Journal of Ion Exchange
Online ISSN : 1884-3360
Print ISSN : 0915-860X
ISSN-L : 0915-860X
Use of a Two Parameter Temperature Dependant Semi-Empirical Thermodynamic Ion Exchange Model
Kathryn A. MumfordKathy A. NorthcottDavid C. ShallcrossGeoff W. StevensIan Snape
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2007 Volume 18 Issue 4 Pages 570-573

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Abstract

A chelating ion exchange resin, Amberlite IRC 748 was investigated for the exchange of copper and sodium from aqueous solutions at three temperatures. A two parameter temperature dependant semi-empirical thermodynamic ion exchange model was used to describe binary systems involving the ions Cu2+ and Na+. All experiments were conducted with Cl- as the non-exchanging anion and at temperatures of 4.0, 20.0 and 40.0±0.1°C. The semi-empirical thermodynamic ion exchange model was shown to predict the shape and position of the ion exchange curves accurately. There was a consistent increase in selectivity of the resin towards copper with an increase in temperature.

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