Magnetic Interaction between d1 [MOR4]− Units of Molybdenum and Tungsten

M. Ángeles García-Monforte; Pablo J. Alonso; Ana B. Arauzo; Miguel Baya; Fernando Luis; Antonio Martín; Babil Menjón; Conrado Rillo

doi:10.4028/www.scientific.net/SSP.257.223

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HomeSolid State PhenomenaSolid State Phenomena Vol. 257Magnetic Interaction between d1 [MOR4]− Units of...

Magnetic Interaction between d¹ [MOR₄]⁻ Units of Molybdenum and Tungsten

Abstract:

Five-coordinate oxo-derivatives [NBu₄][MO(C₆F₅)₄] (1) have been prepared for the heavier Group 6 elements: 1-Mo and 1-W. The magnetic properties of that salts have been studied by a combination of Electron paramagnetic resonance (EPR), calorimetric and magnetochemical techniques, pointing out the existence of weak ferromagnetic interactions. These have been correlated with the arrangement of the magnetic units in the crystal.

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Periodical:

Solid State Phenomena (Volume 257)

Pages:

223-226

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.257.223

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Online since:

October 2016

Authors:

M. Ángeles García-Monforte, Pablo J. Alonso*, Ana B. Arauzo, Miguel Baya, Fernando Luis, Antonio Martín, Babil Menjón, Conrado Rillo

Keywords:

Magnetic Interactions, Molybdenum, Oxo-Derivatives, Perfluorphenyl Ligands, Tungsten

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