DOI QR코드

DOI QR Code

Transparent MWCNT Thin Films Fabricated by using the Spray Method

스프레이법으로 제작된 투명 MWCNT 박막

  • 장경욱 (경원대학교 전기공학과)
  • Published : 2010.04.01

Abstract

Carbon nanotubes (CNTs) have excellent electrical, chemical stability, mechanical and thermal properties. The MWCNT films were investigated as a transparent electrode for the solar cell, OLED, and field-emission display. MWCNT films were fabricated by air spray method, whose process is quite low-costed, using the multi-walled CNTs solution on glass substrates. Moreover, the most stable film was fabricated when the spraying time was 60 sec. The film that was sprayed with the MWCNT dispersion for 60 sec, has 300nm thick. And its electric resistivity, transmittance rate, mobility and carrier concentration are $6{\times}10^{-2}{\Omega}{\cdot}cm$, 50% at ${\lambda}=550mm$, $4.3{\times}10^{-2}cm^2/V{\cdot}s$ and $2.1{\times}10^{21}cm^{-3}$, respectively. Also, absorption energy of MWCNT films show from 3.9 eV to 4.6 eV. Furthermore, we can use MWCNT films fabricated by the spray method for the transparent electrode.

Keywords

References

  1. S. C. Lim, D. S. Lee, H. K. Choi, I. H. Lee, and Y. H. Lee, "Field emission of carbon-nanotube point electron source", Diamond and Related Materials, Vol. 18, Issue 12, p. 1435, 2009. https://doi.org/10.1016/j.diamond.2009.09.010
  2. T. Sawatsuk, A. Chindaduang, C. Sae-Kung, S. Pratontep, and G. Tumcharern, "Dyesensitized solar cells based on $TiO_2$– MWCNTs composite electrodes: Performance improvement and their mechanisms", Diamond and Related Materials, Vol. 18, Issues 2-3, p. 524, 2009. https://doi.org/10.1016/j.diamond.2008.10.052
  3. R. Philippe, B. Caussat, A. Falqui, Y. Kihn, P. Kalck, S. Bordère, D. Plee, P. Gaillard, D. Bernard, and P. Serp, "An original growth mode of MWCNTs on alumina supported iron catalysts", Journal of Catalysis, Vol. 263, Issue 2, p. 345, 2009. https://doi.org/10.1016/j.jcat.2009.02.027
  4. E. F. Antunes, A. O. Lobo, E. J. Corat, V. J. Trava-Airoldi, A. A. Martin, and C. Verissimo, "Comparative study of first- and second-order Raman spectra of MWCNT at visible and infrared laser excitation", Carbon, Vol. 44, Issue 11, p. 2202, 2006. https://doi.org/10.1016/j.carbon.2006.03.003
  5. C.-S. Huang, C.-Y. Yeh, Y.-H. Chang, Y.- M. Hsieh, C.-Y. Ku, and Q.-T. Lai, "Field emission properties of CNT–ZnO composite materials", Diamond and Related Materials, Vol. 18, Issues 2-3, p. 452, 2009. https://doi.org/10.1016/j.diamond.2008.10.058
  6. P. Saini, V. Choudhary, B. P. Singh, R. B. Mathur, and S. K. Dhawan, "Polyaniline– MWCNT nanocomposites for microwave absorption and EMI shielding", Materials Chemistry and Physics, Vol. 113, Issues 2-3, p. 919, 2009. https://doi.org/10.1016/j.matchemphys.2008.08.065
  7. S.-M. Kim, H.-W. Choi, K.-H. Kim, S.-J. Park, and H.-H. Yoon, "Preparation of ITO and thin films by using the facing targets sputtering (FTS) method", Journal of the Korean Physical Society, Vol. 55, No. 5, p. 1996, 2009. https://doi.org/10.3938/jkps.55.1996
  8. Stephen K. O'Leary and P. K. Lim, “On determining the optical gap associated with an amorphous semiconductor: A generalization of the Tauc model”, Solid State Communications, Vol. 104, Issue 1, p. 17, 1997. https://doi.org/10.1016/S0038-1098(97)00268-8