photoactivity. Journal of Catalysis, 212, 145-156.
[48] Hoffman, A. J., Yee, H., Mills, G., Hoffmann, M. R., 1992. Photoinitiated polymerization of methyl methacrylate using Q-sized zinc oxide colloids. Journal of Physical Chemistry, 96, 5540-5546.
DOI: 10.1021/j100192a066
[49] Giuseppe, P. L., Langford, C. H., Vichova, J., Vleck, A., 1993. Photochemistry and picosecond absorption spectra of aqueous suspensions of a polycrystalline titaniumdioxide optically transparent in the visible spectrum. Journal of Photochemistry and Photobiology A: Chemistry, 75, 67-75.
[50] Wang, C. C., Zhang, Z., Ying, J. Y., 1997. Photocatalytic decomposition of alogenated organics over nanocrystalline titania. Nanostructured Materials, 90, 583-586.
[51] Dijkstra, M. F., Panneman, H. J., Winkelman, J. G., Kelly, J. J., Beenackers, A. A., 2002. Modeling the photocatalytic degradation of formic acid in a reactor with immobilized catalyst. Chemical Engineering Science, 57, 4895–4907.
[52] Al-Ekabi, H., De Mayo, P., 1986. Surface Photochemistry: On the Mechanism of the Semiconductor Photoinduced Valence Isomerization of Hexamethyl-Dewar Benzene to Hexamethylbenzene. Journal of Physical Chemistry, 90, 4075-4080.
DOI: 10.1021/j100408a048
[53] Cunningham, J., Srijaranci, S. J., 1991. Sensitized photo-oxidations of dissolved alcohols in homogenous and heterogeneous systems Part 2. TiO2-sensitized hotodehydrogenations of benzyl alcohol. Journal of Photochemistry and Photobiology A: Chemistry, 58, 361-371.
[54] Martin, S. T., Herrmann, H., Choi, W., Hoffmann, M. R., 1994. Time-resolved microwave conductivity. Part1-TiO2 photoreactivity and size quantization. Journal of the Chemical Society, Faraday Transactions, 90, 3315-3323.
DOI: 10.1039/ft9949003315
[55] Peill, N. J., Hoffmann, M. R., 1998. Mathematical model of photocatalytic fiber-optic cable reactor for heterogeneous photocatalysis. Environmental Science and Technology, 32, 398-404.
DOI: 10.1021/es960874e
[56] Haque, M. M., Muneer, M., Bahnemann, D. W., 2006. Semiconductor-mediated photocatalyzed degradation of a herbicide derivative, chlorotoluron, in aqueous suspensions. Environmental Science and Technology, 40, 4765-4770.
DOI: 10.1021/es060051h
[57] Saaduon, L., Ayllon, J. A., Jimenez. Becerril, J., Peral, J., Domenech, X., Rodriguez., Clemente, R., 1999. 1, 2-diolates of titanium as suitable precursors for the preparation of photoactive high surface titania. Applied Catalysis B: Environmental, 21, 269-277.
[58] Chen, D., Ray, A. K., 1999. Photocatalytic kinetics of phenol and its derivatives over UV irradiated TiO2. Applied Catalysis B: Environmental, 23, 143-147.
[59] Sriprang, N., Kaewchinda, D., Kennedy1, J. D., Milne, S. J., 2000. Processing and sol chemistry of a triol-based sol–gel route for preparing lead zirconate titanate thin films. Journal of American Ceramic Society, 83, 1914-1920.
[60] Yoshiya, K., Shin-ya, M., Hiroshi, K., Bunsho, O., 2002. Design, preparation and characterization of highly active metal oxide photocatalysts. In: Photocatalysis: science and technology. Kaneko, M., Okura, I., (eds.). Berlin Heidelberg New York, Springer-Verlag: 29-49.
[61] Hu, C., Tang, Y., Jiang, Z., Hao, Z., Tang, H., Wong, P. K., 2003. Characterization and photocatalytic activity of noble-metal-supported surface TiO2/SiO2. Applied Catalysis A: General, 253, 389-369.
[62] Alfano, O. M., Bahnemann, D., Cassano, A. E., Dillert, R., Goslich, R., 2000. Photocatalysis in water environments using artificial and solar light. Catalysis Today, 58, 199-230.
[63] Pruden, A. L., Ollis, D. F., 1983. Degradation of chloroform by photoassisted heterogeneous catalysis in dilute aqueous suspensions of TiO2. Environmental Science and Technology, 17, 628-631.
DOI: 10.1021/es00116a013
[64] Robertson, K. J., Bahnemann, D. W., Robertson, J. M. C., Wood F., 2005. Photocatalytic detoxification of water and air. In: Environmental photochemistry. Part II. Boule, P., Bahnemann, D. W., Robertson P. (eds.). Berlin Heidelberg, Springer-Verlag, 367-423.
DOI: 10.1007/b138189
[65] Wiszniowski, J., Robert, D., Surmacz., Gorska, J., Miksch, K., Malato, S., Weber, J. V., 2004. Solar photocatalytic degradation of humic acids as a model of organic compounds of landfill leachate in pilot-plant experiments: influence of inorganic salts. Applied Catalysis B: Environmental, 33, 127-137.
[66] Lawton, L. A., Robertson, P. K. J., Cornish, B. J. P. A., Jaspars, M., 1999. Detoxification of microcystins (cyanobacterial hepatotoxins) using TiO2 photocatalytic oxidation. Environmental Science and Technology, 33, 771-775.
DOI: 10.1021/es9806682
[67] Sichel C., Blanco J., Malato S. Fernández-Ibáñez P., 2007. Effects of experimental conditions on E. coli survival during solar photocatalytic water disinfection. Journal of Photochemistry and Photobiology A: Chemistry, 189, 239-246.
[68] Maness P.-C., Smolinski S., Blake D.M., Huang Z., Wolfrum E.J., Jacoby W.A. 1999. Bactericidal activity of photocatalytic TiO reaction: toward an understanding of its killing mechanism. Applied and Environmental Microbiology, 265, 4094-4098.
[69] Ollis, D. F., Turchi, C., 1990. Heterogeneous photocatalysis for water purification: contaminant mineralization kinetics and elementary reactor analysis. Environmental Progress, 9, 229–234.
DOI: 10.1002/ep.670090417
[70] Herrmann, J., 2005. Heterogeneous photocatalysis: State of the art and present applications. Topics in Catalysis, 34, 49–65.
[71] Fujishima, A., Zhang, X., 2006. Titanium dioxide photocatalysis: Present situation and future approaches. Comptes Rendus Chimie , 9, 750–760.
[72] Natarajan T. S., Thomas M., Natarajan, K., Bajaj, H. C., Tayade, R. J., 2011. Study on UV-LED/TiO2 process for degradation of Rhodamine B dye. Chemical Engineering Journal, 169,126–134.
[73] Natarajan, T. S., Natarajan, K., Bajaj, H. C., Tayade, R. J., 2011. Energy Efficient UV-LED source and TiO2 nanotube array-based reactor for photocatalytic application. Industrial & Engineering Chemistry Research, 50, 7753-7762.
DOI: 10.1021/ie200493k